JEE MAIN - Chemistry (2022 - 28th June Morning Shift)
1
Element "E" belongs to the period 4 and group 16 of the periodic table. The valence shell electron configuration of the element, which is just above "E" in the group is
Answer
(A)
3s2, 3p4
2
Nitrogen gas is obtained by thermal decomposition of :
Answer
(B)
Ba(N3)2
3
Which one of the lanthanoids given below is the most stable in divalent form?
Answer
(C)
Eu (Atomic Number 63)
4
Given below are two statements :
Statement I : [Ni(CN)4]2$$-$$ is square planar and diamagnetic complex, with dsp2 hybridization for Ni but [Ni(CO)4] is tetrahedral, paramagnetic and with sp3-hybridication for Ni.
Statement II : [NiCl4]2$$-$$ and [Ni(CO)4] both have same d-electron configuration have same geometry and are paramagnetic.
In light the above statements, choose the correct answer from the options given below :
Answer
(B)
Both Statement I and Statement II are false.
5
Which one of the following techniques is not used to spot components of a mixture separated on thin layer chromatographic plate?
Answer
(C)
Visualisation agent as a component of mobile phase
6
Which of the following structure are aromatic in nature?
Answer
(B)
Only A and B
7
The major product (P) in the reaction
is
Answer
(C)
8
The correct structure of product 'A' formed in the following reaction.
is
Answer
(A)
9
Which one of the following compounds is inactive towards SN1 reaction?
Answer
(C)
10
Identify the major product formed in the following sequence of reactions:
Answer
(C)
11
A primary aliphatic amine on reaction with nitrous acid in cold (273 K) and there after raising temperature of reaction mixture to room temperature (298 K), gives a/an
Answer
(B)
alcohol
12
Stability of $$\alpha$$-Helix structure of proteins depends upon
Answer
(B)
H-bonding interaction
13
The formula of the purple colour formed in Laissaigne's test for sulphur using sodium nitroprusside is :
Answer
(D)
Na4[Fe(CN)5(NOS)]
14
A 2.0 g sample containing MnO2 is treated with HCl liberating Cl2. The Cl2 gas is passed into a solution of KI and 60.0 mL of 0.1 M Na2S2O3 is required to titrate the liberated iodine. The percentage of MnO2 in the sample is _____________. (Nearest integer)
[Atomic masses (in u) Mn = 55; Cl = 35.5; O = 16, I = 127, Na = 23, K = 39, S = 32]
Answer
13
15
If the work function of a metal is 6.63 $$\times$$ 10$$-$$19J, the maximum wavelength of the photon required to remove a photoelectron from the metal is ____________ nm. (Nearest integer)
[Given : h = 6.63 $$\times$$ 10$$-$$34 J s, and c = 3 $$\times$$ 108 m s$$-$$1]
Answer
300
16
The hybridization of P exhibited in PF5 is spxdy. The value of y is __________.
Answer
1
17
4.0 L of an ideal gas is allowed to expand isothermally into vacuum until the total volume is 2.0 L. The amount of heat absorbed in this expansion is ____________ L atm.
Answer
0
18
The vapour pressures of two volatile liquids A and B at 25$$^\circ$$C are 50 Torr and 100 Torr, respectively. If the liquid mixture contains 0.3 mole fraction of A, then the mole fraction of liquid B in the vapour phase is $${x \over {17}}$$. The value of x is ______________.
Answer
14
19
The solubility product of a sparingly soluble salt A2X3 is 1.1 $$\times$$ 10$$-$$23. If specific conductance of the solution is 3 $$\times$$ 10$$-$$5 S m$$-$$1, the limiting molar conductivity of the solution is $$x \,\times$$ 10$$-$$3 S m2 mol$$-$$1. The value of x is ___________.
Answer
3
20
The quantity of electricity in Faraday needed to reduce 1 mol of Cr2O$$_7^{2 - }$$ to Cr3+ is ____________.
Answer
6
21
For a first order reaction A $$\to$$ B, the rate constant, k = 5.5 $$\times$$ 10$$-$$14 s$$-$$1. The time required for 67% completion of reaction is x $$\times$$ 10$$-$$1 times the half life of reaction. The value of x is _____________ (Nearest integer)
(Given : log 3 = 0.4771)
Answer
16
22
Number of complexes which will exhibit synergic bonding amongst, $$[Cr{(CO)_6}]$$, $$[Mn{(CO)_5}]$$ and $$[M{n_2}{(CO)_{10}}]$$ is ___________.
Answer
3
23
In the estimation of bromine, 0.5 g of an organic compound gave 0.40 g of silver bromide. The percentage of bromine in the given compound is _________ % (nearest integer)
(Relative atomic masses of Ag and Br are 108u and 80u, respectively).