JEE MAIN - Chemistry (2024 - 31st January Morning Shift - No. 28)

Molar mass of the salt from $$\mathrm{NaBr}, \mathrm{NaNO}_3, \mathrm{KI}$$ and $$\mathrm{CaF}_2$$ which does not evolve coloured vapours on heating with concentrated $$\mathrm{H}_2 \mathrm{SO}_4$$ is ________ $$\mathrm{g} \mathrm{~mol}{ }^{-1}$$.

(Molar mass in $$\mathrm{g} \mathrm{~mol}^{-1}: \mathrm{Na}: 23, \mathrm{~N}: 14, \mathrm{~K}: 39, \mathrm{O}: 16, \mathrm{Br}: 80, \mathrm{I}: 127, \mathrm{~F}: 19, \mathrm{Ca}: 40)$$

Answer
78

Explanation

$$\mathbf{C a F}_2$$ does not evolve any gas with concentrated $$\mathrm{H}_2 \mathrm{SO}_4$$.

$$\mathrm{NaBr} \rightarrow$$ evolve $$\mathrm{Br}_2$$

$$\mathrm{NaNO}_3 \rightarrow$$ evolve $$\mathrm{NO}_2$$

$$\mathrm{KI} \rightarrow$$ evolve $$\mathrm{I}_2$$

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