Consider the following pairs of electrons
(A) (a) n = 3, $$l$$ = 1, m1 = 1, ms = + $${1 \over 2}$$
(b) n = 3, 1 = 2, m1 = 1, ms = + $${1 \over 2}$$
(B) (a) n = 3, $$l$$ = 2, m1 = $$-$$2, ms = $$-$$$${1 \over 2}$$
(b) n = 3, $$l$$ = 2, m1 = $$-$$1, ms = $$-$$$${1 \over 2}$$
(C) (a) n = 4, $$l$$ = 2, m1 = 2, ms = + $${1 \over 2}$$
(b) n = 3, $$l$$ = 2, m1 = 2, ms = + $${1 \over 2}$$
The pairs of electrons present in degenerate orbitals is/are :
Match List - I with List - II :
List - I | List -II | ||
---|---|---|---|
(A) | $${[PtC{l_4}]^{2 - }}$$ | (I) | $$s{p^3}d$$ |
(B) | $$Br{F_5}$$ | (II) | $${d^2}s{p^3}$$ |
(C) | $$PC{l_5}$$ | (III) | $$ds{p^2}$$ |
(D) | $${[Co{(N{H_3})_6}]^{3 + }}$$ | (IV) | $$s{p^3}{d^2}$$ |
Choose the most appropriate answer from the options given below :
For a reaction at equilibrium
A(g) $$\rightleftharpoons$$ B(g) + $${1 \over 2}$$ C(g)
the relation between dissociation constant (K), degree of dissociation ($$\alpha$$) and equilibrium pressure (p) is given by :
Two statements are given below :
Statement I : The melting point of monocarboxylic acid with even number of carbon atoms is higher than that of with odd number of carbon atoms acid immediately below and above it in the series.
Statement II : The solubility of monocarboxylic acids in water decreases with increase in molar mass.
Choose the most appropriate option :
The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient intravenously, it has to be isotonic with blood. The concentration of glucose solution in gL$$-$$1 is _____________.
(Molar mass of glucose = 180 g mol$$-$$1, R = 0.083 L bar K$$-$$1 mol$$-$$1) (Nearest integer)
The rate constants for decomposition of acetaldehyde have been measured over the temperature range 700 - 1000 K. The data has been analysed by plotting ln k vs $${{{{10}^3}} \over T}$$ graph. The value of activation energy for the reaction is ___________ kJ mol$$-$$1. (Nearest integer)
(Given : R = 8.31 J K$$-$$1 mol$$-$$1)