JEE MAIN - Chemistry (2021 - 17th March Morning Shift)

1
The absolute value of the electron gain enthalpy of halogens satisfies :
Answer
(B)
Cl > F > Br > I
2
What is the spin-only magnetic moment value (BM) of a divalent metal ion with atomic number 25, in it's aqueous solution?
Answer
(D)
5.92
3
Hoffmann bromomide degradation of benzamide gives product A, which upon heating with CHCl3 and NaOH gives product B.

The structures of A and B are :
Answer
(A)
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Compounds Containing Nitrogen Question 139 English Option 1
4
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Haloalkanes and Haloarenes Question 90 English
The above reaction requires which of the following reaction conditions?
Answer
(B)
623 K, 300 atm
5
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 131 English
The product ''A'' in the above reaction is :
Answer
(D)
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 131 English Option 4
6
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Haloalkanes and Haloarenes Question 91 English
Product ''A'' in the above chemical reaction is :
Answer
(B)
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Haloalkanes and Haloarenes Question 91 English Option 2
7
Which of the following compound CANNOT act as a Lewis base?
Answer
(D)
PCl5
8
Given below are two statements :

Statement I : Potassium permanganate on heating at 573K forms potassium manganate.

Statement II : Both potassium permanganate and potassium manganate are tetrahedral and paramagnetic in nature.

In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(A)
Statement I is true but statement II is false
9
Mesityl oxide is a common name of :
Answer
(B)
4-Methyl pent-3-en-2-one
10
Which of the following is an aromatic compound?
Answer
(A)
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Basics of Organic Chemistry Question 154 English Option 1
11
A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The shape of this molecule is :
Answer
(B)
T-shaped
12
Given below are two statements :

Statement I : Retardation factor (Rf) can be measured in meter/centimeter.

Statement II : Rf value of a compound remains constant in all solvents.

Choose the most appropriate answer from the options given below :
Answer
(D)
Both statement I and statement II are false
13
Which of the following is correct structure of tyrosine?
Answer
(D)
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Biomolecules Question 101 English Option 4
14
Which of the following reaction is an example of ammonolysis?
Answer
(D)
C6H5CH2Cl + NH3 $$ \to $$ C6H5CH2NH2
15
A certain orbital has n = 4 and mL = $$-$$3. The number of radial nodes in this orbital is ____________. (Round off to the Nearest Integer).
Answer
0
16
15 mL of aqueous solution of Fe2+ in acidic medium completely reacted with 20 mL of 0.03 M aqueous Cr2O$$_7^{2 - }$$. The molarity of the Fe2+ solution is __________ $$\times$$ 10-2 M. (Round off to the Nearest Integer).
Answer
24
17
JEE Main 2021 (Online) 17th March Morning Shift Chemistry - Practical Organic Chemistry Question 57 English
In the above reaction, 3.9 g of benzene on nitration gives 4.92 g of nitrobenzene. The percentage yield of nitrobenzene in the above reaction is ________%. (Round off to the Nearest Integer).

(Given atomic mass : C : 12.0 u, H : 1.0 u, O : 16.0 u, N : 14.0 u)
Answer
80
18
For a certain first order reaction 32% of the reactant is left after 570s. The rate constant of this reaction is _________ $$\times$$ 10$$-$$3 s$$-$$1. (Round off to the Nearest Integer). [Given : log102 = 0.301, ln10 = 2.303]
Answer
2
19
0.01 moles of a weak acid HA (Ka = 2.0 $$\times$$ 10$$-$$6) is dissolved in 1.0 L of 0.1 M HCl solution. The degree of dissociation of HA is __________ $$\times$$ 10$$-$$5 (Round off to the Nearest Integer).

[Neglect volume change on adding HA. Assume degree of dissociation <<1 ]
Answer
2
20
The mole fraction of a solute in a 100 molal aqueous solution is ___________ $$\times$$ 10$$-$$2. (Round off to the Nearest Integer).

[Given : Atomic masses : H : 1.0 u, O : 16.0 u ]
Answer
64
21
The standard enthalpies of formation of Al2O3 and CaO are $$-$$1675 kJ mol-1 and $$-$$635 kJ mol$$-$$1 respectively.

For the reaction

3CaO + 2Al $$ \to $$ 3Ca + Al2O3 the standard reaction enthalpy $$\Delta$$rH0 = _________ kJ.

(Round off to the Nearest Integer)
Answer
230
22
The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above water. The molar solubility of oxygen in water is __________ $$\times$$ 10$$-$$5 mol dm$$-$$3. (Round off to the Nearest Integer).

[Given : Henry's law constant = KH = 8.0 $$\times$$ 104 kPa for O2. Density of water with dissolved oxygen = 1.0 kg dm$$-$$3 ]
Answer
25