Given below are two statements:
Statement I : Group 13 trivalent halides get easily hydrolyzed by water due to their covalent nature.
Statement II : $$\mathrm{AlCl}_3$$ upon hydrolysis in acidified aqueous solution forms octahedral $$\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$$ ion.
In the light of the above statements, choose the correct answer from the options given below :
Given below are two statements:
Statement I : $$\mathrm{S}_8$$ solid undergoes disproportionation reaction under alkaline conditions to form $$\mathrm{S}^{2-}$$ and $$\mathrm{S}_2 \mathrm{O}_3{ }^{2-}$$.
Statement II : $$\mathrm{ClO}_4^{-}$$ can undergo disproportionation reaction under acidic condition.
In the light of the above statements, choose the most appropriate answer from the options given below :
Choose the correct statements from the following
A. All group 16 elements form oxides of general formula $$\mathrm{EO}_2$$ and $$\mathrm{EO}_3$$, where $$\mathrm{E}=\mathrm{S}, \mathrm{Se}, \mathrm{Te}$$ and $$\mathrm{Po}$$. Both the types of oxides are acidic in nature.
B. $$\mathrm{TeO}_2$$ is an oxidising agent while $$\mathrm{SO}_2$$ is reducing in nature.
C. The reducing property decreases from $$\mathrm{H}_2 \mathrm{~S}$$ to $$\mathrm{H}_2$$ Te down the group.
D. The ozone molecule contains five lone pairs of electrons.
Choose the correct answer from the options given below:
Choose the correct statements from the following
A. $$\mathrm{Mn}_2 \mathrm{O}_7$$ is an oil at room temperature
B. $$\mathrm{V}_2 \mathrm{O}_4$$ reacts with acid to give $$\mathrm{VO}_2{ }^{2+}$$
C. $$\mathrm{CrO}$$ is a basic oxide
D. $$\mathrm{V}_2 \mathrm{O}_5$$ does not react with acid
Choose the correct answer from the options given below :
Consider the following elements.
Which of the following is/are true about $$\mathrm{A}^{\prime}, \mathrm{B}^{\prime}, \mathrm{C}^{\prime}$$ and $$\mathrm{D}^{\prime}$$ ?
A. Order of atomic radii: $$\mathrm{B}^{\prime}<\mathrm{A}^{\prime}<\mathrm{D}^{\prime}<\mathrm{C}^{\prime}$$
B. Order of metallic character: $$\mathrm{B}^{\prime}<\mathrm{A}^{\prime}<\mathrm{D}^{\prime}<\mathrm{C}^{\prime}$$
C. Size of the element: $$\mathrm{D}^{\prime}<\mathrm{C}^{\prime}<\mathrm{B}^{\prime}<\mathrm{A}^{\prime}$$
D. Order of ionic radii: $$\mathrm{B}^{\prime+}<\mathrm{A}^{1^{+}}<\mathrm{D}^{\prime+}<\mathrm{C}^{+}$$
Choose the correct answer from the options given below :
Match List I with List II
List - I (Complex ion) |
List - II (Electronic Configuration) |
||
---|---|---|---|
(A) | $$\mathrm{[Cr(H_2O)_6]^{3+}}$$ | (I) | $$t_{2 g}{ }^2 e_g^0$$ |
(B) | $$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$$ | (II) | $$t_{2 g}{ }^3 e_g{ }^0$$ |
(C) | $$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$ | (III) | $$t_{2 g}{ }^3 e_g{ }^2$$ |
(D) | $$\left[\mathrm{V}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$$ | (IV) | $$t_{2 g}{ }^6 e_g^2$$ |
Choose the correct answer from the options given below:
Given below are two statements :
Statement I : Aniline reacts with con. $$\mathrm{H}_2 \mathrm{SO}_4$$, followed by heating at $$453-473 \mathrm{~K}$$ gives $$\mathrm{p}$$-aminobenzene sulphonic acid, which gives blood red colour in the 'Lassaigne's test'.
Statement II : In Friedel - Craft's alkylation and acylation reactions, aniline forms salt with the $$\mathrm{AlCl}_3$$ catalyst. Due to this, nitrogen of aniline aquires a positive charge and acts as deactivating group.
In the light of the above statements, choose the correct answer from the options given below :
A sample of $$\mathrm{CaCO}_3$$ and $$\mathrm{MgCO}_3$$ weighed $$2.21 \mathrm{~g}$$ is ignited to constant weight of $$1.152 \mathrm{~g}$$. The composition of mixture is :
(Given molar mass in $$\mathrm{g} \mathrm{~mol}^{-1} \mathrm{CaCO}_3: 100, \mathrm{MgCO}_3: 84$$)
The molarity of $$1 \mathrm{~L}$$ orthophosphoric acid $$\left(\mathrm{H}_3 \mathrm{PO}_4\right)$$ having $$70 \%$$ purity by weight (specific gravity $$1.54 \mathrm{~g} \mathrm{~cm}^{-3}$$) is __________ $$\mathrm{M}$$.
(Molar mass of $$\mathrm{H}_3 \mathrm{PO}_4=98 \mathrm{~g} \mathrm{~mol}^{-1}$$)