JEE MAIN - Chemistry (2023 - 15th April Morning Shift)

1
During water-gas shift reaction
Answer
(B)
carbon monoxide is oxidized to carbon dioxide.
2
The complex with highest magnitude of crystal field splitting energy $\left(\Delta_{0}\right)$ is :
Answer
(C)
$\left[\mathrm{Cr}\left(\mathrm{OH}_{2}\right)_{6}\right]^{3+}$
3
The major product formed in the Friedel-Craft acylation of chlorobenzene is
Answer
(A)
JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Haloalkanes and Haloarenes Question 46 English Option 1
4
The number of $\mathrm{P}-\mathrm{O}-\mathrm{P}$ bonds in $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{7},\left(\mathrm{HPO}_{3}\right)_{3}$ and $\mathrm{P}_{4} \mathrm{O}_{10}$ are respectively :
Answer
(A)
$1,3,6$
5
Which of the following statement is correct for paper chromatography?
Answer
(B)
Water present in the pores of the paper forms the stationary phase.
6
Which is not true for arginine?
Answer
(C)
It has high solubility in benzene.
7
Consider the following sequence of reactions:

JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 57 English
The product ' $\mathrm{B}$ ' is
Answer
(A)
JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 57 English Option 1
8
Given below are two statements:

Statement I : According to Bohr's model of hydrogen atom, the angular momentum of an electron in a given stationary state is quantised.

Statement II : The concept of electron in Bohr's orbit, violates the Heisenberg uncertainty principle.

In the light of the above statements, choose the most appropriate answer from the options given below:
Answer
(C)
Both Statement I and Statement II are correct
9
Which of the following statement(s) is/are correct?

(A) The $\mathrm{pH}$ of $1 \times 10^{-8}~ \mathrm{M} ~\mathrm{HCl}$ solution is 8 .

(B) The conjugate base of $\mathrm{H}_{2} \mathrm{PO}_{4}^{-}$ is $\mathrm{HPO}_{4}^{2-}$.

(C) $\mathrm{K}_{\mathrm{w}}$ increases with increase in temperature.

(D) When a solution of a weak monoprotic acid is titrated against a strong base at half neutralisation point, $\mathrm{pH}=\frac{1}{2} \mathrm{pK}_{\mathrm{a}}$

Choose the correct answer from the options given below:
Answer
(B)
(B), (C)
10
Consider the following statements:

(A) NF3 molecule has a trigonal planar structure.

(B) Bond length of $\mathrm{N}_{2}$ is shorter than $\mathrm{O}_{2}$.

(C) Isoelectronic molecules or ions have identical bond order.

(D) Dipole moment of $\mathrm{H}_{2}\mathrm{S}$ is higher than that of water molecule.

Choose the correct answer from the options given below:
Answer
(C)
(B) and (C) are correct
11
JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 58 English
In the above conversion the correct sequence of reagents to be added is
Answer
(C)
(i) $\mathrm{Br}_{2} / \mathrm{Fe}$, (ii) $\mathrm{Fe} / \mathrm{H}^{+}$, (iii) $\mathrm{HONO}$, (iv) $\mathrm{CuCl}$, (v) $\mathrm{KMnO}_{4}$
12
JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 44 English
'A' formed in the above reaction is
Answer
(A)
JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 44 English Option 1
13
The product formed in the following multistep reaction is :

JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Hydrocarbons Question 44 English
Answer
(D)
JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Hydrocarbons Question 44 English Option 4
14
Decreasing order of reactivity towards electrophilic substitution for the following compounds is :

JEE Main 2023 (Online) 15th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 56 English
Answer
(D)
$\mathrm{e}>\mathrm{d}>\mathrm{a}>\mathrm{b}>\mathrm{c}$
15
For a reversible reaction $\mathrm{A} \rightleftharpoons \mathrm{B}$, the $\Delta \mathrm{H}_{\text{forward reaction}} = 20 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The activation energy of the uncatalysed forward reaction is $300 \mathrm{~kJ} \mathrm{~mol}^{-1}$. When the reaction is catalysed keeping the reactant concentration same, the rate of the catalysed forward reaction at $27^{\circ} \mathrm{C}$ is found to be same as that of the uncatalysed reaction at $327^{\circ} \mathrm{C}$.

The activation energy of the catalysed backward reaction is ___________ $\mathrm{kJ}~ \mathrm{mol}^{-1}$.
Answer
130
16
The volume (in $\mathrm{mL}$) of $0.1 \mathrm{M} ~\mathrm{AgNO}_{3}$ required for complete precipitation of chloride ions present in $20 \mathrm{~mL}$ of $0.01 \mathrm{M}$ solution of $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2}$ as silver chloride is __________.
Answer
4
17
The number of correct statements from the following is _______.

(A) Conductivity always decreases with decrease in concentration for both strong and weak electrolytes.

(B) The number of ions per unit volume that carry current in a solution increases on dilution.

(C) Molar conductivity increases with decrease in concentration

(D) The variation in molar conductivity is different for strong and weak electrolytes

(E) For weak electrolytes, the change in molar conductivity with dilution is due to decrease in degree of dissociation.
Answer
3
18
In Chromyl chloride, the oxidation state of chromium is $(+)$ _______________.
Answer
6
19
The vapour pressure of $30 \%(\mathrm{w} / \mathrm{v})$ aqueous solution of glucose is __________ $\mathrm{mm} ~\mathrm{Hg}$ at $25^{\circ} \mathrm{C}$.

[Given : The density of $30 \%$ (w/v), aqueous solution of glucose is $1.2 \mathrm{~g} \mathrm{~cm}^{-3}$ and vapour pressure of pure water is $24 \mathrm{~mm}~ \mathrm{Hg}$.]

(Molar mass of glucose is $180 \mathrm{~g} \mathrm{~mol}^{-1}$.)
Answer
23
20
$30.4 \mathrm{~kJ}$ of heat is required to melt one mole of sodium chloride and the entropy change at the melting point is $28.4 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ at 1 atm. The melting point of sodium chloride is _______________ K (Nearest Integer)
Answer
1070
21
The total change in the oxidation state of manganese involved in the reaction of $\mathrm{KMnO}_{4}$ and potassium iodide in the acidic medium is ____________.
Answer
5
22
The homoleptic and octahedral complex of $\mathrm{Co}^{2+}$ and $\mathrm{H}_{2} \mathrm{O}$ has ___________ unpaired electron(s) in the $t_{2\mathrm{g}}$ set of orbitals.
Answer
1
23
The total number of isoelectronic species from the given set is ___________.

$\mathrm{O}^{2-}, \mathrm{F}^{-}, \mathrm{Al}, \mathrm{Mg}^{2+}, \mathrm{Na}^{+}, \mathrm{O}^{+}, \mathrm{Mg}, \mathrm{Al}^{3+}, \mathrm{F}$
Answer
5