JEE MAIN - Chemistry (2021 - 25th February Evening Shift - No. 3)

The solubility of Ca(OH)2 in water is :

[Given : The solubility product of Ca(OH)2 in water = 5.5 $$\times$$ 10$$-$$6]
1.11 $$\times$$ 10$$-$$6
1.11 $$\times$$ 10$$-$$2
1.77 $$\times$$ 10$$-$$6
1.77 $$\times$$ 10$$-$$2

Explanation

Let, solubility of Ca(OH)2 in pure water = S mol/L

$$Ca{(OH)_2}$$ $$\rightleftharpoons$$ $$\mathop {C{a^{2 + }}}\limits_{S\,mol/L} + \mathop {2O{H^ - }}\limits_{2 \times S\,(mol/L)} $$

Ksp = [Ca2+] [OH$$-$$]2 = S $$\times$$ (2S)2 = 4 S3 (mol/L)

The expression of Ksp can also be written as,

Ksp = xx . yy . Sx + y

= 11 . 22 . S1 + 2

= 4 S3 [$$\because$$ For Ca(OH)2 : x = 1, y = 2]

x and y are the coefficients of cations and anions respectively

$$S = {\left( {{{{K_{sp}}} \over 4}} \right)^{1/3}} = {\left( {{{5.5 \times {{10}^{ - 6}}} \over 4}} \right)^{1/3}}$$

$$ = 1.11 \times {10^{ - 2}}$$ ml/L

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