JEE MAIN - Chemistry (2022 - 29th June Morning Shift - No. 3)
Explanation
The solubility of AgCl will be maximum in deionized water.
Silver chloride (AgCl) is a sparingly soluble salt. Its solubility in water can be represented by the equilibrium:
$$ \text{AgCl (s)} \rightleftharpoons \text{Ag}^+ (aq) + \text{Cl}^- (aq) $$
In the presence of a common ion, the solubility of AgCl decreases due to the common ion effect, which is explained by Le Chatelier's Principle. Here's an analysis of each option:
Option A: 0.01 M KCl
The presence of additional chloride ions ($\text{Cl}^-$) from KCl will shift the equilibrium to the left, reducing the solubility of AgCl.
Option B: 0.01 M HCl
Similar to KCl, HCl also provides more chloride ions, which will decrease the solubility of AgCl due to the common ion effect.
Option C: 0.01 M AgNO$_3$
AgNO$_3$ introduces additional silver ions ($\text{Ag}^+$) into the solution, also shifting the equilibrium to the left, hence decreasing the solubility of AgCl.
Option D: Deionized water
This option does not introduce additional ions that impact the equilibrium, so there are no additional silver or chloride ions to shift the equilibrium. As a result, the solubility of AgCl will be highest in deionized water, as there is no common ion effect.
Therefore, the solubility of AgCl is highest in deionized water.
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