JEE MAIN - Chemistry (2024 - 4th April Evening Shift)

1

Fuel cell, using hydrogen and oxygen as fuels,

A. has been used in spaceship

B. has as efficiency of $$40 \%$$ to produce electricity

C. uses aluminum as catalysts

D. is eco-friendly

E. is actually a type of Galvanic cell only

Choose the correct answer from the options given below:

Answer
(A)
A, D, E only
2

Match List I with List II

LIST I LIST II
A. $$\alpha$$ - Glucose and $$\alpha$$ - Galactose I. Functional isomers
B. $$
\alpha \text { - Glucose and } \beta \text { - Glucose }
$$
II. Homologous
C. $$
\alpha \text { - Glucose and } \alpha \text { - Fructose }
$$
III. Anomers
D. $$
\alpha \text { - Glucose and } \alpha \text { - Ribose }
$$
IV. Epimers

Choose the correct answer from the options given below:

Answer
(B)
A-IV, B-III, C-I, D-II
3
If an iron (III) complex with the formula $$\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_x(\mathrm{CN})_y\right]^-$$ has no electron in its $$e_g$$ orbital, then the value of $$x+y$$ is
Answer
(A)
6
4
The number of unpaired d-electrons in $$\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$$ is ________.
Answer
(A)
0
5

Correct order of stability of carbanion is :

JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Basics of Organic Chemistry Question 34 English

Answer
(A)
d > c > b > a
6

JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 16 English

Product P is

Answer
(D)
JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 16 English Option 4
7
The correct order of the first ionization enthalpy is
Answer
(B)
$$\mathrm{Tl}>\mathrm{Ga}>\mathrm{Al}$$
8

Given below are two statements :

Statement I : The correct order of first ionization enthalpy values of $$\mathrm{Li}, \mathrm{Na}, \mathrm{F}$$ and $$\mathrm{Cl}$$ is $$\mathrm{Na}<\mathrm{Li}<\mathrm{Cl}<\mathrm{F}$$.

Statement II : The correct order of negative electron gain enthalpy values of $$\mathrm{Li}, \mathrm{Na}, \mathrm{F}$$ and $$\mathrm{Cl}$$ is $$\mathrm{Na}<\mathrm{Li}<\mathrm{F}<\mathrm{Cl}$$

In the light of the above statements, choose the correct answer from the options given below :

Answer
(D)
Both Statement I and Statement II are true
9
For a strong electrolyte, a plot of molar conductivity against (concentration) $${ }^{1 / 2}$$ is a straight line, with a negative slope, the correct unit for the slope is
Answer
(D)
$$\mathrm{S} \mathrm{cm}^2 \mathrm{~mol}^{-3 / 2} \mathrm{~L}^{1 / 2}$$
10
When $$\mathrm{MnO}_2$$ and $$\mathrm{H}_2 \mathrm{SO}_4$$ is added to a salt $$(\mathrm{A})$$, the greenish yellow gas liberated as salt (A) is :
Answer
(A)
$$\mathrm{NH}_4 \mathrm{Cl}$$
11

The correct statement/s about Hydrogen bonding is/are

A. Hydrogen bonding exists when H is covalently bonded to the highly electro negative atom.

B. Intermolecular H bonding is present in $$o$$-nitro phenol

C. Intramolecular $$\mathrm{H}$$ bonding is present in HF.

D. The magnitude of $$\mathrm{H}$$ bonding depends on the physical state of the compound.

E. H-bonding has powerful effect on the structure and properties of compounds

Choose the correct answer from the options given below:

Answer
(C)
A, D, E only
12
Choose the Incorrect Statement about Dalton's Atomic Theory
Answer
(A)
Compounds are formed when atoms of different elements combine in any ratio.
13

$$\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{Br}+\mathrm{NaOH} \xrightarrow{\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}} \text { Product 'A' }$$

JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 17 English

Consider the above reactions, identify product B and product C.

Answer
(D)
$$\mathrm{B}=2$$-Propanol $$\mathrm{C}=1$$-Propanol
14

The number of species from the following that have pyramidal geometry around the central atom is _________

$$\mathrm{S}_2 \mathrm{O}_3^{2-}, \mathrm{SO}_4^{2-}, \mathrm{SO}_3^{2-}, \mathrm{S}_2 \mathrm{O}_7^{2-}$$

Answer
(D)
1
15
A first row transition metal in its +2 oxidation state has a spin-only magnetic moment value of $$3.86 \mathrm{~BM}$$. The atomic number of the metal is
Answer
(B)
23
16
Common name of Benzene - 1,2 - diol is -
Answer
(A)
catechol
17

The equilibrium constant for the reaction

$$\mathrm{SO}_3(\mathrm{~g}) \rightleftharpoons \mathrm{SO}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g})$$

is $$\mathrm{K}_{\mathrm{c}}=4.9 \times 10^{-2}$$. The value of $$\mathrm{K}_{\mathrm{c}}$$ for the reaction given below is $$2 \mathrm{SO}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{SO}_3(\mathrm{~g})$$ is :

Answer
(B)
416
18

Find out the major product formed from the following reaction. $$[\mathrm{Me}:-\mathrm{CH}_3]$$

JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 18 English

Answer
(A)
JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 18 English Option 1
19

The adsorbent used in adsorption chromatography is/are -

A. silica gel

B. alumina

C. quick lime

D. magnesia

Choose the most appropriate answer from the options given below :

Answer
(D)
A and B only
20

JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Hydrocarbons Question 21 English

In the above chemical reaction sequence "$$\mathrm{A}$$" and "$$\mathrm{B}$$" respectively are

Answer
(D)
$$\mathrm{O}_3, \mathrm{Zn} / \mathrm{H}_2 \mathrm{O}$$ and $$\mathrm{NaOH}_{(\mathrm{alc})} / \mathrm{I}_2$$
21
The maximum number of orbitals which can be identified with $$\mathrm{n}=4$$ and $$m_l=0$$ is _________.
Answer
4
22

Number of compounds / species from the following with non-zero dipole moment is _________.

$$\mathrm{BeCl}_2, \mathrm{BCl}_3, \mathrm{NF}_3, \mathrm{XeF}_4, \mathrm{CCl}_4, \mathrm{H}_2 \mathrm{O}, \mathrm{H}_2 \mathrm{~S}, \mathrm{HBr}, \mathrm{CO}_2, \mathrm{H}_2, \mathrm{HCl}$$

Answer
5
23
The total number of 'sigma' and 'pi' bonds in 2-oxohex-4-ynoic acid is ______.
Answer
18
24
From $$6.55 \mathrm{~g}$$ of aniline, the maximum amount of acetanilide that can be prepared will be ________ $$\times 10^{-1} \mathrm{~g}$$.
Answer
95
25

$$2.7 \mathrm{~kg}$$ of each of water and acetic acid are mixed. The freezing point of the solution will be $$-x^{\circ} \mathrm{C}$$. Consider the acetic acid does not dimerise in water, nor dissociates in water. $$x=$$ ________ (nearest integer)

[Given: Molar mass of water $$=18 \mathrm{~g} \mathrm{~mol}^{-1}$$, acetic acid $$=60 \mathrm{~g} \mathrm{~mol}^{-1}$$

$${ }^{\mathrm{K}_{\mathrm{f}}} \mathrm{H}_2 \mathrm{O}: 1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$

$$\mathrm{K}_{\mathrm{f}}$$ acetic acid: $$3.90 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$

freezing point: $$\mathrm{H}_2 \mathrm{O}=273 \mathrm{~K}$$, acetic acid $$=290 \mathrm{~K}$$]

Answer
31
26

Consider the following reaction, the rate expression of which is given below

$$\begin{aligned} & \mathrm{A}+\mathrm{B} \rightarrow \mathrm{C} \\ & \text { rate }=\mathrm{k}[\mathrm{A}]^{1 / 2}[\mathrm{~B}]^{1 / 2} \end{aligned}$$

The reaction is initiated by taking $$1 \mathrm{~M}$$ concentration of $$\mathrm{A}$$ and $$\mathrm{B}$$ each. If the rate constant $$(\mathrm{k})$$ is $$4.6 \times 10^{-2} \mathrm{~s}^{-1}$$, then the time taken for $$\mathrm{A}$$ to become $$0.1 \mathrm{~M}$$ is _________ sec. (nearest integer)

Answer
50
27
Three moles of an ideal gas are compressed isothermally from $$60 \mathrm{~L}$$ to $$20 \mathrm{~L}$$ using constant pressure of $$5 \mathrm{~atm}$$. Heat exchange $$\mathrm{Q}$$ for the compression is - _________ Lit. atm.
Answer
200
28
Vanillin compound obtained from vanilla beans, has total sum of oxygen atoms and $$\pi$$ electrons is __________.
Answer
11
29

Phthalimide is made to undergo following sequence of reactions.

JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 25 English

Total number of $$\pi$$ bonds present in product 'P' is/are ________.

Answer
8
30

A first row transition metal with highest enthalpy of atomisation, upon reaction with oxygen at high temperature forms oxides of formula $$\mathrm{M}_2 \mathrm{O}_{\mathrm{n}}$$ (where $$\mathrm{n}=3,4,5$$). The 'spin-only' magnetic moment value of the amphoteric oxide from the above oxides is _________ $$\mathrm{BM}$$ (near integer)

(Given atomic number: $$\mathrm{Sc}: 21, \mathrm{Ti}: 22, \mathrm{~V}: 23, \mathrm{Cr}: 24, \mathrm{Mn}: 25, \mathrm{Fe}: 26, \mathrm{Co}: 27, \mathrm{Ni}: 28, \mathrm{Cu}: 29, \mathrm{Zn}: 30$$)

Answer
0