JEE MAIN - Chemistry (2021 - 26th August Evening Shift)

1
Which one of the following phenols does not give colour when condensed with phthalic anhydride in presence of conc. H2SO4 ?
Answer
(B)
JEE Main 2021 (Online) 26th August Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 91 English Option 2
2
The bond order and magnetic behaviour of $$O_2^ - $$ ion are respectively :
Answer
(A)
1.5 and paramagnetic
3
Given below are two statements : one is labelled as Assertion (A) and other is labelled as Reason (R).

Assertion (A) : Sucrose is a disaccharide and a non-reducing sugar.

Reason (R) : Sucrose involves glycosidic linkage between C1 of $$\beta$$-glucose and C2 of $$\alpha$$-fructose.

Choose the most appropriate answer from the options given below :
Answer
(C)
(A) is true but (R) is false.
4
Match List - I with List - II :


Choose the most appropriate match :
Answer
(C)
a-ii, b-iii, c-iv, d-i
5
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Barium carbonate is insoluble in water and is highly stable.

Reason (R) : The thermal stability of the carbonates increases with increasing cationic size.
Answer
(A)
Both (A) and (R) are true and (R) is the true explanation of (A)
6
JEE Main 2021 (Online) 26th August Evening Shift Chemistry - Compounds Containing Nitrogen Question 115 English
The major product in the above reaction is :
Answer
(D)
JEE Main 2021 (Online) 26th August Evening Shift Chemistry - Compounds Containing Nitrogen Question 115 English Option 4
7
Indicate the complex/complex ion which did not show any geometrical isomerism :
Answer
(B)
[Co(CN)5(NC)]3$$-$$
8
Arrange the following Cobalt complexes in the order of increasing Crystal Field Stabilization Energy (CFSE) value.

Complexes : $$\mathop {{{[Co{F_6}]}^{3 - }}}\limits_A ,\mathop {{{[Co{{({H_2}O)}_6}]}^{2 + }}}\limits_B ,\mathop {{{[Co{{(N{H_3})}_6}]}^{3 + }}}\limits_C and \mathop {{{[Co{{({en})}_3}]}^{3 + }}}\limits_D $$

Choose the correct option :
Answer
(B)
B < A < C < D
9
Which one of the following compounds is not aromatic?
Answer
(C)
JEE Main 2021 (Online) 26th August Evening Shift Chemistry - Basics of Organic Chemistry Question 135 English Option 3
10
The number of stereoisomers possible for 1, 2-dimethyl cyclopropane is :
Answer
(D)
Three
11

Consider the given reaction, identify 'X' and 'Y' :
Answer
(C)
JEE Main 2021 (Online) 26th August Evening Shift Chemistry - Compounds Containing Nitrogen Question 114 English Option 3
12

Consider the given reaction, the product A is :
Answer
(C)
JEE Main 2021 (Online) 26th August Evening Shift Chemistry - Haloalkanes and Haloarenes Question 80 English Option 3
13
In the sulphur estimation, 0.471 g of an organic compound gave 1.44 g of barium sulphate. The percentage of sulphur in the compound is ____________%. (Nearest integer)

(Atomic Mass of Ba = 137 u)
Answer
42
14
The equilibrium constant Kc at 298 K for the reaction A + B $$\rightleftharpoons$$ C + D is 100. Starting with an equimolar solution with concentrations of A, B, C and D all equal to 1M, the equilibrium concentration of D is ___________ $$\times$$ 10$$-$$2 M. (Nearest integer)
Answer
182
15
For water $$\Delta$$vap H = 41 kJ mol$$-$$1 at 373 K and 1 bar pressure. Assuming that water vapour is an ideal gas that occupies a much larger volume than liquid water, the internal energy change during evaporation of water is ___________ kJ mol$$-$$1

[Use : R = 8.3 J mol$$-$$1 K$$-$$1]
Answer
38
16
A metal surface is exposed to 500 nm radiation. The threshold frequency of the metal for photoelectric current is 4.3 $$\times$$ 1014 Hz. The velocity of ejected electron is ____________ $$\times$$ 105 ms$$-$$1 (Nearest integer)

[Use : h = 6.63 $$\times$$ 10$$-$$34 Js, me = 9.0 $$\times$$ 10$$-$$31 kg]
Answer
5
17
For the galvanic cell,

Zn(s) + Cu2+ (0.02 M) $$\to$$ Zn2+ (0.04 M) + Cu(s),

Ecell = ______________ $$\times$$ 10$$-$$2 V. (Nearest integer)

[Use : $$E_{Cu/C{u^{2 + }}}^0$$ = $$-$$ 0.34 V, $$E_{Zn/Z{n^{2 + }}}^0$$ = + 0.76 V, $${{2.303RT} \over F} = 0.059\,V$$]
Answer
109
18
100 mL of Na3PO4 solution contains 3.45 g of sodium. The molarity of the solution is _____________ $$\times$$ 10$$-$$2 mol L$$-$$1. (Nearest integer)

[Atomic Masses - Na : 23.0 u, O : 16.0 u, P : 31.0 u]
Answer
50
19
The overall stability constant of the complex ion [Cu(NH3)4]2+ is 2.1 $$\times$$ 1013. The overall dissociations constant is y $$\times$$ 10$$-$$14. Then y is __________. (Nearest integer)
Answer
5
20
83 g of ethylene glycol dissolved in 625 g of water. The freezing point of the solution is ____________ K. (Nearest integer)

[Use : Molal Freezing point depression constant of water = 1.86 K kg mol$$-$$1]

Freezing Point of water = 273 K

Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u]
Answer
269
21
The reaction rate for the reaction

[PtCl4]2$$-$$ + H2O $$\rightleftharpoons$$ [Pt(H2O)Cl3]$$-$$ + Cl$$-$$

was measured as a function of concentrations of different species. It was observed that $${{ - d\left[ {{{\left[ {PtC{l_4}} \right]}^{2 - }}} \right]} \over {dt}} = 4.8 \times {10^{ - 5}}\left[ {{{\left[ {PtC{l_4}} \right]}^{2 - }}} \right] - 2.4 \times {10^{ - 3}}\left[ {{{\left[ {Pt({H_2}O)C{l_3}} \right]}^ - }} \right]\left[ {C{l^ - }} \right]$$.

where square brackets are used to denote molar concentrations. The equilibrium constant Kc = ____________ . (Nearest integer)
Answer
0
22
A chloro compound "A".

(i) forms aldehydes on ozonolysis followed by the hydrolysis.

(ii) when vaporized completely 1.53 g of A, gives 448 mL of vapour at STP.

The number of carbon atoms in a molecule of compound A is ___________.
Answer
3