JEE MAIN - Chemistry (2019 - 11th January Evening Slot)

1
Which of the following compounds will produce a precipitate with AgNO3 ?
Answer
(B)
JEE Main 2019 (Online) 11th January Evening Slot Chemistry - Haloalkanes and Haloarenes Question 128 English Option 2
2
In the following compound,

JEE Main 2019 (Online) 11th January Evening Slot Chemistry - Basics of Organic Chemistry Question 190 English

the favourable site/s for protonation is/are :
Answer
(A)
(b), (c) and (d)
3
The major product obtained in the following conversion is JEE Main 2019 (Online) 11th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 189 English
Answer
(A)
JEE Main 2019 (Online) 11th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 189 English Option 1
4
Which of the following compounds reacts with ethylmagnesium bromide and also decolourizes bromine water solution:
Answer
B
C
5
The major product of the following reaction is :

JEE Main 2019 (Online) 11th January Evening Slot Chemistry - Alcohols, Phenols and Ethers Question 132 English
Answer
(B)
JEE Main 2019 (Online) 11th January Evening Slot Chemistry - Alcohols, Phenols and Ethers Question 132 English Option 2
6
The major product obtained in the following reaction is :

JEE Main 2019 (Online) 11th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 190 English
Answer
(D)
JEE Main 2019 (Online) 11th January Evening Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 190 English Option 4
7
The coordination number of Th in K4[Th(C2O4)4(OH2)2] is :
(C2O$${_4^{2 - }}$$ = Oxalato)
Answer
(B)
10
8
The correct match between Item I and Item II is :

Item I Item II
(A) Ester test (P) Tyr
(B) Carbylamine test (Q) Asp
(C) Phthalein dye test
(R) Ser
(S) Lys
Answer
(A)
(A)$$ \to $$(Q); (B)$$ \to $$(S); (C)$$ \to $$(P)
9
For the equilibrium,
2H2O $$\rightleftharpoons$$ H3O+ + OH$$-$$, the value of $$\Delta $$Go at 298 K is approximately :
Answer
(D)
80 kJ mol–1
10
25 ml of the given HCl solution requires 30 mL of 0.1 M sodium carbonate solution. What is the volume of this HCl solution required to titrate 30 mL of 0.2 M aqueous NaOH solutions ?
Answer
(C)
25 mL
11
Given the equilibrium constant:

KC of the reaction :

Cu(s) + 2Ag+ (aq) $$ \to $$ Cu2+ (aq) + 2Ag(s) is

10 $$ \times $$ 1015, calculate the E$$_{cell}^0$$ of this reaciton at 298 K

[2.303 $${{RT} \over F}$$ at 298 K = 0.059V]
Answer
(C)
0.4736 V
12
The number of bridging CO ligand(s) and Co-Co bond(s) in Co2(CO)8, respectively are :
Answer
(D)
2 and 1
13
The reaction 2X $$ \to $$ B is a zeroth order reaction. If the initial concentration of X is 0.2 M, the half-life is 6 h. When the initial concentration of X is 0.5 M, the time required to reach its final concentration of 0.2 M will be:
Answer
(A)
18.0 h
14
A compound 'X' on treatment with Br2/NaOH, provided C3H9N, which gives positive carbylamine test. Compound 'X' is :
Answer
(A)
CH3CH2CH2CONH2
15
The standard reaction Gibbs energy for a chemical reaction at an absolute temperature T is given by $$\Delta $$rGo = A – BT

Where A and B are non-zero constants. Which of the following is TRUE about this reaction?
Answer
(B)
Endothermic if A > 0
16
$$\underline A \,\,\buildrel {4KOH,{O_2}} \over \longrightarrow \,\,\mathop {2\underline B }\limits_{\left( {Green} \right)} \,\, + \,\,2{H_2}O$$

$$3\underline B \,\,\buildrel {4HCl} \over \longrightarrow \,\,\mathop {2\underline C }\limits_{\left( {Purple} \right)} \,\, + \,\,Mn{O_2} + 2{H_2}O$$

$$2\underline C \,\,\buildrel {{H_2}O.KI} \over \longrightarrow \,\,\mathop {2\underline A }\limits_{\left( {Purple} \right)} \,\, + \,\,2KOH\,\, + \,\,\underline D $$

In the above sequence of reactions, $${\underline A }$$ and $${\underline D }$$, respectively, are :
Answer
(D)
MnO2 and KlO3
17
The reaction, MgO(s) + C(s) $$ \to $$ Mg(s) + CO(g), for which $$\Delta $$rHo + 491.1 kJ mol–1 and $$\Delta $$rSo = 198.0 JK–1 mol–1, is not feasible at 298 K. Temperature above which reaciton will be feasible is :
Answer
(A)
2480.3 K
18
The de Broglie wavelength ($$\lambda $$) associated with a photoelectron varies with the frequency (v) of the incident radiation as, [v0 is threshold frequency] :
Answer
(D)
$$\lambda \,\infty \,{1 \over {{{\left( {v - {v_0}} \right)}^{{1 \over 2}}}}}$$
19
K2Hgl4 is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is:
Answer
(D)
1.8
20
The correct option with respect to the Pauling electronegativity values of the element is :
Answer
(A)
Ga < Ge