JEE MAIN - Chemistry (2020 - 7th January Evening Slot)
1
Two open beakers one containing a solvent and the other containing a mixture of that solvent
with a non voltatile solute are together selated in a container. Over time :
Answer
(A)
The volume of the solution increases and the volume of the solvent decreases.
2
Among the statements(a)-(d) the incorrect ones are :
(a) Octahedral CO(III) complexes with strong fields ligands have very high magnetic moments.
(b) When $$\Delta $$0 < P, the d-electron configuration of Co(III) in an octahedral complex is $$t_{eg}^4e_g^2$$
(c) Wavelength of light absorbed by [Co(en)3]3+ is lower than that of [CoF6]3-
(d) If the $$\Delta $$0 for an octahedral complex of CO(III) is 18,000 cm-1, the $$\Delta $$t for its tetrahedral complex with the same ligand be 16,000 cm-1
Answer
(D)
(a) and (d) only
3
In the following reaction sequence,
The major product B is :
Answer
(B)
4
The ammonia (NH3) released on quantitative reaction of 0.6 g urea (NH2CONH2) with sodium hydroxide (NaOH) can be neutralized by :
Answer
(B)
100 ml of 0.2 N HCl
5
Within each pair of elements F & Cl, S & Se, and Li & Na, respectively, the elements that release
more energy upon and electron gain are :
Answer
(C)
Cl, S and Li
6
Which of the following statements is correct ?
Answer
(B)
Gluconic acid is a partial oxidation product of glucose
7
A chromatography column, packed with silica gel as stationary phase, was used to separate a
mixture of compounds consisting of (A) benzanilide (B) aniline and (C) acetophenone. When the
column is eluted with a mixture of solvents, hexane : ethylacelate (20:80), the sequence of
obtained compounds is :
Answer
(C)
(C), (A) and (B)
8
The redox reaction among the following is :
Answer
(C)
combination of dinitrogen with dioxygen at 2000 K
9
In the following reactions sequence, structure of A and B respectively will be :
Answer
(D)
10
For the following reactions
Ks and Ke, are respectively, the rate constants for substitution and elimination and $$\mu = {{{k_s}} \over {{k_e}}}$$ the
correct options is
Answer
(B)
$${\mu _A} > {\mu _B}$$ and Ke(B) > Ke(A)
11
The number of possible optical isomers for the complexes MA2B2 with sp3 and dsp2 hydridized metal atom. respectively, is :
Note : A and B are unidentate netural and unidentate monoanionic ligands, respectively.
Answer
(B)
0 and 0
12
The bond order and the magnetic characteristics of CN-
are :
The correct order of stability for the following alkoxides is :
Answer
(A)
(C) > (B) > (A)
15
For the reaction 2H2(g) + 2NO(g) $$ \to $$ N2(g) + 2H2O(g) the observed rate expression is, rate = Kf[NO]2[H2]. The rate expression for the reverse reaction is :
Answer
(B)
Kb[N2][H2O]2/[H2]
16
Consider the following reactions :
Which of these reactions are possible ?
Answer
(D)
(b) and (d)
17
The flocculation value of HCl for arsenic sulphide sol. is 30 m mol L-1 If H2SO4 is used for the flocculatiopn of arsenic sulphide, the amount in grams, of H2SO4 in 250 ml required for the above purposed is ______.
(molecular mass of H2SO4 = 98 g/mol)
Answer
0.36to0.38
18
3 g of acetic acid is added to 250 mL of 0.1 M HCL and the solution made up to 500 mL. To 20 mL
of this solutions $${1 \over 2}$$ mL of 5 M NaOH is added. The pH of the solution is __________.
[Given : pKa of acetic acid = 4.75, molar mass of acetic of acid = 60 g/mol, log 3 = 0.4771]
Neglect any changes in volume.
Answer
5.22TO5.24
19
The standard heat of formation $$\left( {{\Delta _f}H_{298}^0} \right)$$ of ethane (in kj/mol), if the heat of combustion of
ethane, hydrogen and graphite are - 1560, -393.5 and -286 Kj/mol, respectively is :