Given below are two statements: One is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion $$\mathbf{A}$$ : Zero orbital overlap is an out of phase overlap.

Reason $$\mathbf{R}$$ : It results due to different orientation / direction of approach of orbitals.

In the light of the above statements, choose the correct answer from the options given below

Given below are two statements: One is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion A : The reduction of a metal oxide is easier if the metal formed is in liquid state than solid state.

Reason $$\mathbf{R}$$ : The value of $$\Delta G ^\Theta$$ becomes more on negative side as entropy is higher in liquid state than solid state.

In the light of the above statements, choose the most appropriate answer from the options given below

Which of the following pair is not isoelectronic species?

(At. no. Sm, 62; Er, 68; Yb, 70; Lu, 71; Eu, 63; Tb, 65; Tm, 69)

Given below are two statements : One is labelled as Assertion A and the other is labelled as Reason R

Assertion A : Permanganate titrations are not performed in presence of hydrochloric acid.

Reason R : Chlorine is formed as a consequence of oxidation of hydrochloric acid.

In the light of the above statements, choose the correct answer from the options given below

Match List I with List II

	List - I (Complex)		List - II (Hybridization)
(A)	$$Ni{(CO)_4}$$	(I)	$$s{p^3}$$
(B)	$${[Ni{(CN)_4}]^{2 - }}$$	(II)	$$s{p^3}{d^2}$$
(C)	$${[Co{(CN)_6}]^{3 - }}$$	(III)	$${d^2}s{p^3}$$
(D)	$${[Co{F_6}]^{3 - }}$$	(IV)	$$ds{p^2}$$

Choose the correct answer from the options given below :

Dinitrogen and dioxygen, the main constituents of air do not react with each other in atmosphere to form oxides of nitrogen because :

The major product in the given reaction is

Arrange the following in increasing order of reactivity towards nitration

A. p-xylene

B. bromobenzene

C. mesitylene

D. nitrobenzene

E. benzene

Choose the correct answer from the options given below

Compound I is heated with Conc. HI to give a hydroxy compound A which is further heated with Zn dust to give compound B. Identify A and B.

Given below are two statements: one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion A : Aniline on nitration yields ortho, meta & para nitro derivatives of aniline.

Reason $$\mathrm{R}$$ : Nitrating mixture is a strong acidic mixture.

In the light of the above statements, choose the correct answer from the options given below

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R

Assertion A : Thin layer chromatography is an adsorption chromatography.

Reason R : A thin layer of silica gel is spread over a glass plate of suitable size in thin layer chromatography which acts as an adsorbent.

In the light of the above statements, choose the correct answer from the options given below

The formulas of A and B for the following reaction sequence

are

Find out the major product for the above reaction.

2L of 0.2M H₂SO₄ is reacted with 2L of 0.1M NaOH solution, the molarity of the resulting product Na₂SO₄ in the solution is _________ millimolar. (Nearest integer)

If the wavelength for an electron emitted from $$\mathrm{H}$$-atom is $$3.3 \times 10^{-10} \mathrm{~m}$$, then energy absorbed by the electron in its ground state compared to minimum energy required for its escape from the atom, is _________ times. (Nearest integer)

$$\left[\right.$$ Given $$: \mathrm{h}=6.626 \times 10^{-34} \mathrm{~J} \mathrm{~s}$$ ]

Mass of electron $$=9.1 \times 10^{-31} \mathrm{~kg}$$

A gaseous mixture of two substances A and B, under a total pressure of $$0.8$$ atm is in equilibrium with an ideal liquid solution. The mole fraction of substance A is $$0.5$$ in the vapour phase and $$0.2$$ in the liquid phase. The vapour pressure of pure liquid $$\mathrm{A}$$ is __________ atm. (Nearest integer)

At $$600 \mathrm{~K}, 2 \mathrm{~mol}$$ of $$\mathrm{NO}$$ are mixed with $$1 \mathrm{~mol}$$ of $$\mathrm{O}_{2}$$.

$$2 \mathrm{NO}_{(\mathrm{g})}+\mathrm{O}_{2}(\mathrm{g}) \rightleftarrows 2 \mathrm{NO}_{2}(\mathrm{g})$$

The reaction occurring as above comes to equilibrium under a total pressure of 1 atm. Analysis of the system shows that $$0.6 \mathrm{~mol}$$ of oxygen are present at equilibrium. The equilibrium constant for the reaction is ________. (Nearest integer)

A sample of $$0.125 \mathrm{~g}$$ of an organic compound when analyzed by Duma's method yields $$22.78 \mathrm{~mL}$$ of nitrogen gas collected over $$\mathrm{KOH}$$ solution at $$280 \mathrm{~K}$$ and $$759 \mathrm{~mm}\, \mathrm{Hg}$$. The percentage of nitrogen in the given organic compound is __________. (Nearest integer)

Given :

(a) The vapour pressure of water of $$280 \mathrm{~K}$$ is $$14.2 \mathrm{~mm} \,\mathrm{Hg}$$.

(b) $$\mathrm{R}=0.082 \mathrm{~L}$$ atm $$\mathrm{K}^{-1} \mathrm{~mol}^{-1}$$

For a reaction, given below is the graph of $$\ln k$$ vs $${1 \over T}$$. The activation energy for the reaction is equal to ____________ $$\mathrm{cal} \,\mathrm{mol}^{-1}$$. (nearest integer)

(Given : $$\mathrm{R}=2 \,\mathrm{cal} \,\mathrm{K}^{-1} \,\mathrm{~mol}^{-1}$$ )

Among the following the number of state variables is ______________.

Internal energy (U)

Volume (V)

Heat (q)

Enthalpy (H)