JEE MAIN - Chemistry (2022 - 30th June Morning Shift)

1
The number of radial nodes and total number of nodes in 4p orbital respectively are :
Answer
(A)
2 and 3
2

For a solution of the gases A, B, C and D in water at 298 K, the values of Henry's law constant (KH) are 30.40, 2.34, 1.56 $$\times$$ 10$$-$$5 and 0.513 k bar respectively. In the given graph, the lines marked as 'p' and 's' correspond respectively to :

JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Solutions Question 58 English

Answer
(A)
A and C
3

The equilibrium constant for the reversible reaction

2A(g) $$\rightleftharpoons$$ 2B(g) + C(g) is K1

$${3 \over 2}$$A(g) $$\rightleftharpoons$$ $${3 \over 2}$$B(g) + $${3 \over 4}$$C(g) is K2.

K1 and K2 are related as :

Answer
(C)
$${K_2} = K_1^{3/4}$$
4
In which of the following half cells, electrochemical reaction is pH dependent?
Answer
(B)
$$MnO_4^ - \,|M{n^{2 + }}$$
5
The correct order of electron gain enthalpy ($$-$$ ve value) is :
Answer
(C)
O < S > Se > Te
6
$$\Delta$$G$$^\circ$$ vs T plot for the formation of MgO, involving reaction

2Mg + O2 $$\to$$ 2MgO, will look like :
Answer
(A)
JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Thermodynamics Question 76 English Option 1
7

A $$\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{}^{573\,K}} $$ Red phosphorus $$\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{under\,pressure}^{heat\,;\,803\,K}} $$ B

Red phosphorus is obtained by heating "A" at 573 K, and can be converted to "B" by heating at 803 K under pressure.

A and B, respectively, are

Answer
(D)
white phosphorus and $$\alpha$$-black phosphorus.
8
Correct formula of the compound which gives a white precipitate with BaCl2 solution, but not with AgNO3 solution, is :
Answer
(A)
[Co(NH3)5Br]SO4
9

Consider the given chemical reaction

JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 89 English

Identify the product P.

Answer
(A)
JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 89 English Option 1
10
Choose the reaction which is not possible:
Answer
(D)
JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 92 English Option 4
11

Which among the following will be the major product of the given reaction?

JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 90 English

Answer
(B)
JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 90 English Option 2
12

JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 73 English

Consider the above reaction sequence. Identify the component A and component B :

Answer
(B)
JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 73 English Option 2
13
The sugar produced after complete hydrolysis of DNA is
Answer
(A)
a pentose sugar.
14
The reagent neutral ferric chloride is used to detect the presence of ______________
Answer
(B)
acetate ion and phenolic $$-$$OH group.
15

Blister copper is produced by reaction of copper oxide with copper sulphide.

2Cu2O + Cu2S $$\to$$ 6Cu + SO2

When 2.86 $$\times$$ 103 g of Cu2O and 4.77 $$\times$$ 103 g of Cu2S are used for reaction, the mass of copper produced is _____________ g. (nearest integer)

(Atomic mass of Cu = 63.5 a.m. u, S = 32.0 a.m. u, O = 16.0 a.m. u)

Answer
3810
16

Amongst the following, the number of molecule/(s) having net resultant dipole moment is ____________.

NF3, BF3, BeF2, CHCl3, H2S, SiF4, CCl4, PF5

Answer
3
17

1.0 mol of monoatomic ideal gas is expanded from state 1 to state 2 as shown in the figure. The magnitude of the work done for the expansion of gas from state 1 to state 2 at 300 K is ____________ J. (Nearest integer)

(Given : R = 8.3 J K$$-$$1 mol$$-$$1, ln10 = 2.3, log2 = 0.30)

JEE Main 2022 (Online) 30th June Morning Shift Chemistry - Thermodynamics Question 75 English

Answer
1718
18

For the reaction P $$\to$$ B, the values of frequency factor A and activation energy EA are 4 $$\times$$ 1013 s$$-$$1 and 8.3 kJ mol$$-$$1 respectively. If the reaction is of first order, the temperature at which the rate constant is 2 $$\times$$ 10$$-$$6 s$$-$$1 is _____________ $$\times$$ 10$$-$$1 K.

(Given : ln 10 = 2.3, R = 8.3 J K$$-$$1 mol$$-$$1, log2 = 0.30)

Answer
225
19

In the following brown complex, the oxidation state of iron is +_____________.

$${[Fe{({H_2}O)_6}]^{2 + }} + NO \to \mathop {{{[Fe{{({H_2}O)}_5}(NO)]}^{2 + }}}\limits_{\text{Brown complex}} + {H_2}O$$

Answer
1
20

Spin only magnetic moment ($$\mu$$s) of $${K_3}[Fe{(CN)_6}]$$ is ____________ B.M.

(Nearest integer)

Answer
2
21

An organic compound with 51.6% sulfur is heated in a Carius tube. The amount of this compound which will form 0.752 g of barium sulphate is ___________ $$\times$$ 10$$-$$1 g.

(Given molar mass of barium sulphate 233 g mol$$-$$1) (Nearest integer).

Answer
2
22
A hydrocarbon 'X' is found to have molar mass of 80. A 10.0 mg of compound 'X' on hydrogenation consumed 8.40 mL of H2 gas (measured at STP). Ozonolysis of compound 'X' yields only formaldehyde and dialdehyde. The total number of fragments/molecules produced from the ozonolysis of compound 'X' is _____________.
Answer
4