JEE MAIN - Chemistry (2022 - 29th June Morning Shift)
1
Production of iron in blast furnace follows the following equation
Fe3O4(s) + 4CO(g) $$\to$$ 3Fe(l) + 4CO2(g)
when 4.640 kg of Fe3O4 and 2.520 kg of CO are allowed to react then the amount of iron (in g) produced is :
[Given : Molar Atomic mass (g mol$$-$$1) : Fe = 56, Molar Atomic mass (g mol$$-$$1) : O
= 16, Molar Atomic mass (g mol$$-$$1) : C = 12]
Answer
(C)
3360
2
Which of the following statements are correct?
(A) The electronic configuration of Cr is [Ar] 3d5 4s1.
(B) The magnetic quantum number may have a negative value.
(C) In the ground state of an atom, the orbitals are filled in order of their increasing energies.
(D) The total number of nodes are given by n $$-$$ 2.
Choose the most appropriate answer from the options given below :
Answer
(D)
(A), (B) and (C) only
3
The solubility of AgCl will be maximum in which of the following?
Answer
(D)
Deionised water
4
The electronic configuration of Pt (atomic number 78) is :
Answer
(A)
[Xe] 4f14 5d9 6s1
5
Two isomers 'A' and 'B' with molecular formula C4H8 give different products on oxidation with KMnO4 in acidic medium. Isomer 'A' on reaction with KMnO4/H+ results in effervescence of a gas and gives ketone. The compound 'A' is
Answer
(D)
2-methyl propene.
6
In the given conversion the compound A is :
Answer
(B)
7
Given below are two statements :
Statement I : The esterification of carboxylic acid with an alcohol is a nucleophilic acyl substitution.
Statement II : Electron withdrawing groups in the carboxylic acid will increase the rate of esterification reaction.
Choose the most appropriate option :
Answer
(A)
Both Statement I and Statement II are correct.
8
Consider the above reactions, the product A and product B respectively are
Answer
(C)
9
Sugar moiety in DNA and RNA molecules respectively are
Answer
(B)
$$\beta$$-D-2-deoxyribose, $$\beta$$-D-ribose
10
Given below are two statements :
Statement I : Phenols are weakly acidic.
Statement II : Therefore they are freely soluble in NaOH solution and are weaker acids than alcohols and water.
Choose the most appropriate option :
Answer
(C)
Statement I is correct but Statement II is incorrect.
11
17.0 g of NH3 completely vapourises at $$-$$33.42$$^\circ$$C and 1 bar pressure and the enthalpy change in the process is 23.4 kJ mol$$-$$1. The enthalpy change for the vapourisation of 85 g of NH3 under the same conditions is _________ kJ.
Answer
117
12
1.2 mL of acetic acid is dissolved in water to make 2.0 L of solution. The depression in freezing point observed for this strength of acid is 0.0198$$^\circ$$C. The percentage of dissociation of the acid is ___________. (Nearest integer)
[Given : Density of acetic acid is 1.02 g mL$$-$$1, Molar mass of acetic acid is 60 g mol$$-$$1, Kf(H2O) = 1.85 K kg mol$$-$$1]
Answer
5
13
A dilute solution of sulphuric acid is electrolysed using a current of 0.10 A for 2 hours to produce hydrogen and oxygen gas. The total volume of gases produced a STP is _____________ cm3. (Nearest integer)
[Given : Faraday constant F = 96500 C mol$$-$$1 at STP, molar volume of an ideal gas is 22.7 L mol$$-$$1]
Answer
127
14
The activation energy of one of the reactions in a biochemical process is 532611 J mol$$-$$1. When the temperature falls from 310 K to 300 K, the change in rate constant observed is k300 = x $$\times$$ 10$$-$$3 k310. The value of x is ____________.
The number of terminal oxygen atoms present in the product B obtained from the following reaction is _____________.
FeCr2O4 + Na2CO3 + O2 $$\to$$ A + Fe2O3 + CO2
A + H+ $$\to$$ B + H2O + Na+
Answer
6
16
An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in higher oxidation state is _____________ B.M. (Nearest integer)
Answer
0
17
Kjeldahl's method was used for the estimation of nitrogen in an organic compound. The ammonia evolved from 0.55 g of the compound neutralised 12.5 mL of 1 M H2SO4 solution. The percentage of nitrogen in the compound is _____________. (Nearest integer)
Answer
64
18
Observe structures of the following compounds
The total number of structures/compounds which possess asymmetric carbon atoms is ______________.
Answer
3
19
C6H12O6 $$\buildrel \text{Zymase} \over
\longrightarrow $$ A $$\mathrel{\mathop{\kern0pt\longrightarrow}
\limits_\Delta ^\text{NaOI}} $$ B + CHI3
The number of carbon atoms present in the product B is _______________.