JEE MAIN - Chemistry (2021 - 22th July Evening Shift)

1
Which one of the following statements for D.I. Mendeleeff, is incorrect?
Answer
(B)
At the time, he proposed Periodic Table of elements structure of atom was known.
2
Which purification technique is used for high boiling organic liquid compound (decomposes near its boiling point)?
Answer
(D)
Reduced pressure distillation
3
Which of the following compounds will provide a tertiary alcohol or reaction with excess of CH3MgBr followed by hydrolysis?
Answer
(A)
JEE Main 2021 (Online) 22th July Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 97 English Option 1
4
Which of the following compounds does not exhibit resonance?
Answer
(D)
CH3CH2CH = CHCH2NH2
5

In the chemical reactions given above A and B respectively are :
Answer
(A)
H3PO2 and CH3CH2Cl
6
Isotope(s) of hydrogen which emits low energy $$\beta$$$$-$$ particles with t1/2 value > 12 years is/are
Answer
(B)
Tritium
7
Match List-I with List-II :

List-I
(Species)
List-II
(Hybrid Orbitals)
(a) $$S{F_4}$$ (i) $$s{p^3}{d^2}$$
(b) $$I{F_5}$$ (ii) $${d^2}s{p^3}$$
(c) $$NO_2^ + $$ (iii) $$s{p^3}d$$
(d) $$NH_4^ + $$ (iv) $$s{p^3}$$
(v) $$sp$$


Choose the correct answer from the options given below :
Answer
(C)
(a)-(iii), (b)-(i), (c)-(v) and (d)-(iv)
8
Which of the following molecules does not show stereo isomerism?
Answer
(C)
3-Ethylhex-3-ene
9
Which one of the following group-15 hydride is the strongest reducing agent?
Answer
(B)
BiH3
10
The set having ions which are coloured and paramagnetic both is :
Answer
(A)
Cu2+, Cr3+, Sc+
11
Thiamine and pyridoxine are also known respectively as :
Answer
(D)
Vitamin B1 and Vitamin B6
12
An organic compound A (C6H6O) gives dark green colouration with ferric chloride. On treatment with CHCl3 and KOH, followed by acidification gives compound B. Compound B can also be obtained from compound C on reaction with pyridinium chlorochromate (PCC). Identify A, B and C.
Answer
(A)
13
Which one of the following reactions does not occur?
Answer
(C)
JEE Main 2021 (Online) 22th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 127 English Option 3
14
Which one of the following 0.06 M aqueous solutions has lowest freezing point?
Answer
(A)
Al2(SO4)3
15
The total number of unpaired electrons present in [Co(NH3)6]Cl2 and [Co(NH3)6]Cl3 is :
Answer
3
16
Methylation of 10 g of benzene gave 9.2 g of toluene. Calculate the percentage yield of toluene __________. (Nearest integer)
Answer
78
17
The number of acyclic structural isomers (including geometrical isomers) for pentene are ___________
Answer
6
18
Assume a cell with the following reaction

$$C{u_{(s)}} + 2A{g^ + }(1 \times {10^{ - 3}}M) \to C{u^{2 + }}(0.250M) + 2A{g_{(s)}}$$

$$E_{cell}^\Theta = 2.97$$ V

Ecell for the above reaction is ______________ V. (Nearest integer)

[Given : log 2.5 = 0.3979, T = 298 K]
Answer
3
19
Value of KP for the equilibrium reaction

N2O4(g) $$\rightleftharpoons$$ 2NO2(g) at 288 K is 47.9. The KC for this reaction at same temperature is ____________. (Nearest integer)

(R = 0.083 L bar K$$-$$1 mol$$-$$1)
Answer
2
20
If the standard molar enthalpy change for combustion of graphite powder is $$-$$2.48 $$\times$$ 102 kJ mol$$-$$1, the amount of heat generated on combustion of 1 g of graphite powder is ___________ kJ. (Nearest integer)
Answer
21
21
Number of electrons that Vanadium (Z = 23) has in p-orbitals is equal to _____________
Answer
12
22
$${N_2}{O_{5(g)}} \to 2N{O_{2(g)}} + {1 \over 2}{O_{2(g)}}$$

In the above first order reaction the initial concentration of N2O5 is 2.40 $$\times$$ 10$$-$$2 mol L$$-$$1 at 318 K. The concentration of N2O5 after 1 hour was 1.60 $$\times$$ 10$$-$$2 mol L$$-$$1. The rate constant of the reaction at 318 K is ______________ $$\times$$ 10$$-$$3 min$$-$$1. (Nearest integer)

[Given : log 3 = 0.477, log 5 = 0.699]
Answer
7
23
If the concentration of glucose (C6H12O6) in blood is 0.72 g L$$-$$1, the molarity of glucose in blood is ____________ $$\times$$ 10$$-$$3 M. (Nearest integer)

[Given : Atomic mass of C = 12, H = 1, O = 16 u]
Answer
4