JEE MAIN - Chemistry (2020 - 9th January Evening Slot)

1
In the following reaction A is : JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 166 English
Answer
(B)
JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 166 English Option 2
2
Which of the following reactions will not produce a racemic product?
Answer
(C)
JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Haloalkanes and Haloarenes Question 111 English Option 3
3
The first and second ionisation enthalpies of a metal are 496 and 4560 kJ mol–1, respectively. How many moles of HCl and H2SO4, respectively, will be needed to react completely with 1 mole of the metal hydroxide ?
Answer
(B)
1 and 0.5
4
A, B and C are three biomolecules. The results of the tests performed on them are given below:

$$ \begin{array}{|l|l|l|l|} \hline & \begin{array}{l} \text { Molisch's } \\ \text { Test } \end{array} & \begin{array}{l} \text { Barfoed } \\ \text { Test } \end{array} & \begin{array}{l} \text { Biuret } \\ \text { Test } \end{array} \\ \hline \text { A } & \text { Positive } & \text { Negative } & \text { Negative } \\ \hline \text { B } & \text { Positive } & \text { Positive } & \text { Negative } \\ \hline \text { C } & \text { Negative } & \text { Negative } & \text { Positive } \\ \hline \end{array} $$

A, B and C are respectively :
Answer
(A)
A = Lactose, B = Glucose, C = Albumin
5
Consider the following reactions

JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 165 English
The mass percentage of carbon in A is ______.
Answer
66.66TO66.67
6
10.30 mg of O2 is dissolved into a liter of sea water of density 1.03 g/mL. The concentration of O2 in ppm is__________.
Answer
10
7
The sum of the total number of bonds between chromium and oxygen atoms in chromate and dichromate ions is ____________.
Answer
18
8
A sample of milk splits after 60 min. at 300 K and after 40 min. at 400 K when the population of lactobacillus acidophilus in it doubles. The activa tion energy (in kJ/ mol) for this process is closest to__________.

(Given, R = 8.3 J mol–1 K–1, $$\ln \left( {{3 \over 2}} \right) = 0.4$$, e–3 = 4.0)
Answer
3.98TO3.99
9
A cylinder containing an ideal gas (0.1 mol of 1.0 dm3) is in thermal equilibrium with a large volume of 0.5 molal aqueous solution of ethylene glycol at its freezing point. If the stoppers S1 and S2 (as shown in the figure) are suddenly withdrawn, the volume of the gas in litres after equilibrium is achieved will be____.

(Given, Kf (water) = 2.0 K kg mol–1,
R = 0.08 dm3 atm K–1 mol–1)

JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Solutions Question 103 English
Answer
2.17TO2.23
10
The true statement amongst the following is :
Answer
(C)
Both $$\Delta $$S and S are functions of temperature.
11
The number of sp2 hybrid orbitals in a molecule of benzene is :
Answer
(D)
18
12
The isomer(s) of [Co(NH3)4Cl2] that has/have a Cl–Co–Cl angle of 90°, is/are :
Answer
(A)
cis only
13
The reaction of H3N3B3Cl3 (A) with LiBH4 in tetrahydrofuran gives inorganic benzene (B). Further, the reaction of (A) with (C) leads to H3N3B3(Me)3. Compounds (B) and (C) respectively, are :
Answer
(D)
Borazine and MeMgBr
14
Consider the following reactions,

JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 163 English
The compound [P] is :
Answer
(B)
JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 163 English Option 2
15
5 g of zinc is treated separately with an excess of

(a) dilute hydrochloric acid and
(b) aqueous sodium hydroxide.

The ratio of the volumes of H2 evolved in these two reactions is :
Answer
(B)
1 : 1
16
The solubility product of Cr(OH)3 at 298 K is 6.0 × 10–31. The concentration of hydroxide ions in a saturated solution of Cr(OH)3 will be :
Answer
(C)
(18 × 10–31)1/4
17
The decreasing order of basicity of the following amines is : JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 164 English 1 JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 164 English 2 JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 164 English 3 JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 164 English 4
Answer
(A)
(III) > (II) > (I) > (IV)
18
In the figure shown below reactant A (represented by square) is in equilibrium with product B (represented by circle). The equilibrium constant is : JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Chemical Equilibrium Question 68 English
Answer
(B)
2
19
Which of the following has the shortest C-Cl bond?
Answer
(B)
Cl–CH=CH–NO2
20
The correct order of the spin-only magnetic moments of the following complexes is :
(I) [Cr(H2O)6]Br2
(II) Na4[Fe(CN)6]
(III) Na3[Fe(C2O4)3] ($$\Delta $$0 $$>$$ P)
(IV) (Et4N)2[CoCl4]
Answer
(D)
(I) > (IV) > (III) > (II)