JEE MAIN - Chemistry (2020 - 6th September Morning Slot)
1
The number of Cl = O bonds in perchloric acid
is, "________".
Answer
3
2
The elevation of boiling point of 0.10 m
aqueous CrCl3.xNH3 solution is two times that
of 0.05 m aqueous CaCl2 solution. The value of
x is ______.
[Assume 100% ionisation of the complex and
CaCl2, coordination number of Cr as 6, and that
all NH3 molecules are present inside the
coordination sphere]
Answer
5
3
Potassium chlorate is prepared by the
electrolysis of KCl in basic solution
6OH- + Cl- $$ \to $$ ClO3- + 3H2O + 6e-
If only 60% of the current is utilized in the
reaction, the time (rounded to the nearest hour)
required to produce 10 g of KClO3 using a
current of 2 A is_________.
(Given : F = 96,500 C mol–1; molar mass of
KCIO3 = 122 g mol–1)
Answer
11
4
In an estimation of bromine by Carius method,
1.6 g of an organic compound gave 1.88 g of
AgBr. The mass percentage of bromine in the
compound is _______.
(Atomic mass, Ag = 108, Br = 80 g mol–1)
Answer
50
5
The set that contains atomic numbers of only
transition elements, is :
Answer
(D)
21, 25, 42, 72
6
Consider the following reactions
'A' is :
Answer
(B)
7
The variation of equilibrium constant with
temperature is given below :
Temperature
Equilibrium Constant
T1 = 25oC
K1 = 10
T2 = 100oC
K2 = 100
The values of $$\Delta $$Ho, $$\Delta $$Go at T1 and $$\Delta $$Go at T2
(in kJ mol–1) respectively, are close to : [Use
R = 8.314 J K–1 mol–1]
Answer
(A)
28.4, –5.71 and –14.29
8
Consider the following reactions
A $$ \to $$ P1 ; B $$ \to $$ P2 ; C $$ \to $$ P3 ; D $$ \to $$ P4,
The order of the above reactions are a, b, c,
and d, respectively. The following graph is
obtained when log[rate] vs. log[conc.] are
plotted
Among the following, the correct sequence for
the order of the reactions is :
Answer
(A)
d > b > a > c
9
The correct statement with respect to
dinitrogen is :
Answer
(B)
it can be used as an inert diluent for
reactive chemicals
10
The major product obtained from the following
reaction is :
Answer
(C)
11
Which of the following compounds shows
geometrical isomerism?
Answer
(D)
4-methylpent-2-ene
12
The lanthanoid that does NOT show +4 oxidation
state is :
Answer
(D)
Eu
13
The major products of the following reaction are :
Answer
(D)
14
The major product of the following reaction is :
Answer
(A)
15
The species that has a spin-only magnetic
moment of 5.9 BM, is :
(Td = tetrahedral)
Answer
(A)
[MnBr4]2– (Td)
16
Arrange the following solutions in the
decreasing order of pOH :
(A) 0.01 M HCl
(B) 0.01 M NaOH
(C) 0.01 M CH3COONa
(D) 0.01 M NaCl
Answer
(B)
(A) > (D) > (C) > (B)
17
For the reaction
Fe2N(s) + $${3 \over 2}$$H2(g) ⇌ 2Fe(s) + NH3(g)
Answer
(A)
KC = Kp(RT)1/2
18
A solution of two components containing
n1 moles of the 1st component and n2 moles of
the 2nd component is prepared. M1 and M2 are
the molecular weights of component 1 and 2
respectively. If d is the density of the solution
in g mL–1, C2 is the molarity and x2 is the mole
fraction of the 2nd component, then C2 can be
expressed as :