JEE MAIN - Chemistry (2021 - 31st August Evening Shift)

1
Arrange the following conformational isomers of n-butane in order of their increasing potential energy :

JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Basics of Organic Chemistry Question 130 English
Answer
(D)
I < III < IV < II
2
The Eu2+ ion is a strong reducing agent in spite of its ground state electronic configuration (outermost) : [Atomic number of Eu = 63]
Answer
(C)
4f7
3
The structures A and B formed in the following reaction are : [Ph = $$-$$C6H5]

JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 110 English
Answer
(D)
4
In which one of the following sets all species show disproportionation reaction?
Answer
(E)
None of the above
5
Match List - I with List - II

List - I
(Parmeter)
List - II
(Unit)
(a) Cell constant (i) $$S\,c{m^2}mo{l^{ - 1}}$$
(b) Molar conductivity (ii) Dimensionless
(c) Conductivity (iii) $${m^{ - 1}}$$
(d) Degree of dissociation of electrolyte (iv) $${\Omega ^{ - 1}}{m^{ - 1}}$$


Choose the most appropriate answer from the options given below :
Answer
(A)
(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
6
The major products A and B formed in the following reaction sequence are :

JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Compounds Containing Nitrogen Question 104 English
Answer
(C)
JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Compounds Containing Nitrogen Question 104 English Option 3
7
Which of the following is not an example of fibrous protein?
Answer
(B)
Albumin
8
For the reaction given below :-

JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 107 English

The compound which is not formed as a product in the reaction is a :
Answer
(C)
dicarboxylic acid
9
Spin only magnetic moment in BM of [Fe(CO)4(C2O4)]+ is :
Answer
(D)
1.73
10
The incorrect expression among the following is :
Answer
(B)
$$K = {{\Delta H^\circ - T\Delta S^\circ } \over {RT}}$$
11
Match List - I with List - II :

List - I
(Metal Ion)
List - II
(Group of Qualitative analysis)
(a) $$M{n^{2 + }}$$ (i) Group - III
(b) $$A{s^{3 + }}$$ (ii) Group - IIA
(c) $$C{u^{2 + }}$$ (iii) Group - IV
(d) $$A{l^{3 + }}$$ (iv) Group - IIB


Choose the most appropriate answer from the options given below :
Answer
(B)
(a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
12
The major product of the following reaction is :

JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Haloalkanes and Haloarenes Question 75 English
Answer
(D)
JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Haloalkanes and Haloarenes Question 75 English Option 4
13
For the following sequence of reactions, the correct products are :

JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Hydrocarbons Question 68 English
Answer
(A)
JEE Main 2021 (Online) 31st August Evening Shift Chemistry - Hydrocarbons Question 68 English Option 1
14
Identify correct A, B and C in the reaction sequence given below :

Answer
(B)
15
1.22 g of an organic acid is separately dissolved in 100 g of benzene (Kb = 2.6 K kg mol$$-$$1) and 100 g of acetone (Kb = 1.7 K kg mol$$-$$1). The acid is known to dimerize in benzene but remain as a monomer in acetone. The boiling point of the solution in acetone increases by 0.17$$^\circ$$C. The increase in boiling point of solution in benzene in $$^\circ$$C is x $$\times$$ 10$$-$$2. The value of x is ______________. (Nearest integer) [Atomic mass : C = 12.0, H = 1.0, O =16.0]
Answer
13
16
The value of magnetic quantum number of the outermost electron of Zn+ ion is ______________.
Answer
0
17
The pH of a solution obtained by mixing 50 mL of 1 M HCl and 30 mL of 1 M NaOH is x $$\times$$ 10$$-$$4. The value of x is ____________. (Nearest integer) [log 2.5 = 0.3979]
Answer
6021
18
For the reaction A $$\to$$ B, the rate constant k(in s$$-$$1) is given by

$${\log _{10}}k = 20.35 - {{(2.47 \times {{10}^3})} \over T}$$

The energy of activation in kJ mol$$-$$1 is ____________. (Nearest integer) [Given : R = 8.314 J K$$-$$1 mol$$-$$1]
Answer
47
19
Sodium oxide reacts with water to produce sodium hydroxide. 20.0 g of sodium oxide is dissolved in 500 mL of water. Neglecting the change in volume, the concentration of the resulting NaOH solution is ______________ $$\times$$ 10$$-$$1 M. (Nearest integer) [Atomic mass : Na = 23.0, O = 16.0, H = 1.0]
Answer
13
20
According to molecular orbital theory, the number of unpaired electron(s) in $$O_2^{2 - }$$ is :
Answer
0
21
The transformation occurring in Duma's method is given below :

$${C_2}{H_7}N + \left( {2x + {y \over 2}} \right)CuO \to xC{O_2} + {y \over 2}{H_2}O + {z \over 2}{N_2} + \left( {2x + {y \over 2}} \right)Cu$$

The value of y is ______________. (Integer answer)
Answer
7