JEE MAIN - Chemistry (2022 - 25th June Morning Shift)
1
Bonding in which of the following diatomic molecule(s) become(s) stronger, on the basis of MO Theory, by removal of an electron?
(A) NO
(B) N2
(C) O2
(D) C2
(E) B2
Choose the most appropriate answer from the options given below :
Answer
(C)
(A), (C) only
2
The pair, in which ions are isoelectronic with AI3+ is :
Answer
(D)
O2$$-$$ and Mg2+
3
Number of electron deficient molecules among the following
PH3, B2H6, CCl4, NH3, LiH and BCl3 is
Answer
(C)
2
4
White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of :
Answer
(C)
[Ag(NH3)2]Cl
5
Cerium (IV) has a noble gas configuration. Which of the following is correct statement about it?
Answer
(B)
It will prefer to gain electron and act as an oxidizing agent.
6
Among the following, which is the strongest oxidizing agent?
Answer
(A)
Mn3+
7
Phenol on reaction with dilute nitric acid, gives two products. Which method will be most efficient for large scale separation?
Answer
(C)
Steam distillation
8
In the following structures, which on is having staggered conformation with maximum dihedral angle?
Answer
(C)
9
The product formed in the following reaction.
Answer
(B)
10
The IUPAC name of ethylidene chloride is :
Answer
(D)
1,1-Dichloroethane
11
The major product in the reaction
Answer
(D)
2-Methyl prop-1-ene
12
The intermediate X, in the reaction :
Answer
(C)
13
In the following reaction :
The compounds A and B respectively are :
Answer
(C)
14
The reaction of with bromine and KOH gives RNH2 as the end product. Which one of the following is the intermediate product formed in this reation?
Answer
(C)
R $$-$$ N = C = O
15
The number of N atoms in 681 g of C7H5N3O6 is x $$\times$$ 1021. The value of x is (NA = 6.02 $$\times$$ 1023 mol$$-$$1) (Nearest Integer)
Answer
5418
16
The longest wavelength of light that can be used for the ionisation of lithium atom (Li) in its ground state is x $$\times$$ 10$$-$$8 m. The value of x is ___________. (Nearest Integer).
(Given : Energy of the electron in the first shell of the hydrogen atom is $$-$$2.2 $$\times$$ 10$$-$$18 J ; h = 6.63 $$\times$$ 10$$-$$34 Js and c = 3 $$\times$$ 108 ms$$-$$1)
Answer
4
17
The standard entropy change for the reaction
4Fe(s) + 3O2(g) $$\to$$ 2Fe2O3(s) is $$-$$550 J K$$-$$1 at 298 K.
[Given : The standard enthalpy change for the reaction is $$-$$165 kJ mol$$-$$1]. The temperature in K at which the reaction attains equilibrium is _____________. (Nearest Integer)
Answer
300
18
1 L aqueous solution of H2SO4 contains 0.02 m mol H2SO4. 50% of this solution is diluted with deionized water to give 1 L solution (A). In solution (A), 0.01 m mol of H2SO4 are added. Total m mols of H2SO4 in the final solution is ___________ $$\times$$ 103 m mols.
Answer
0
19
The standard free energy change ($$\Delta$$G$$^\circ$$) for 50% dissociation of N2O4 into NO2 at 27$$^\circ$$C and 1 atm pressure is $$-$$ x J mol$$-$$1. The value of x is ___________. (Nearest Integer)
The standard electrode potential for the spontaneous reaction in the cell is x $$\times$$ 10$$-$$2 V 298 K. The value of x is ____________. (Nearest Integer)
Concentration of C changes from 10 mmol dm$$-$$3 to 20 mmol dm$$-$$3 in 10 seconds. Rate of appearance of D is 1.5 times the rate of disappearance of B which is twice the rate of disappearance A. The rate of appearance of D has been experimentally determined to be 9 mmol dm$$-$$3 s$$-$$1. Therefore, the rate of reaction is _____________ mmol dm$$-$$3 s$$-$$1. (Nearest Integer)
Answer
1
22
If [Cu(H2O)4]2+ absorbs a light of wavelength 600 nm for d-d transition, then the value of octahedral crystal field splitting energy for [Cu(H2O)6]2+ will be ____________ $$\times$$ 10$$-$$21 J. [Nearest Integer]
(Given : h = 6.63 $$\times$$ 10$$-$$34 Js and c = 3.08 $$\times$$ 108 ms$$-$$1)
Answer
766
23
Number of grams of bromine that will completely react with 5.0 g of pent-1-ene is ___________ $$\times$$ 10$$-$$2 g. (Atomic mass of Br = 80 g/mol) [Nearest Integer]