JEE MAIN - Chemistry (2020 - 9th January Morning Slot)

1
Identify (A) in the following reaction sequence : JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 167 English
Answer
(A)
JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 167 English Option 1
2
If enthalpy of atomisation for Br2(1) is x kJ/mol and bond enthalpy for Br2 is y kJ/mol, the relation between them :
Answer
(C)
is x > y
3
If the magnetic moment of a dioxygen species is 1.73 B.M, it may be :
Answer
(A)
$$O_2^ - $$ or $$O_2^ + $$
4
[Pd(F)(Cl)(Br)(I)]2– has n number of geometrical isomers. Then, the spin-only magnetic moment and crystal field stabilisation energy [CFSE] of [Fe(CN)6]n–6, respectively, are:
[Note : Ignore the pairing energy]
Answer
(A)
1.73 BM and –2.0 $$\Delta $$0
5
The Ksp for the following dissociation is 1.6 × 10–5

$$PbC{l_{2(s)}} \leftrightharpoons Pb_{(aq)}^{2 + } + 2Cl_{(aq)}^ - $$

Which of the following choices is correct for a mixture of 300 mL 0.134 M Pb(NO3)2 and 100 mL 0.4 M NaCl ?
Answer
(A)
Q > Ksp
6
The correct order of heat of combustion for following alkadienes is :
JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Hydrocarbons Question 97 English 1 JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Hydrocarbons Question 97 English 2 JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Hydrocarbons Question 97 English 3
Answer
(C)
(a) < (b) < (c)
7
For the following reactions
$$A\buildrel {700K} \over \longrightarrow {\mathop{\rm Product}\nolimits} $$
$$A\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{catalyst}^{500K}} {\mathop{\rm Product}\nolimits} $$
it was found that Ea is decreased by 30 kJ/mol in the presence of catalyst.
If the rate remains unchanged, the activation energy for catalysed reaction is (Assume pre exponential factor is same):
Answer
(D)
75 kJ/mol
8
The increasing order of basicity for the following intermediates is (from weak to strong)
JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Basics of Organic Chemistry Question 172 English 1 JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Basics of Organic Chemistry Question 172 English 2 JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Basics of Organic Chemistry Question 172 English 3 JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Basics of Organic Chemistry Question 172 English 4 JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Basics of Organic Chemistry Question 172 English 5
Answer
(D)
(v) < (iii) < (ii) < (iv) < (i)
9
The electronic configurations of bivalent europium and trivalent cerium are
(atomic number : Xe = 54, Ce = 58, Eu = 63)
Answer
(D)
[Xe] 4f7 and [Xe] 4f1
10
How much amount of NaCl should be added to 600 g of water ($$\rho $$ = 1.00 g/mL) to decrease the freezing point of water to – 0.2 °C ? ______.
(The freezing point depression constant for water = 2K kg mol–1)
Answer
1.74to1.76
11
The mass percentage of nitrogen in histamine is _____.
Answer
37.80to38.20
12
108 g of silver (molar mass 108 g mol–1) is deposited at cathode from AgNO3(aq) solution by a certain quantity of electricity. The volume (in L) of oxygen gas produced at 273 K and 1 bar pressure from water by the same quantity of electricity is _______.
Answer
5.66to5.68
13
The molarity of HNO3 in a sample which has density 1.4 g/mL and mass percentage of 63% is _____.
(Molecular Weight of HNO3 = 63)
Answer
14
14
The hardness of a water sample containing 10–3 M MgSO4 expressed as CaCO3 equivalents (in ppm) is ______.
(molar mass of MgSO4 is 120.37 g/mol)
Answer
100
15
The de Broglie wavelength of an electron in the 4th Bohr orbit is :
Answer
(C)
8$$\pi $$a0
16
The major product (Y) in the following reactions is : JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Hydrocarbons Question 96 English
Answer
(D)
JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Hydrocarbons Question 96 English Option 4
17
Complex X of composition Cr(H2O)6Cln has a spin only magnetic moment of 3.83 BM. It reacts with AgNO3 and shows geometrical isomerism. The IUPAC nomenclature of X is :
Answer
(C)
Tetraaquadichlorido chromium (III) chloride dihydrate
18
The compound that cannot act both as oxidising and reducing agent is :
Answer
(A)
H3PO4
19
Which of these will produce the highest yield in Friedel Crafts reaction?
Answer
(A)
JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Haloalkanes and Haloarenes Question 112 English Option 1
20
The major product Z obtained in the following reaction scheme is : JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Compounds Containing Nitrogen Question 166 English
Answer
(A)
JEE Main 2020 (Online) 9th January Morning Slot Chemistry - Compounds Containing Nitrogen Question 166 English Option 1
21
The acidic, basic and amphoteric oxides, respectively, are :
Answer
(B)
N2O3, Li2O, Al2O3
22
B has a smaller first ionization enthalpy than Be. Consider the following statements :

(I) It is easier to remove 2p electron than 2s electron

(II) 2p electron of B is more shielded from the nucleus by the inner core of electrons than the 2s electrons of Be.

(III) 2s electron has more penetration power than 2p electron.

(IV) atomic radius of B is more than Be (Atomic number B = 5, Be = 4)

The correct statements are :
Answer
(D)
(I), (II) and (III)