Match List-I with List-II :

	List I (Compound)		List II (Shape)
(A)	BrF$$_5$$	(I)	bent
(B)	[CrF$$_6$$]$$^{3 - }$$	(II)	square pyramidal
(C)	O$$_3$$	(III)	trigonal bipyramidal
(D)	PCl$$_5$$	(IV)	octahedral

Choose the correct answer from the options given below :

Match List - I with List - II.

	List I (Processes / Reactions)		List II (Catalyst)
(A)	2SO$$_2$$(g) + O$$_2$$(g) $$ \to $$ 2SO$$_3$$(g)	(I)	Fe(s)
(B)	4NH$$_3$$(g) + 5O$$_2$$(g) $$ \to $$ 4NO(g) + 6H$$_2$$O(g)	(II)	Pt(s) $$ - $$ Rh(s)
(C)	N$$_2$$(g) + 3H$$_2$$(g) $$ \to $$ 2NH$$_3$$(g)	(III)	V$$_2$$O$$_5$$
(D)	Vegetable oil(l) + H$$_2$$ $$ \to $$ Vegetable ghee(s)	(IV)	Ni(s)

Choose the correct answer from the options given below :

Given two statements below :

Statement I : In $$\mathrm{Cl}_{2}$$ molecule the covalent radius is double of the atomic radius of chlorine.

Statement II : Radius of anionic species is always greater than their parent atomic radius.

Choose the most appropriate answer from options given below :

Which of the given reactions is not an example of disproportionation reaction?

The dark purple colour of $$\mathrm{KMnO}_{4}$$ disappears in the titration with oxalic acid in acidic medium. The overall change in the oxidation number of manganese in the reaction is :

$$ \stackrel{\bullet}{\mathrm{Cl}}+\mathrm{CH}_{4} \rightarrow \mathrm{A}+\mathrm{B} $$

A and B in the above atmospheric reaction step are :

Which technique among the following, is most appropriate in separation of a mixture of $$100 \,\mathrm{mg}$$ of $$p$$-nitrophenol and picric acid ?

The difference in the reaction of phenol with bromine in chloroform and bromine in water medium is due to :

Which of the following compounds is not aromatic?

The products formed in the following reaction, A and B are

Which reactant will give the following alcohol on reaction with one mole of phenyl magnesium bromide $$(\mathrm{PhMgBr})$$ followed by acidic hydrolysis?

The major product of the following reaction is

The correct stability order of the following diazonium salt is

Which one of the following is a reducing sugar?

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Experimental reaction of $$\mathrm{CH}_{3} \mathrm{Cl}$$ with aniline and anhydrous $$\mathrm{AlCl}_{3}$$ does not give $$o$$ and $$p$$-methylaniline.

Reason (R): The $$-\mathrm{NH}_{2}$$ group of aniline becomes deactivating because of salt formation with anhydrous $$\mathrm{AlCl}_{3}$$ and hence yields $$m$$-methyl aniline as the product.

In the light of the above statements, choose the most appropriate answer from the options given below :

Chlorophyll extracted from the crushed green leaves was dissolved in water to make $$2 \mathrm{~L}$$ solution of Mg of concentration $$48\, \mathrm{ppm}$$. The number of atoms of $$\mathrm{Mg}$$ in this solution is $$x \times 10^{20}$$ atoms. The value of $$x$$ is ___________. (Nearest Integer)

(Given : Atomic mass of $$\mathrm{Mg}$$ is $$24 \mathrm{~g} \mathrm{~mol}^{-1} ; \mathrm{N}_{\mathrm{A}}=6.02 \times 10^{23} \mathrm{~mol}^{-1}$$ )

The wavelength of an electron and a neutron will become equal when the velocity of the electron is $$x$$ times the velocity of neutron. The value of $$x$$ is ____________. (Nearest Integer)

(Mass of electron is $$9.1 \times 10^{-31} \mathrm{~kg}$$ and mass of neutron is $$1.6 \times 10^{-27} \mathrm{~kg}$$ )

$$2.4 \mathrm{~g}$$ coal is burnt in a bomb calorimeter in excess of oxygen at $$298 \mathrm{~K}$$ and $$1 \mathrm{~atm}$$ pressure. The temperature of the calorimeter rises from $$298 \mathrm{~K}$$ to $$300 \mathrm{~K}$$. The enthalpy change during the combustion of coal is $$-x \mathrm{~kJ} \mathrm{~mol}^{-1}$$. The value of $$x$$ is ___________. (Nearest Integer)

(Given : Heat capacity of bomb calorimeter $$20.0 \mathrm{~kJ} \mathrm{~K}^{-1}$$. Assume coal to be pure carbon)

When 800 mL of 0.5 M nitric acid is heated in a beaker, its volume is reduced to half and 11.5 g of nitric acid is evaporated. The molarity of the remaining nitric acid solution is x $$\times$$ 10^$$-$$2 M. (Nearest integer)

(Molar mass of nitric acid is 63 g mol^$$-$$1)

At $$298 \mathrm{~K}$$, the equilibrium constant is $$2 \times 10^{15}$$ for the reaction :

$$\mathrm{Cu}(\mathrm{s})+2 \mathrm{Ag}^{+}(\mathrm{aq}) \rightleftharpoons \mathrm{Cu}^{2+}(\mathrm{aq})+2 \mathrm{Ag}(\mathrm{s})$$

The equilibrium constant for the reaction

$$ \frac{1}{2} \mathrm{Cu}^{2+}(\mathrm{aq})+\mathrm{Ag}(\mathrm{s}) \rightleftharpoons \frac{1}{2} \mathrm{Cu}(\mathrm{s})+\mathrm{Ag}^{+}(\mathrm{aq}) $$

is $$x \times 10^{-8}$$. The value of $$x$$ is _____________. (Nearest Integer)

The amount of charge in $$\mathrm{F}$$ (Faraday) required to obtain one mole of iron from $$\mathrm{Fe}_{3} \mathrm{O}_{4}$$ is ___________. (Nearest Integer)

For a reaction $$\mathrm{A} \rightarrow 2 \mathrm{~B}+\mathrm{C}$$ the half lives are $$100 \mathrm{~s}$$ and $$50 \mathrm{~s}$$ when the concentration of reactant $$\mathrm{A}$$ is $$0.5$$ and $$1.0 \mathrm{~mol} \mathrm{~L}^{-1}$$ respectively. The order of the reaction is ______________ . (Nearest Integer)

The difference between spin only magnetic moment values of $$\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]\mathrm{Cl}_{2}$$ and $$\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}$$ is ___________.

In the presence of sunlight, benzene reacts with Cl₂ to give product, X. The number of hydrogens in X is _____________.