The Crystal Field Stabilization Energy (CFSE) and magnetic moment (spin-only) of an octahedral aqua complex of a metal ion (Mz+) are $$-$$0.8 $$\Delta$$0 and 3.87 BM, respectively. Identify (Mz+) :
Answer
(D)
Co2+
6
Which one of the following compounds is aromatic in nature?
Answer
A
D
7
In the given chemical reaction, colors of the Fe2+ and Fe3+ ions, are respectively :
The stereoisomers that are formed by electrophilic addition of bromine to trans-but-2-ene is/are :
Answer
(B)
2 identical mesomers
9
In the following sequence of reactions,
The compounds B and C respectively are :-
Answer
(D)
CHI3, CH3COOK
10
Given below are two statements :
Statement I : The nucleophilic addition of sodium hydrogen sulphite to an aldehyde or a ketone involves proton transfer to form a stable ion.
Statement II : The nucleophilic addition of hydrogen cyanide to an aldehyde or a ketone yields amine as final product.
In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(B)
Statement I is true but Statement II is false.
11
Which one of the following gives the most stable Diazonium salt?
Answer
(B)
12
The potassium ferrocyanide solution gives a Prussian blue colour, when added to :
Answer
(D)
FeCl3
13
Number of paramagnetic oxides among the following given oxides is ____________.
Li2O, CaO, Na2O2, KO2, MgO and K2O
Answer
(A)
1
14
Identify the element for which electronic configuration in +3 oxidation state is [Ar]3d5 :
Answer
(D)
Fe
15
The molar solubility of Zn(OH)2 in 0.1 M NaOH solution is x $$\times$$ 10$$-$$18 M. The value of x is _________ (Nearest integer)
(Given : The solubility product of Zn(OH)2 is 2 $$\times$$ 10$$-$$20)
Answer
2
16
For the reaction, 2NO2(g) $$\rightleftharpoons$$ N2O4(g), when $$\Delta$$S = $$-$$176.0 JK$$-$$1 and $$\Delta$$H = $$-$$57.8 kJ mol$$-$$1, the magnitude of $$\Delta$$G at 298 K for the reaction is ___________ kJ mol$$-$$1. (Nearest integer)
Answer
5
17
The sum of oxidation states of two silver ions in [Ag(NH3)2] [Ag(CN)2] complex is _____________.
Answer
2
18
The number of atoms in 8g of sodium is x $$\times$$ 1023. The value of x is ____________. (Nearest integer)
[Given : NA = 6.02 $$\times$$ 1023 mol$$-$$1
Atomic mass of Na = 23.0 u]
Answer
2
19
If 80 g of copper sulphate CuSO4 . 5H2O is dissolved in deionised water to make 5L of solution. The concentration of the copper sulphate solution is x $$\times$$ 10$$-$$3 mol L$$-$$1. The value of x is _____________.
[Atomic masses Cu : 63.54u, S : 32u, O : 16u, H : 1u]
Answer
64
20
A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The number of photons emitted per second by the bulb is x $$\times$$ 1020. The value of x is __________. [Given : h = 6.63 $$\times$$ 10$$-$$34 Js and c = 3.0 $$\times$$ 108 ms$$-$$1]
Answer
2
21
The spin-only magnetic moment value of $$B_2^ + $$ species is _____________ $$\times$$ 10$$-$$2 BM. (Nearest integer) [Given : $$\sqrt 3 $$ = 1.73]
Answer
173
22
If the conductivity of mercury at 0$$^\circ$$C is 1.07 $$\times$$ 106 S m$$-$$1 and the resistance of a cell containing mercury is 0.243$$\Omega$$, then the cell constant of the cell is x $$\times$$ 104 m$$-$$1. The value of x is ____________. (Nearest integer)
Answer
26
23
A peptide synthesized by the reactions of one molecule each of Glycine, Leucine, Aspartic acid and Histidine will have _________ peptide linkages.