JEE MAIN - Chemistry (2021 - 27th July Morning Shift)

1
Which one of the following compounds will give orange precipitate when treated with 2, 4-dinitrophenyl hydrazine?
Answer
(D)
JEE Main 2021 (Online) 27th July Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 117 English Option 4
2
The oxidation states of 'P' in H4P2O7, H4P2O5 and H4P2O6, respectively, are :
Answer
(C)
5, 3 and 4
3
For a reaction of order n, the unit of the rate constant is :
Answer
(C)
mol1$$-$$n Ln$$-$$1 s$$-$$1
4
Given below are two statements :

Statement I : Aniline is less basic than acetamide.

Statement II : In aniline, the lone pair of electrons on nitrogen atom is delocalized over benzene ring due to resonance and hence less available to a proton.

Choose the most appropriate option;
Answer
(B)
Statement I is false but statement II is true.
5
The type of hybridisation and magnetic property of the complex [MnCl6]3$$-$$, respectively, are :
Answer
(D)
sp3d2 and paramagnetic
6
The number of geometrical isomers found in the metal
complexes [PtCl2(NH3)2], [Ni(CO)4], [Ru(H2O)3Cl3 and [CoCl2(NH3)4]+ respectively, are :
Answer
(C)
2, 0, 2, 2
7
Presence of which reagent will affect the reversibility of the following reaction, and change it to a irreversible reaction :

CH4 + I2 $$\mathrel{\mathop{\kern0pt\rightleftharpoons} \limits_{{\mathop{\rm Re}\nolimits} versible}^{hv}} $$ CH3 $$-$$ I + HI
Answer
(D)
Concentrated HIO3
8
Which one among the following chemical tests is used to distinguish monosaccharide from disaccharide?
Answer
(C)
Barfoed test
9

Consider the above reaction and identify the Product P :
Answer
(D)
JEE Main 2021 (Online) 27th July Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 95 English Option 4
10
JEE Main 2021 (Online) 27th July Morning Shift Chemistry - Biomolecules Question 90 English
The compound 'A' is a complementary base of _______________ in DNA stands.
Answer
(C)
Adenine
11
Staggered and eclipsed conformers of ethane are :
Answer
(B)
Rotamers
12
Match List - I with List - II :

List - I List - II
(a) NaOH (i) Acidic
(b) $$Be{(OH)_2}$$ (ii) Basic
(c) $$Ca{(OH)_2}$$ (iii) Amphoteric
(d) $$B{(OH)_3}$$
(e) $$Al{(OH)_3}$$


Choose the most appropriate answer from the options given below
Answer
(B)
(a)-(ii), (b)-(iii), (c)-(ii), (d)-(i), (e)-(iii)
13
JEE Main 2021 (Online) 27th July Morning Shift Chemistry - Basics of Organic Chemistry Question 139 English
The correct order of stability of given carbocation is :
Answer
(A)
A > C > B > D
14
The density of NaOH solution is 1.2 g cm$$-$$3. The molality of this solution is _____________ m. (Round off to the Nearest Integer)

[Use : Atomic mass : Na : 23.0 u, O : 16.0 u, H : 1.0 u, Density of H2O : 1.0 g cm$$-$$3]
Answer
5
15
The conductivity of a weak acid HA of concentration 0.001 mol L$$-$$1 is 2.0 $$\times$$ 10$$-$$5 S cm$$-$$1. If $$\Lambda _m^o$$(HA) = 190 S cm2 mol$$-$$1, the ionization constant (Ka) of HA is equal to ______________ $$\times$$ 10$$-$$6. (Round off to the Nearest Integer)
Answer
12
16
1.46 g of a biopolymer dissolved in a 100 mL water at 300 K exerted an osmotic pressure of 2.42 $$\times$$ 10$$-$$3 bar.

The molar mass of the biopolymer is _____________ $$\times$$ 104 g mol$$-$$1. (Round off to the Nearest Integer)

[Use : R = 0.083 L bar mol$$-$$1 K$$-$$1]
Answer
15
17
An organic compound is subjected to chlorination to get compound A using 5.0 g of chlorine. When 0.5 g of compound A is reacted with AgNO3 [Carius Method], the percentage of chlorine in compound A is ____________ when it forms 0.3849 g of AgCl. (Round off to the Nearest Integer)

(Atomic masses of Ag and Cl are 107.87 and 35.5 respectively)
Answer
19
18
The number of geometrical isomers possible in triamminetrinitrocobalt (III) is X and in trioxalatochromate (III) is Y. Then the value of X + Y is _______________.
Answer
2
19
In gaseous triethyl amine the "$$-$$C$$-$$N$$-$$C$$-$$" bond angle is _________ degree.
Answer
108
20
For water at 100$$^\circ$$ C and 1 bar,

$$\Delta$$vap H $$-$$ $$\Delta$$vap U = _____________ $$\times$$ 102 J mol$$-$$1. (Round off to the Nearest Integer)

[Use : R = 8.31 J mol$$-$$1 K$$-$$1]

[Assume volume of H2O(l) is much smaller than volume of H2O(g). Assume H2O(g) treated as an ideal gas]
Answer
31
21
PCl5 $$\rightleftharpoons$$ PCl3 + Cl2

Kc = 1.844

3.0 moles of PCl5 is introduced in a 1 L closed reaction vessel at 380 K. The number of moles of PCl5 at equilibrium is ______________ $$\times$$ 10$$-$$3. (Round off to the Nearest Integer)
Answer
1400
22
The difference between bond orders of CO and NO$$^ \oplus $$ is $${x \over 2}$$ where x = _____________. (Round off to the Nearest Integer)
Answer
0