JEE MAIN - Chemistry (2024 - 31st January Morning Shift)

1

Match List I with List II

List - I List - II
(A) Glucose/$$\mathrm{NaHCO_3/\Delta}$$ (I) Gluconic acid
(B) $$\text { Glucose } / \mathrm{HNO}_3$$ (II) No reaction
(C) $$\text { Glucose } / \mathrm{HI} / \Delta$$ (III) n-hexane
(D) Glucose/Bromine water (IV) Saccharic acid

Choose the correct answer from the options given below:

Answer
(A)
A-II, B-IV, C-III, D-I
2
Consider the oxides of group 14 elements $$\mathrm{SiO}_2, \mathrm{GeO}_2, \mathrm{SnO}_2, \mathrm{PbO}_2, \mathrm{CO}$$ and $$\mathrm{GeO}$$. The amphoteric oxides are
Answer
(C)
$$\mathrm{SnO}_2, \mathrm{PbO}_2$$
3
The compound that is white in color is
Answer
(D)
lead sulphate
4

Give below are two statements:

Statement - I: Noble gases have very high boiling points.

Statement - II: Noble gases are monoatomic gases. They are held together by strong dispersion forces. Because of this they are liquefied at very low temperature. Hence, they have very high boiling points.

In the light of the above statements, choose the correct answer from the options given below:

Answer
(A)
Both Statement I and Statement II are false.
5
A species having carbon with sextet of electrons and can act as electrophile is called
Answer
(D)
carbocation
6
Identify the mixture that shows positive deviations from Raoult's Law
Answer
(A)
$$\left(\mathrm{CH}_3\right)_2 \mathrm{CO}+\mathrm{CS}_2$$
7

The correct statements from following are:

A. The strength of anionic ligands can be explained by crystal field theory.

B. Valence bond theory does not give a quantitative interpretation of kinetic stability of coordination compounds.

C. The hybridization involved in formation of $$\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$$ complex is $$\mathrm{dsp}^2$$.

D. The number of possible isomer(s) of cis- $$\left[\mathrm{PtCl}_2(\mathrm{en})_2\right]^{2+}$$ is one

Choose the correct answer from the options given below:

Answer
(A)
B, C only
8

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: Alcohols react both as nucleophiles and electrophiles.

Reason R: Alcohols react with active metals such as sodium, potassium and aluminum to yield corresponding alkoxides and liberate hydrogen.

In the light of the above statements, choose the correct answer from the options given below:

Answer
(B)
Both $$A$$ and $$R$$ are true but $$R$$ is NOT the correct explanation of $$A$$.
9

The product (C) in the below mentioned reaction is :

$$\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{Br} \xrightarrow[\Delta]{\mathrm{KOH}_{(\text {alc) }}} \mathrm{A} \xrightarrow{\mathrm{HBr}} \mathrm{B} \xrightarrow[\mathrm{KOH}_{(\mathrm{aq})}]{\Delta} \mathrm{C}$$

Answer
(C)
Propan-2-ol
10
Identify the factor from the following that does not affect electrolytic conductance of a solution.
Answer
(C)
The nature of the electrode used.
11
Integrated rate law equation for a first order gas phase reaction is given by (where $$\mathrm{P}_{\mathrm{i}}$$ is initial pressure and $$\mathrm{P}_{\mathrm{t}}$$ is total pressure at time $$t$$)
Answer
(A)
$$k=\frac{2.303}{t} \times \log \frac{P_i}{\left(2 P_i-P_t\right)}$$
12

For the given reaction, choose the correct expression of $$\mathrm{K}_{\mathrm{C}}$$ from the following :-

$$\mathrm{Fe}_{(\mathrm{aq})}^{3+}+\mathrm{SCN}_{(\mathrm{aq})}^{-} \rightleftharpoons(\mathrm{FeSCN})_{(\mathrm{aq})}^{2+}$$

Answer
(B)
$$\mathrm{K}_{\mathrm{C}}=\frac{\left[\mathrm{FeSCN}^{2+}\right]}{\left[\mathrm{Fe}^{3+}\right]\left[\mathrm{SCN}^{-}\right]}$$
13

The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals

A. have the same energy

B. have the minimum overlap

C. have same symmetry about the molecular axis

D. have different symmetry about the molecular axis

Choose the most appropriate from the options given below:

Answer
(D)
A and C only
14

Identify correct statements from below:

A. The chromate ion is square planar.

B. Dichromates are generally prepared from chromates.

C. The green manganate ion is diamagnetic.

D. Dark green coloured $$\mathrm{K}_2 \mathrm{MnO}_4$$ disproportionates in a neutral or acidic medium to give permanganate.

E. With increasing oxidation number of transition metal, ionic character of the oxides decreases.

Choose the correct answer from the options given below:

Answer
(A)
B, D, E only
15

The metals that are employed in the battery industries are

A. $$\mathrm{Fe}$$

B. $$\mathrm{Mn}$$

C. $$\mathrm{Ni}$$

D. $$\mathrm{Cr}$$

E. $$\mathrm{Cd}$$

Choose the correct answer from the options given below:

Answer
(D)
B, C and E only
16

Match List I with List II

List - I (Technique) List - II (Application
(A) Distillation (I) Separation of glycerol from spent-lye
(B) Fractional distillation (II) Aniline - Water mixture
(C) Steam distillation (III) Separation of crude oil fractions
(D) Distillation under reduced pressure (IV) Chloroform - Aniline

Choose the correct answer from the options given below:

Answer
(D)
A-IV, B-III, C-II, D-I
17
'Adsorption' principle is used for which of the following purification method?
Answer
(A)
Chromatography
18

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: $$\mathrm{pK}_{\mathrm{a}}$$ value of phenol is 10.0 while that of ethanol is 15.9 .

Reason R: Ethanol is stronger acid than phenol.

In the light of the above statements, choose the correct answer from the options given below:

Answer
(D)
$$A$$ is true but $$R$$ is false.
19

Given below are two statements:

Statement I: IUPAC name of $$\mathrm{HO}-\mathrm{CH}_2-\left(\mathrm{CH}_2\right)_3-\mathrm{CH}_2-\mathrm{COCH}_3$$ is 7-hydroxyheptan-2-one.

Statement II: 2-oxoheptan-7-ol is the correct IUPAC name for above compound. In the light of the above statements, choose the most appropriate answer from the options given below:

Answer
(B)
Statement I is correct but Statement II is incorrect.
20

The correct sequence of electron gain enthalpy of the elements listed below is

A. Ar

B. Br

C. F

D. S

Choose the most appropriate from the options given below:

Answer
(B)
$$\mathrm{A}>\mathrm{D}>\mathrm{B}>\mathrm{C}$$
21
Consider the following reaction at $$298 \mathrm{~K} \cdot \frac{3}{2} \mathrm{O}_{2(g)} \rightleftharpoons \mathrm{O}_{3(g)} \cdot \mathrm{K}_{\mathrm{P}}=2.47 \times 10^{-29}$$. $$\Delta_r G^{\ominus}$$ for the reaction is _________ $$\mathrm{kJ}$$. (Given $$\mathrm{R}=8.314 \mathrm{~JK}^{-1} \mathrm{~mol}^{-1}$$)
Answer
163
22

The product of the following reaction is P.

JEE Main 2024 (Online) 31st January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 38 English

The number of hydroxyl groups present in the product P is ________.

Answer
0
23
The ionization energy of sodium in $$\mathrm{~kJ} \mathrm{~mol}^{-1}$$, if electromagnetic radiation of wavelength $$242 \mathrm{~nm}$$ is just sufficient to ionize sodium atom is _______.
Answer
494
24
Number of alkanes obtained on electrolysis of a mixture of $$\mathrm{CH}_3 \mathrm{COONa}$$ and $$\mathrm{C}_2 \mathrm{H}_5 \mathrm{COONa}$$ is ________.
Answer
3
25
The 'Spin only' Magnetic moment for $$\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+}$$ is _________ $$\times 10^{-1} \mathrm{~BM}$$. (given $$=$$ Atomic number of $$\mathrm{Ni}: 28$$)
Answer
28
26
One Faraday of electricity liberates $$x \times 10^{-1}$$ gram atom of copper from copper sulphate. $$x$$ is ________.
Answer
5
27
Number of moles of methane required to produce $$22 \mathrm{~g} \mathrm{~CO}_{2(\mathrm{~g})}$$ after combustion is $$\mathrm{x} \times 10^{-2}$$ moles. The value of $$\mathrm{x}$$ is _________.
Answer
50
28

Molar mass of the salt from $$\mathrm{NaBr}, \mathrm{NaNO}_3, \mathrm{KI}$$ and $$\mathrm{CaF}_2$$ which does not evolve coloured vapours on heating with concentrated $$\mathrm{H}_2 \mathrm{SO}_4$$ is ________ $$\mathrm{g} \mathrm{~mol}{ }^{-1}$$.

(Molar mass in $$\mathrm{g} \mathrm{~mol}^{-1}: \mathrm{Na}: 23, \mathrm{~N}: 14, \mathrm{~K}: 39, \mathrm{O}: 16, \mathrm{Br}: 80, \mathrm{I}: 127, \mathrm{~F}: 19, \mathrm{Ca}: 40)$$

Answer
78
29

JEE Main 2024 (Online) 31st January Morning Shift Chemistry - Haloalkanes and Haloarenes Question 30 English

The total number of hydrogen atoms in product A and product B is _________.

Answer
10
30

The number of species from the following in which the central atom uses $$\mathrm{sp}^3$$ hybrid orbitals in its bonding is __________.

$$\mathrm{NH}_3, \mathrm{SO}_2, \mathrm{SiO}_2, \mathrm{BeCl}_2, \mathrm{CO}_2, \mathrm{H}_2 \mathrm{O}, \mathrm{CH}_4, \mathrm{BF}_3$$

Answer
3