JEE MAIN - Chemistry (2021 - 17th March Morning Shift)
1
The absolute value of the electron gain enthalpy of halogens satisfies :
Answer
(B)
Cl > F > Br > I
2
What is the spin-only magnetic moment value (BM) of a divalent metal ion with atomic number 25, in it's aqueous solution?
Answer
(D)
5.92
3
Hoffmann bromomide degradation of benzamide gives product A, which upon heating with CHCl3 and NaOH gives product B.
The structures of A and B are :
Answer
(A)
4
The above reaction requires which of the following reaction conditions?
Answer
(B)
623 K, 300 atm
5
The product ''A'' in the above reaction is :
Answer
(D)
6
Product ''A'' in the above chemical reaction is :
Answer
(B)
7
Which of the following compound CANNOT act as a Lewis base?
Answer
(D)
PCl5
8
Given below are two statements :
Statement I : Potassium permanganate on heating at 573K forms potassium manganate.
Statement II : Both potassium permanganate and potassium manganate are tetrahedral and paramagnetic in nature.
In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(A)
Statement I is true but statement II is false
9
Mesityl oxide is a common name of :
Answer
(B)
4-Methyl pent-3-en-2-one
10
Which of the following is an aromatic compound?
Answer
(A)
11
A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The shape of this molecule is :
Answer
(B)
T-shaped
12
Given below are two statements :
Statement I : Retardation factor (Rf) can be measured in meter/centimeter.
Statement II : Rf value of a compound remains constant in all solvents.
Choose the most appropriate answer from the options given below :
Answer
(D)
Both statement I and statement II are false
13
Which of the following is correct structure of tyrosine?
Answer
(D)
14
Which of the following reaction is an example of ammonolysis?
Answer
(D)
C6H5CH2Cl + NH3 $$ \to $$ C6H5CH2NH2
15
A certain orbital has n = 4 and mL = $$-$$3. The number of radial nodes in this orbital is ____________. (Round off to the Nearest Integer).
Answer
0
16
15 mL of aqueous solution of Fe2+ in acidic medium completely reacted with 20 mL of 0.03 M aqueous Cr2O$$_7^{2 - }$$. The molarity of the Fe2+ solution is __________ $$\times$$ 10-2 M. (Round off to the Nearest Integer).
Answer
24
17
In the above reaction, 3.9 g of benzene on nitration gives 4.92 g of nitrobenzene. The percentage yield of nitrobenzene in the above reaction is ________%. (Round off to the Nearest Integer).
(Given atomic mass : C : 12.0 u, H : 1.0 u, O : 16.0 u, N : 14.0 u)
Answer
80
18
For a certain first order reaction 32% of the reactant is left after 570s. The rate constant of this reaction is _________ $$\times$$ 10$$-$$3 s$$-$$1. (Round off to the Nearest Integer). [Given : log102 = 0.301, ln10 = 2.303]
Answer
2
19
0.01 moles of a weak acid HA (Ka = 2.0 $$\times$$ 10$$-$$6) is dissolved in 1.0 L of 0.1 M HCl solution. The degree of dissociation of HA is __________ $$\times$$ 10$$-$$5 (Round off to the Nearest Integer).
[Neglect volume change on adding HA. Assume degree of dissociation <<1 ]
Answer
2
20
The mole fraction of a solute in a 100 molal aqueous solution is ___________ $$\times$$ 10$$-$$2. (Round off to the Nearest Integer).
[Given : Atomic masses : H : 1.0 u, O : 16.0 u ]
Answer
64
21
The standard enthalpies of formation of Al2O3 and CaO are $$-$$1675 kJ mol-1 and $$-$$635 kJ mol$$-$$1 respectively.
For the reaction
3CaO + 2Al $$ \to $$ 3Ca + Al2O3 the standard reaction enthalpy $$\Delta$$rH0 = _________ kJ.
(Round off to the Nearest Integer)
Answer
230
22
The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above water. The molar solubility of oxygen in water is __________ $$\times$$ 10$$-$$5 mol dm$$-$$3. (Round off to the Nearest Integer).
[Given : Henry's law constant = KH = 8.0 $$\times$$ 104 kPa for O2. Density of water with dissolved oxygen = 1.0 kg dm$$-$$3 ]