JEE MAIN - Chemistry (2019 - 9th January Evening Slot)

1
The increasing basicity order of the following compounds is :
JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Basics of Organic Chemistry Question 194 English
Answer
(B)
D < C < A < B
2
Which of the following compounds is not aromatic ?
Answer
(A)
JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Basics of Organic Chemistry Question 195 English Option 1
3
The tests performed on compound X and their inferences are :

Test Inference
(a) 2, 4 - DNP test Coloured precipitate
(b) Idoform test Yellow precipitate
(c) Azo-dye test No dye formation

Compound 'X' is :
Answer
(B)
JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Practical Organic Chemistry Question 73 English Option 2
4
The products formed in the reaction of cumene with O2 followed by treatment with dil. HCl are :
Answer
(C)
JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 197 English Option 3
5
The correct sequence of amino acids present in the tripeptide given below is :

JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Biomolecules Question 140 English
Answer
(A)
Val - Ser - Thr
6
Consider the following reversible chemical reactions :

JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Chemical Equilibrium Question 78 English

The relation between K1 and K2 is :
Answer
(C)
K2 = K1$$-$$3
7
The major product of the following reaction is :

JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 198 English
Answer
(D)
JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 198 English Option 4
8
The major product obtained in the following reaction is :

JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 189 English
Answer
(D)
JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 189 English Option 4
9
The major product of the following reaction is :

JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 188 English
Answer
(C)
JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Compounds Containing Nitrogen Question 188 English Option 3
10
The major product in the following reaction is :

JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 199 English
Answer
(C)
JEE Main 2019 (Online) 9th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 199 English Option 3
11
If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the reaction

Zn(s) + Cu2+ (aq) $$\rightleftharpoons$$ Zn2+(aq) + Cu(s)

at 300 K is approximately,

(R = 8 JK$$-$$1mol$$-$$1, F = 96000 C mol$$-$$1)
Answer
(D)
e160
12
Homoleptic octahedral complexes of a metal ion 'M3+' with three monodenate ligands L1, L2 and L3 adsorb wavelenths in the region of green, blue and red respectively. The increasing order of the ligands strength is :
Answer
(A)
L3 < L1 < L2
13
A solution containing 62 g ethylene glycol in 250 g water is cooled to $$-$$ 10oC. If Kf for water is 1.86 K kg mol$$-$$1 , the amount of water (in g) separated as ice is :
Answer
(C)
64
14
The transition element that has lowest enthalpy of atomisation, is :
Answer
(B)
Cu
15
When the first electron gain enthalpy $$\left( {{\Delta _{eg}}H} \right)$$ of oxygen is $$-$$ 141 kJ/mol, its second electron gain enthalpy is :
Answer
(D)
a positive value
16
In which of the following process, the bond order has increased and paramagnetic character has charged to diamagnetic ?
Answer
(A)
NO $$ \to $$ NO+
17
Which of the following combination of statements is true regarding the interpretation of the atomic orbitals ?

(a) An electron in an orbital of high angular momentum stays away from the nucleus than an electron in the orbital of lower angular momentum.

(b) For a given value of the principal quantum number, the size of the orbit is inversely proportional to the azimuthal quantum number.

(c) According to wave mechanics, the ground state angular momentum is equal to $${h \over {2\pi }}$$.

(d) The plot of $$\psi $$ vs r for various azimuthal quantum numbers, shows peak shifting towards higher r value.
Answer
(B)
(a), (d)
18
For the reaction, 2A + B $$ \to $$ products, when the concentrations of A and B both were doubled, the rate of the reaction increased from 0.3 mol L$$-$$1s$$-$$1 to 2.4 mol L$$-$$1s$$-$$1. When the concentration of A alone is doubled, the rate increased from 0.3 mol L$$-$$1s$$-$$1 to 0.6 mol L$$-$$1s$$-$$1.
Answer
(B)
Order of the reaction with respect to B is 2
19
The pH of rain water, is approximately :
Answer
(A)
5.6
20
The complex that has highest crystal field splitting energy ($$\Delta $$), is :
Answer
(D)
K3[Co(CN)6]
21
The correct match between Item I and Item II is :

Item - I Item - II
(A) Benzaldehyde (P) Mobile phase
(B) Alumina (Q) Adsorbent
(C) Acetonitrile (R) Adsorbate
Answer
(B)
(A) $$ \to $$ (R); (B) $$ \to $$ (Q); (C) $$ \to $$ (P)
22
For the following reaction, in the mass of water produced from 445 g of C57H110O6 is :

2C57H110O6(s) + 163 O2(g) $$ \to $$ 114 CO2(g) + 110 H2O(l)
Answer
(C)
495 g
23
The entropy change associated with the conversion of 1 kg of ice at 273 K to water vapours at 383 K is :

(Specific heat of water liquid and water vapour are 4.2 kJ K$$-$$1 kg$$-$$1 and 2.0 kJ K$$-$$1 kg$$-$$1; heat of liquid fusion and vapourisation of water are 334 kJ$$-$$1 and 2491 kJ kg$$-$$1, respectively). (log 273 = 2.436, log 373 = 2.572, log 383 = 2.583)
Answer
(D)
9.26 kJ kg$$-$$1 K$$-$$1