JEE MAIN - Chemistry (2021 - 27th August Evening Shift)

1
The addition of dilute NaOH to Cr3+ salt solution will give :
Answer
(B)
precipitate of Cr2O3(H2O)n
2
Given below are two statements :

Statement I : Ethyl pent-4-yn-oate on reaction with CH3MgBr gives a 3$$^\circ$$-alcohol.

Statement II : In this reaction one mole of ethyl pent-4-yn-oate utilizes two moles of CH3MgBr.

In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(C)
Statement I is true but Statement II is false.
3
The compound/s which will show significant intermolecular H-bonding is/are :

Answer
(A)
(b) only
4
Which one of the following reactions will not yield propionic acid?
Answer
(D)
CH3CH2CH2Br + Mg, CO2 dry ether/H3O+
5
The correct order of ionic radii for the ions, P3$$-$$, S2$$-$$, Ca2+, K+, Cl$$-$$ is :
Answer
(A)
P3$$-$$ > S2$$-$$ > Cl$$-$$ > K+ > Ca2+
6
Which one of the following is the major product of the given reaction?

Answer
(A)
JEE Main 2021 (Online) 27th August Evening Shift Chemistry - Compounds Containing Nitrogen Question 109 English Option 1
7
The major product (A) formed in the reaction given below is :

Answer
(B)
JEE Main 2021 (Online) 27th August Evening Shift Chemistry - Haloalkanes and Haloarenes Question 77 English Option 2
8
The major product of the following reaction, if it occurs by SN2 mechanism is :

JEE Main 2021 (Online) 27th August Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 88 English
Answer
(D)
JEE Main 2021 (Online) 27th August Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 88 English Option 4
9
Potassium permanganate on heating at 513 K gives a product which is :
Answer
(D)
paramagnetic and green
10
Which one of the following tests used for the identification of functional groups in organic compounds does not use copper reagent?
Answer
(B)
Seliwanoff's test
11
Hydrolysis of sucrose gives :
Answer
(D)
$$\alpha$$-D-(+)-Glucose and $$\beta$$-D-($$-$$)-Fructose
12
The correct structures of A and B formed in the following reactions are :

JEE Main 2021 (Online) 27th August Evening Shift Chemistry - Compounds Containing Nitrogen Question 110 English
Answer
(D)
JEE Main 2021 (Online) 27th August Evening Shift Chemistry - Compounds Containing Nitrogen Question 110 English Option 4
13
The first order rate constant for the decomposition of CaCO3 at 700 K is 6.36 $$\times$$ 10$$-$$3s$$-$$1 and activation energy is 209 kJ mol$$-$$1. Its rate constant (in s$$-$$1) at 600 K is x $$\times$$ 10$$-$$6. The value of x is ___________. (Nearest integer)

[Given R = 8.31 J K$$-$$ mol$$-$$1; log 6.36 $$\times$$ 10$$-$$3 = $$-$$2.19, 10$$-$$4.79 = 1.62 $$\times$$ 10$$-$$5]
Answer
16
14
The number of optical isomers possible for [Cr(C2O4)3]3$$-$$ is ____________.
Answer
2
15
Two flasks I and II shown below are connected by a valve of negligible volume.

JEE Main 2021 (Online) 27th August Evening Shift Chemistry - Thermodynamics Question 90 English
When the valve is opened, the final pressure of the system in bar is x $$\times$$ 10$$-$$2. The value of x is __________. (Integer answer)

[Assume - Ideal gas; 1 bar = 105 Pa; Molar mass of N2 = 28.0 g mol$$-$$1; R = 8.31 J mol$$-$$1 K$$-$$1]
Answer
84
16
100 g of propane is completely reacted with 1000 g of oxygen. The mole fraction of carbon dioxide in the resulting mixture is x $$\times$$ 10$$-$$2. The value of x is ____________. (Nearest integer)

[Atomic weight : H = 1.008; C = 12.00; O = 16.00]
Answer
19
17
40 g of glucose (Molar mass = 180) is mixed with 200 mL of water. The freezing point of solution is __________ K. (Nearest integer) [Given : Kf = 1.86 K kg mol$$-$$1; Density of water = 1.00 g cm$$-$$3; Freezing point of water = 273.15 K]
Answer
271
18
The resistance of a conductivity cell with cell constant 1.14 cm$$-$$1, containing 0.001 M KCl at 298 K is 1500 $$\Omega$$. The molar conductivity of 0.001 M KCl solution at 298 K in S cm2 mol$$-$$1 is ____________. (Integer answer)
Answer
760
19
The number of photons emitted by a monochromatic (single frequency) infrared range finder of power 1 mW and wavelength of 1000 nm, in 0.1 second is x $$\times$$ 1013. The value of x is _____________. (Nearest integer)

(h = 6.63 $$\times$$ 10$$-$$34 Js, c = 3.00 $$\times$$ 108 ms$$-$$1)
Answer
50
20
When 5.1 g of solid NH4HS is introduced into a two litre evacuated flask at 27$$^\circ$$C, 20% of the solid decomposes into gaseous ammonia and hydrogen sulphide. The Kp for the reaction at 27$$^\circ$$C is x $$\times$$ 10$$-$$2. The value of x is _____________. (Integer answer) [Given R = 0.082 L atm K$$-$$1 mol$$-$$]
Answer
6
21
The number of species having non-pyramidal shape among the following is ___________.

(A) SO3

(B) NO$$_3^ - $$

(C) PCl3

(D) CO$$_3^{2 - }$$
Answer
3
22
Data given for the following reaction is as follows :

FeO(s) + C(graphite) $$\to$$ Fe(s) + CO(g)

Substance $$\Delta H^\circ $$
(kJ mol$$^{ - 1}$$)
$$\Delta S^\circ $$
(J mol$$^{ - 1}$$ K$$^{ - 1}$$)
$$Fe{O_{(s)}}$$ $$ - 266.3$$ 57.49
$${C_{(graphite)}}$$ 0 5.74
$$F{e_{(s)}}$$ 0 27.28
$$C{O_{(g)}}$$ $$ - 110.5$$ 197.6


The minimum temperature in K at which the reaction becomes spontaneous is ___________. (Integer answer)
Answer
964