Formation of which complex, among the following, is not a confirmatory test of $$\mathrm{Pb}^{2+}$$ ions :

Element not present in Nessler's reagent is :

Consider the following reaction that goes from A to B in three steps as shown below:

Choose the correct option

Find out the major product from the following reaction.

If the radius of the first orbit of hydrogen atom is $$\alpha_{0}$$, then de Broglie's wavelength of electron in $$3^{\text {rd }}$$ orbit is :

Which one of the following elements will remain as liquid inside pure boiling water?

Given below are two statements: one is labelled as "Assertion A" and the other is labelled as "Reason R"

Assertion A : In the complex $$\mathrm{Ni}(\mathrm{CO})_{4}$$ and $$\mathrm{Fe}(\mathrm{CO})_{5}$$, the metals have zero oxidation state.

Reason R : Low oxidation states are found when a complex has ligands capable of $$\pi$$-donor character in addition to the $\sigma$-bonding.

In the light of the above statements, choose the most appropriate answer from the options given below

Group-13 elements react with $$\mathrm{O}_{2}$$ in amorphous form to form oxides of type $$\mathrm{M}_{2} \mathrm{O}_{3}~(\mathrm{M}=$$ element). Which among the following is the most basic oxide?

During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value of 3. Identify which of the below medium will favour the reaction.

In the following reaction, 'B' is

The IUPAC name of $$\mathrm{K}_{3}\left[\mathrm{Co}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}\right]$$ is:-

The strongest acid from the following is

Match List I with List II

	LIST I Natural Amino Acid		LIST II One Letter Code
A.	Arginine	I.	D
B.	Aspartic acid	II.	N
C.	Asparagine	III.	A
D.	Alanine	IV.	R

Choose the correct answer from the options given below:

From the figure of column chromatography given below, identify incorrect statements.

A. Compound 'c' is more polar than 'a' and 'b'

B. Compound '$$\mathrm{a}$$' is least polar

C. Compound 'b' comes out of the column before 'c' and after 'a'

D. Compound 'a' spends more time in the column

Choose the correct answer from the options given below:

The volume of $$0.02 ~\mathrm{M}$$ aqueous $$\mathrm{HBr}$$ required to neutralize $$10.0 \mathrm{~mL}$$ of $$0.01 ~\mathrm{M}$$ aqueous $$\mathrm{Ba}(\mathrm{OH})_{2}$$ is (Assume complete neutralization)

The number of species having a square planar shape from the following is __________.

$$\mathrm{XeF}_{4}, \mathrm{SF}_{4}, \mathrm{SiF}_{4}, \mathrm{BF}_{4}^{-}, \mathrm{BrF}_{4}^{-},\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+},\left[\mathrm{FeCl}_{4}\right]^{2-},\left[\mathrm{PtCl}_{4}\right]^{2-}$$

The standard reduction potentials at $$298 \mathrm{~K}$$ for the following half cells are given below:

$$\mathrm{NO}_{3}^{-}+4 \mathrm{H}^{+}+3 \mathrm{e}^{-} \rightarrow \mathrm{NO}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O} \quad \mathrm{E}^{\theta}=0.97 \mathrm{~V}$$

$$\mathrm{V}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{V} \quad\quad\quad \mathrm{E}^{\theta}=-1.19 \mathrm{~V}$$

$$\mathrm{Fe}^{3+}(\mathrm{aq})+3 \mathrm{e}^{-} \rightarrow \mathrm{Fe} \quad\quad\quad \mathrm{E}^{\theta}=-0.04 \mathrm{~V}$$

$$\mathrm{Ag}^{+}(\mathrm{aq})+\mathrm{e}^{-} \rightarrow \mathrm{Ag}(\mathrm{s}) \quad\quad\quad \mathrm{E}^{\theta}=0.80 \mathrm{~V}$$

$$\mathrm{Au}^{3+}(\mathrm{aq})+3 \mathrm{e}^{-} \rightarrow \mathrm{Au}(\mathrm{s}) \quad\quad\quad \mathrm{E}^{\theta}=1.40 \mathrm{~V}$$

The number of metal(s) which will be oxidized by $$\mathrm{NO}_{3}^{-}$$ in aqueous solution is __________.

Consider the following data

Heat of combustion of $$\mathrm{H}_{2}(\mathrm{g})\quad\quad=-241.8 \mathrm{~kJ} \mathrm{~mol}^{-1}$$

Heat of combustion of $$\mathrm{C}(\mathrm{s})\quad\quad=-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$$

Heat of combustion of $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(\mathrm{l})\quad=-1234.7 \mathrm{~kJ}~{\mathrm{mol}}^{-1}$$

The heat of formation of $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(\mathrm{l})$$ is $$(-)$$ ___________ $$\mathrm{kJ} ~\mathrm{mol}^{-1}$$ (Nearest integer).

Number of isomeric aromatic amines with molecular formula $$\mathrm{C}_{8} \mathrm{H}_{11} \mathrm{~N}$$, which can be synthesized by Gabriel Phthalimide synthesis is ____________.

The equilibrium composition for the reaction $$\mathrm{PCl}_{3}+\mathrm{Cl}_{2} \rightleftharpoons \mathrm{PCl}_{5}$$ at $$298 \mathrm{~K}$$ is given below:

$$\left[\mathrm{PCl}_{3}\right]_{\mathrm{eq}}=0.2 \mathrm{~mol} \mathrm{~L}^{-1},\left[\mathrm{Cl}_{2}\right]_{\mathrm{eq}}=0.1 \mathrm{~mol} \mathrm{~L}^{-1},\left[\mathrm{PCl}_{5}\right]_{\mathrm{eq}}=0.40 \mathrm{~mol} \mathrm{~L}^{-1}$$

If $$0.2 \mathrm{~mol}$$ of $$\mathrm{Cl}_{2}$$ is added at the same temperature, the equilibrium concentrations of $$\mathrm{PCl}_{5}$$ is __________ $$\times 10^{-2} \mathrm{~mol} \mathrm{~L}^{-1}$$

Given : $$\mathrm{K}_{\mathrm{c}}$$ for the reaction at $$298 \mathrm{~K}$$ is 20

In an ice crystal, each water molecule is hydrogen bonded to ____________ neighbouring molecules.

Among the following, the number of compounds which will give positive iodoform reaction is _________

(a) 1-Phenylbutan-2-one

(b) 2-Methylbutan-2-ol

(c) 3-Methylbutan-2-ol

(d) 1-Phenylethanol

(e) 3,3-dimethylbutan-2-one

(f) 1-Phenylpropan-2-ol

Consider the following pairs of solution which will be isotonic at the same temperature. The number of pairs of solutions is / are ___________.

A. $$1 ~\mathrm{M}$$ aq. $$\mathrm{NaCl}$$ and $$2 ~\mathrm{M}$$ aq. urea

B. $$1 ~\mathrm{M}$$ aq. $$\mathrm{CaCl}_{2}$$ and $$1.5 ~\mathrm{M}$$ aq. $$\mathrm{KCl}$$

C. $$1.5 ~\mathrm{M}$$ aq. $$\mathrm{AlCl}_{3}$$ and $$2 ~\mathrm{M}$$ aq. $$\mathrm{Na}_{2} \mathrm{SO}_{4}$$

D. $$2.5 ~\mathrm{M}$$ aq. $$\mathrm{KCl}$$ and $$1 ~\mathrm{M}$$ aq. $$\mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}$$