Given below are two statements :

Statement I : Boron is extremely hard indicating its high lattice energy.

Statement II : Boron has highest melting and boiling point compared to its other group members.

In the light of the above statements, choose the most appropriate answer from the options given below :

Match List I with List II

	LIST I Complex		LIST II CFSE ($$\Delta_0$$)
A.	$$\mathrm{[Cu(NH_3)_6]^{2+}}$$	I.	$$-0.6$$
B.	$$\mathrm{[Ti(H_2O)_6]^{3+}}$$	II.	$$-2.0$$
C.	$$\mathrm{[Fe(CN)_6]^{3-}}$$	III.	$$-1.2$$
D.	$$\mathrm{[NiF_6]^{4-}}$$	IV.	$$-0.4$$

Choose the correct answer from the options given below:

The two products formed in above reaction are -

The bond order and magnetic property of acetylide ion are same as that of

'A' in the above reaction is:

Given below are two statement: one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion A: $$5 \mathrm{f}$$ electrons can participate in bonding to a far greater extent than $$4 \mathrm{f}$$ electrons

Reason R: $$5 \mathrm{f}$$ orbitals are not as buried as $$4 \mathrm{f}$$ orbitals

In the light of the above statements, choose the correct answer from the options given below

A metal chloride contains $$55.0 \%$$ of chlorine by weight . $$100 \mathrm{~mL}$$ vapours of the metal chloride at STP weigh $$0.57 \mathrm{~g}$$. The molecular formula of the metal chloride is

(Given: Atomic mass of chlorine is $$35.5 \mathrm{u}$$)

Correct statements for the given reaction are :

A. Compound '$$\mathrm{B}$$' is aromatic

B. The completion of above reaction is very slow

C. 'A' shows tautomerism

D. The bond lengths of C-C in compound $B$ are found to be same

Choose the correct answer from the options given below:

The incorrect statement regarding the reaction given below is

For lead storage battery pick the correct statements

A. During charging of battery, $$\mathrm{PbSO}_{4}$$ on anode is converted into $$\mathrm{PbO}_{2}$$

B. During charging of battery, $$\mathrm{PbSO}_{4}$$ on cathode is converted into $$\mathrm{PbO}_{2}$$

C. Lead storage battery consists of grid of lead packed with $$\mathrm{PbO}_{2}$$ as anode

D. Lead storage battery has $$\sim 38 \%$$ solution of sulphuric acid as an electrolyte

Choose the correct answer from the options given below:

Given below are two statements :

Statement I : $$\mathrm{SbCl}_{5}$$ is more covalent than $$\mathrm{SbCl}_{3}$$

Statement II: The higher oxides of halogens also tend to be more stable than the lower ones.

In the light of the above statements, choose the most appropriate answer from the options given below :

In the following reaction

'A' is

The major product 'P' formed in the following sequence of reactions is

In an oligopeptide named Alanylglycylphenyl alanyl isoleucine, the number of $$\mathrm{sp}^{2}$$ hybridised carbons is __________.

80 mole percent of $$\mathrm{MgCl}_{2}$$ is dissociated in aqueous solution. The vapour pressure of $$1.0 ~\mathrm{molal}$$ aqueous solution of $$\mathrm{MgCl}_{2}$$ at $$38^{\circ} \mathrm{C}$$ is ____________ $$\mathrm{mm} ~\mathrm{Hg.} ~\mathrm{(Nearest} ~\mathrm{integer)}$$

Given : Vapour pressure of water at $$38^{\circ} \mathrm{C}$$ is $$50 \mathrm{~mm} ~\mathrm{Hg}$$

Values of work function (W$$_0$$) for a few metals are given below

Metal	Li	Na	K	Mg	Cu	Ag
W$$_0$$/eV	2.42	2.3	2.25	3.7	4.8	4.3

The number of metals which will show photoelectric effect when light of wavelength $$400 \mathrm{~nm}$$ falls on it is ___________

Given: $$\mathrm{h}=6.6 \times 10^{-34} \mathrm{~J} \mathrm{~s}$$

$$c=3 \times 10^{8} \mathrm{~ms}^{-1}$$

$$e=1.6 \times 10^{-19} \mathrm{C}$$

Three organic compounds A, B and $$\mathrm{C}$$ were allowed to run in thin layer chromatography using hexane and gave the following result (see figure). The $$\mathrm{R}_{\mathrm{f}}$$ value of the most polar compound is ____________ $$\times 10^{-2}$$

The value of $$x$$ in compound 'D' is _________.

The mass of NH$$_3$$ produced when 131.8 kg of cyclohexanecarbaldehyde undergoes Tollen's test is ________ kg. (Nearest Integer)

Molar Mass of

C = 12g/mol

N = 14g/mol

O = 16g/mol

The reaction $$2 \mathrm{NO}+\mathrm{Br}_{2} \rightarrow 2 \mathrm{NOBr}$$

takes places through the mechanism given below:

$$\mathrm{NO}+\mathrm{Br}_{2} \Leftrightarrow \mathrm{NOBr}_{2}$$ (fast)

$$\mathrm{NOBr}_{2}+\mathrm{NO} \rightarrow 2 \mathrm{NOBr}$$ (slow)

The overall order of the reaction is ___________.

An analyst wants to convert $$1 \mathrm{~L} \mathrm{~HCl}$$ of $$\mathrm{pH}=1$$ to a solution of $$\mathrm{HCl}$$ of $$\mathrm{pH} ~2$$. The volume of water needed to do this dilution is __________ $$\mathrm{mL}$$. (Nearest integer)

One mole of an ideal gas at $$350 \mathrm{~K}$$ is in a $$2.0 \mathrm{~L}$$ vessel of thermally conducting walls, which are in contact with the surroundings. It undergoes isothermal reversible expansion from 2.0 L to $$3.0 \mathrm{~L}$$ against a constant pressure of $$4 \mathrm{~atm}$$. The change in entropy of the surroundings ( $$\Delta \mathrm{S})$$ is ___________ $$\mathrm{J} \mathrm{K}^{-1}$$ (Nearest integer)

Given: $$\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$.