JEE MAIN - Chemistry (2020 - 9th January Morning Slot)
1
Identify (A) in the following reaction sequence :
Answer
(A)
2
If enthalpy of atomisation for Br2(1) is x kJ/mol
and bond enthalpy for Br2 is y kJ/mol, the
relation between them :
Answer
(C)
is x > y
3
If the magnetic moment of a dioxygen species
is 1.73 B.M, it may be :
Answer
(A)
$$O_2^ - $$ or $$O_2^ + $$
4
[Pd(F)(Cl)(Br)(I)]2– has n number of
geometrical isomers. Then, the spin-only
magnetic moment and crystal field stabilisation
energy [CFSE] of [Fe(CN)6]n–6, respectively,
are:
[Note : Ignore the pairing energy]
Answer
(A)
1.73 BM and –2.0 $$\Delta $$0
5
The Ksp for the following dissociation is
1.6 × 10–5
Which of the following choices is correct for
a mixture of 300 mL 0.134 M Pb(NO3)2 and
100 mL 0.4 M NaCl ?
Answer
(A)
Q > Ksp
6
The correct order of heat of combustion for
following alkadienes is :
Answer
(C)
(a) < (b) < (c)
7
For the following reactions
$$A\buildrel {700K} \over
\longrightarrow {\mathop{\rm Product}\nolimits} $$
$$A\mathrel{\mathop{\kern0pt\longrightarrow}
\limits_{catalyst}^{500K}} {\mathop{\rm Product}\nolimits} $$
it was found that Ea is decreased by 30 kJ/mol
in the presence of catalyst.
If the rate remains unchanged, the activation
energy for catalysed reaction is (Assume pre
exponential factor is same):
Answer
(D)
75 kJ/mol
8
The increasing order of basicity for the
following intermediates is (from weak to
strong)
Answer
(D)
(v) < (iii) < (ii) < (iv) < (i)
9
The electronic configurations of bivalent
europium and trivalent cerium are
(atomic number : Xe = 54, Ce = 58, Eu = 63)
Answer
(D)
[Xe] 4f7 and [Xe] 4f1
10
How much amount of NaCl should be added
to 600 g of water ($$\rho $$ = 1.00 g/mL) to decrease
the freezing point of water to – 0.2 °C ?
______.
(The freezing point depression constant for water = 2K kg mol–1)
Answer
1.74to1.76
11
The mass percentage of nitrogen in histamine is _____.
Answer
37.80to38.20
12
108 g of silver (molar mass 108 g mol–1) is
deposited at cathode from AgNO3(aq) solution
by a certain quantity of electricity. The
volume (in L) of oxygen gas produced at
273 K and 1 bar pressure from water by the
same quantity of electricity is _______.
Answer
5.66to5.68
13
The molarity of HNO3 in a sample which has
density 1.4 g/mL and mass percentage of 63%
is _____.
(Molecular Weight of HNO3 = 63)
Answer
14
14
The hardness of a water sample containing
10–3 M MgSO4 expressed as CaCO3 equivalents
(in ppm) is ______.
(molar mass of MgSO4 is 120.37 g/mol)
Answer
100
15
The de Broglie wavelength of an electron in the
4th Bohr orbit is :
Answer
(C)
8$$\pi $$a0
16
The major product (Y) in the following
reactions is :
Answer
(D)
17
Complex X of composition Cr(H2O)6Cln
has a spin only magnetic moment of 3.83
BM. It reacts with AgNO3 and shows
geometrical isomerism. The IUPAC
nomenclature of X is :