JEE MAIN - Chemistry (2021 - 1st September Evening Shift)

1
Experimentally reducing a functional group cannot be done by which one of the following reagents?
Answer
(B)
Na/H2
2
Which one of the following given graphs represents the variation of rate constant (k) with temperature (T) for an endothermic reaction?
Answer
(A)
JEE Main 2021 (Online) 1st September Evening Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 81 English Option 1
3
Identify A in the following reaction.

JEE Main 2021 (Online) 1st September Evening Shift Chemistry - Compounds Containing Nitrogen Question 103 English
Answer
(A)
JEE Main 2021 (Online) 1st September Evening Shift Chemistry - Compounds Containing Nitrogen Question 103 English Option 1
4
In the following sequence of reactions a compound A, (molecular formula C6H12O2) with a straight chain structure gives a C4 carboxylic acid. A is :

JEE Main 2021 (Online) 1st September Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 106 English
Answer
(C)
$$C{H_3} - C{H_2} - C{H_2} - COO - C{H_2} - C{H_3}$$
5
The Crystal Field Stabilization Energy (CFSE) and magnetic moment (spin-only) of an octahedral aqua complex of a metal ion (Mz+) are $$-$$0.8 $$\Delta$$0 and 3.87 BM, respectively. Identify (Mz+) :
Answer
(D)
Co2+
6
Which one of the following compounds is aromatic in nature?
Answer
A
D
7
In the given chemical reaction, colors of the Fe2+ and Fe3+ ions, are respectively :

5Fe2+ + MnO$$_4^ - $$ + 8H+ $$\to$$ Mn2+ + 4H2O + 5Fe3+
Answer
(D)
Green, Yellow
8
The stereoisomers that are formed by electrophilic addition of bromine to trans-but-2-ene is/are :
Answer
(B)
2 identical mesomers
9
In the following sequence of reactions,

JEE Main 2021 (Online) 1st September Evening Shift Chemistry - Haloalkanes and Haloarenes Question 74 English
The compounds B and C respectively are :-
Answer
(D)
CHI3, CH3COOK
10
Given below are two statements :

Statement I : The nucleophilic addition of sodium hydrogen sulphite to an aldehyde or a ketone involves proton transfer to form a stable ion.

Statement II : The nucleophilic addition of hydrogen cyanide to an aldehyde or a ketone yields amine as final product.

In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(B)
Statement I is true but Statement II is false.
11
Which one of the following gives the most stable Diazonium salt?
Answer
(B)
JEE Main 2021 (Online) 1st September Evening Shift Chemistry - Compounds Containing Nitrogen Question 106 English Option 2
12
The potassium ferrocyanide solution gives a Prussian blue colour, when added to :
Answer
(D)
FeCl3
13
Number of paramagnetic oxides among the following given oxides is ____________.

Li2O, CaO, Na2O2, KO2, MgO and K2O
Answer
(A)
1
14
Identify the element for which electronic configuration in +3 oxidation state is [Ar]3d5 :
Answer
(D)
Fe
15
The molar solubility of Zn(OH)2 in 0.1 M NaOH solution is x $$\times$$ 10$$-$$18 M. The value of x is _________ (Nearest integer)

(Given : The solubility product of Zn(OH)2 is 2 $$\times$$ 10$$-$$20)
Answer
2
16
For the reaction, 2NO2(g) $$\rightleftharpoons$$ N2O4(g), when $$\Delta$$S = $$-$$176.0 JK$$-$$1 and $$\Delta$$H = $$-$$57.8 kJ mol$$-$$1, the magnitude of $$\Delta$$G at 298 K for the reaction is ___________ kJ mol$$-$$1. (Nearest integer)
Answer
5
17
The sum of oxidation states of two silver ions in [Ag(NH3)2] [Ag(CN)2] complex is _____________.
Answer
2
18
The number of atoms in 8g of sodium is x $$\times$$ 1023. The value of x is ____________. (Nearest integer)

[Given : NA = 6.02 $$\times$$ 1023 mol$$-$$1

Atomic mass of Na = 23.0 u]
Answer
2
19
If 80 g of copper sulphate CuSO4 . 5H2O is dissolved in deionised water to make 5L of solution. The concentration of the copper sulphate solution is x $$\times$$ 10$$-$$3 mol L$$-$$1. The value of x is _____________.

[Atomic masses Cu : 63.54u, S : 32u, O : 16u, H : 1u]
Answer
64
20
A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The number of photons emitted per second by the bulb is x $$\times$$ 1020. The value of x is __________. [Given : h = 6.63 $$\times$$ 10$$-$$34 Js and c = 3.0 $$\times$$ 108 ms$$-$$1]
Answer
2
21
The spin-only magnetic moment value of $$B_2^ + $$ species is _____________ $$\times$$ 10$$-$$2 BM. (Nearest integer) [Given : $$\sqrt 3 $$ = 1.73]
Answer
173
22
If the conductivity of mercury at 0$$^\circ$$C is 1.07 $$\times$$ 106 S m$$-$$1 and the resistance of a cell containing mercury is 0.243$$\Omega$$, then the cell constant of the cell is x $$\times$$ 104 m$$-$$1. The value of x is ____________. (Nearest integer)
Answer
26
23
A peptide synthesized by the reactions of one molecule each of Glycine, Leucine, Aspartic acid and Histidine will have _________ peptide linkages.
Answer
3