JEE MAIN - Chemistry (2021 - 25th February Evening Shift)

1
The correct sequence of reagents used in the preparation of 4-bromo-2-nitroethyl benzene from benzene is :
Answer
(B)
$$C{H_3}COCl/AlC{l_3},Zn - Hg/HCl,B{r_2}/AlB{r_3},HN{O_3}/{H_2}S{O_4}$$
2
What is 'X' in the given reaction?

JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 107 English
Answer
(C)
JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 107 English Option 3
3
The solubility of Ca(OH)2 in water is :

[Given : The solubility product of Ca(OH)2 in water = 5.5 $$\times$$ 10$$-$$6]
Answer
(B)
1.11 $$\times$$ 10$$-$$2
4
Which among the following species has unequal bond lengths?
Answer
(D)
SF4
5
In which of the following order the given complex ions are arranged correctly with respect to their decreasing spin only magnetic moment?

(i) [FeF6]3$$-$$

(ii) [Co(NH3)6]3+

(iii) [NiCl4]2$$-$$

(iv) [Cu(NH3)4]2+
Answer
(C)
(i) > (iii) > (iv) > (ii)
6
The correct order of acid character of the following compounds is :

JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Basics of Organic Chemistry Question 159 English
Answer
(C)
II > III > IV > I
7
The major product of the following reaction is :

JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Hydrocarbons Question 84 English
Answer
(A)
JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Hydrocarbons Question 84 English Option 1
8
JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Compounds Containing Nitrogen Question 146 English
Correct statement about the given chemical reaction is :
Answer
(C)
Reaction is possible and compound (A) will be major product.
9
Given below are two statements :

Statement I : The identification of Ni2+ is carried out by dimethyl glyoxime in the presence of NH4OH.

Statement II : The dimethyl glyoxime is a bidentate neutral ligand.

In the light of the above statements, choose the correct answer from the options given below :
Answer
(D)
Both Statement I and Statement II are true.
10
Carbylamine test is used to detect the presence of primary amino group in an organic compound. Which of the following compound is formed when this test is performed with aniline?
Answer
(D)
JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Compounds Containing Nitrogen Question 147 English Option 4
11
Which of the following is correct structure of $$\alpha$$-anomer of maltose?
Answer
(C)
JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Biomolecules Question 106 English Option 3
12
Which of the following compound is added to the sodium extract before addition of silver nitrate for testing of halogens?
Answer
(A)
Nitric acid
13
The major product of the following reaction is :

JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 140 English
Answer
(D)
JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 140 English Option 4
14
The correct order of bond dissociation enthalpy of halogens is :
Answer
(B)
Cl2 > Br2 > F2 > I2
15
Copper reduces NO$$_3^ - $$ into NO and NO2 depending upon the concentration of HNO3 in solution. (Assuming fixed [Cu2+] and PNO = PNO2), the HNO3 concentration at which the thermodynamic tendency for reduction of NO$$_3^ - $$ into NO and NO2 by copper is same is 10x M. The value of 2x is _______. (Rounded off to the nearest integer)

[Given, $$E_{C{u^{2 + }}/Cu}^o = 0.34$$ V, $$E_{NO_3^ - /NO}^o = 0.96$$ V, $$E_{NO_3^ - /N{O_2}}^o = 0.79$$ V and at 298 K, $${{RT} \over F}$$(2.303) = 0.059]
Answer
1
16
The spin only magnetic moment of a divalent ion in aqueous solution (atomic number 29) is _________ BM.
Answer
2
17
If a compound AB dissociates to the extent of 75% in an aqueous solution, the molality of the solution which shows a 2.5 K rise in the boiling point of the solution is ____________ molal. (Rounded off to the nearest integer)

[Kb = 0.52 K kg mol$$-$$1]
Answer
3
18
Electromagnetic radiation of wavelength 663 nm is just sufficient to ionise the atom of metal A. The ionization enegy of metal A in kJ mol$$-$$1 is __________. (Rounded off to the nearest integer)

[h = 6.63 $$\times$$ 10$$-$$34 Js, c = 3.00 $$\times$$ 108 ms$$-$$1, NA = 6.02 $$\times$$ 1023 mol$$-$$1]
Answer
181
19
Consider titration of NaOH solution versus 1.25 M oxalic acid solution. At the end point following burette readings were obtained.

(i) 4.5 mL

(ii) 4.5 mL

(iii) 4.4 mL

(iv) 4.4 mL

(v) 4.4 mL

If the volume of oxalic acid taken was 10.0 mL then the molarity of the NaOH solution is ________ M. (Rounded off to the nearest integer)
Answer
6
20
Five moles of an ideal gas at 293 K is expanded isothermally from an initial pressure of 2.1 MPa to 1.3 MPa against at constant external pressure 4.3 MPa. The heat transferred in this process is _________ kJ mol$$-$$1. (Rounded off to the nearest integer) [Use R = 8.314 J mol$$-$$1K$$-$$1]
Answer
15
21
The number of compound/s given below which contain/s -COOH group is __________. (Integer answer)

(A) Sulphanilic acid

(B) Picric acid

(C) Aspirin

(D) Ascorbic acid
Answer
1
22
The rate constant of a reaction increases by five times on increase in temperature from 27$$^\circ$$C to 52$$^\circ$$C. The value of activation energy in kJ mol$$-$$1 is _________. (Rounded off to the nearest integer)

[R = 8.314 J K$$-$$1mol$$-$$1]
Answer
52
23
Among the following, number of metal/s which can be used as electrodes in the photoelectric cell is _________. (Integer answer)

(A) Li

(B) Na

(C) Rb

(D) Cs
Answer
1