JEE MAIN - Chemistry (2024 - 31st January Morning Shift - No. 14)

Identify correct statements from below:

A. The chromate ion is square planar.

B. Dichromates are generally prepared from chromates.

C. The green manganate ion is diamagnetic.

D. Dark green coloured $$\mathrm{K}_2 \mathrm{MnO}_4$$ disproportionates in a neutral or acidic medium to give permanganate.

E. With increasing oxidation number of transition metal, ionic character of the oxides decreases.

Choose the correct answer from the options given below:

B, D, E only
A, B, C only
A, D, E only
B, C, D only

Explanation

A. $$\mathrm{CrO}_4{ }^{2-}$$ is tetrahedral

B. $$2 \mathrm{Na}_2 \mathrm{CrO}_4+2 \mathrm{H}^{+} \rightarrow \mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7+2 \mathrm{Na}^{+}+\mathrm{H}_2 \mathrm{O}$$

C. As per NCERT, green manganate is paramagnetic with 1 unpaired electron.

D. Statement is correct

E. Statement is correct

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