JEE MAIN - Chemistry (2022 - 29th June Morning Shift)

1

Production of iron in blast furnace follows the following equation

Fe3O4(s) + 4CO(g) $$\to$$ 3Fe(l) + 4CO2(g)

when 4.640 kg of Fe3O4 and 2.520 kg of CO are allowed to react then the amount of iron (in g) produced is :

[Given : Molar Atomic mass (g mol$$-$$1) : Fe = 56, Molar Atomic mass (g mol$$-$$1) : O = 16, Molar Atomic mass (g mol$$-$$1) : C = 12]

Answer
(C)
3360
2

Which of the following statements are correct?

(A) The electronic configuration of Cr is [Ar] 3d5 4s1.

(B) The magnetic quantum number may have a negative value.

(C) In the ground state of an atom, the orbitals are filled in order of their increasing energies.

(D) The total number of nodes are given by n $$-$$ 2.

Choose the most appropriate answer from the options given below :

Answer
(D)
(A), (B) and (C) only
3
The solubility of AgCl will be maximum in which of the following?
Answer
(D)
Deionised water
4
The electronic configuration of Pt (atomic number 78) is :
Answer
(A)
[Xe] 4f14 5d9 6s1
5
Two isomers 'A' and 'B' with molecular formula C4H8 give different products on oxidation with KMnO4 in acidic medium. Isomer 'A' on reaction with KMnO4/H+ results in effervescence of a gas and gives ketone. The compound 'A' is
Answer
(D)
2-methyl propene.
6

JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Haloalkanes and Haloarenes Question 73 English

In the given conversion the compound A is :

Answer
(B)
JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Haloalkanes and Haloarenes Question 73 English Option 2
7

Given below are two statements :

Statement I : The esterification of carboxylic acid with an alcohol is a nucleophilic acyl substitution.

Statement II : Electron withdrawing groups in the carboxylic acid will increase the rate of esterification reaction.

Choose the most appropriate option :

Answer
(A)
Both Statement I and Statement II are correct.
8

JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 102 English 1
JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 102 English 2

Consider the above reactions, the product A and product B respectively are

Answer
(C)
JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 102 English Option 3
9
Sugar moiety in DNA and RNA molecules respectively are
Answer
(B)
$$\beta$$-D-2-deoxyribose, $$\beta$$-D-ribose
10

Given below are two statements :

Statement I : Phenols are weakly acidic.

Statement II : Therefore they are freely soluble in NaOH solution and are weaker acids than alcohols and water.

Choose the most appropriate option :

Answer
(C)
Statement I is correct but Statement II is incorrect.
11
17.0 g of NH3 completely vapourises at $$-$$33.42$$^\circ$$C and 1 bar pressure and the enthalpy change in the process is 23.4 kJ mol$$-$$1. The enthalpy change for the vapourisation of 85 g of NH3 under the same conditions is _________ kJ.
Answer
117
12

1.2 mL of acetic acid is dissolved in water to make 2.0 L of solution. The depression in freezing point observed for this strength of acid is 0.0198$$^\circ$$C. The percentage of dissociation of the acid is ___________. (Nearest integer)

[Given : Density of acetic acid is 1.02 g mL$$-$$1, Molar mass of acetic acid is 60 g mol$$-$$1, Kf(H2O) = 1.85 K kg mol$$-$$1]

Answer
5
13

A dilute solution of sulphuric acid is electrolysed using a current of 0.10 A for 2 hours to produce hydrogen and oxygen gas. The total volume of gases produced a STP is _____________ cm3. (Nearest integer)

[Given : Faraday constant F = 96500 C mol$$-$$1 at STP, molar volume of an ideal gas is 22.7 L mol$$-$$1]

Answer
127
14

The activation energy of one of the reactions in a biochemical process is 532611 J mol$$-$$1. When the temperature falls from 310 K to 300 K, the change in rate constant observed is k300 = x $$\times$$ 10$$-$$3 k310. The value of x is ____________.

[Given : $$\ln 10 = 2.3$$, R = 8.3 J K$$-$$1 mol$$-$$1]

Answer
1
15

The number of terminal oxygen atoms present in the product B obtained from the following reaction is _____________.

FeCr2O4 + Na2CO3 + O2 $$\to$$ A + Fe2O3 + CO2

A + H+ $$\to$$ B + H2O + Na+

Answer
6
16
An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in higher oxidation state is _____________ B.M. (Nearest integer)
Answer
0
17
Kjeldahl's method was used for the estimation of nitrogen in an organic compound. The ammonia evolved from 0.55 g of the compound neutralised 12.5 mL of 1 M H2SO4 solution. The percentage of nitrogen in the compound is _____________. (Nearest integer)
Answer
64
18

Observe structures of the following compounds

JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Basics of Organic Chemistry Question 129 English

The total number of structures/compounds which possess asymmetric carbon atoms is ______________.

Answer
3
19

C6H12O6 $$\buildrel \text{Zymase} \over \longrightarrow $$ A $$\mathrel{\mathop{\kern0pt\longrightarrow} \limits_\Delta ^\text{NaOI}} $$ B + CHI3

The number of carbon atoms present in the product B is _______________.

Answer
1