JEE MAIN - Chemistry (2018 - 15th April Morning Slot)

1
The reagent(s) required for the following conversion are :

JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 208 English
Answer
(A)
(i) B2H6;    (ii) SnCl2/HCl;    (iii) H3O+
2
The major product of the following reaction is :

JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Alcohols, Phenols and Ethers Question 143 English
Answer
(A)
JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Alcohols, Phenols and Ethers Question 143 English Option 1
3
Which of the following will not exist in zwitter ionic form at pH=7 ?
Answer
(D)
JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Compounds Containing Nitrogen Question 199 English Option 4
4
Which of the following will most readily give the dehydrohalogenation product ?
Answer
(D)
JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Hydrocarbons Question 126 English Option 4
5
The main reduction product of the following compound with NaBH4 in methanol is :

JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 209 English
Answer
(B)
JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 209 English Option 2
6
The increasing order of nitration of the following compounds is :

JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Compounds Containing Nitrogen Question 200 English
Answer
(D)
(a) < (b) < (d) < (c)
7
The correct match between items of List-I and List-II is :

List - I List - II
(A) Coloured impurity (P) Steam distilation
(B) Mixture of o-nitrophenol
and p-nitrophenol
(Q) Fractional distilation
(C) Crude Naphtha (R) Charcoal treatment
(d) Mixture of glycerol
and sugars
(S) Distillation under
reduced pressure
Answer
(C)
(A)-(R), (B)-(P), (C)-(Q), (D)-(S)
8
Which of the following is the correct structure of Adenosine?
Answer
(A)
JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Biomolecules Question 148 English Option 1
9
JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Chemical Bonding & Molecular Structure Question 192 English
In hydrogen azide (above) the bond orders of bond (I) and (II) are :
Answer
(A)
$$\eqalign{ & (\mathrm{I})\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,(\mathrm{II}) \cr & < 2\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, > 2 \cr} $$
10
An ideal gas undergoes a cyclic process as shown in Figure.

JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Thermodynamics Question 160 English
$$\Delta $$UBC = $$-$$5 kJ mol-1, qAB = $$2$$ kJ mol-1, WAB = $$-$$5 kJ mol-1, WCA = 3 kJ mol-1. Heat absorbed by the system during process $$CA$$ is :
Answer
(B)
+5 kJ mol-1
11
The IUPAC name of the following compound is :

JEE Main 2018 (Online) 15th April Morning Slot Chemistry - Basics of Organic Chemistry Question 208 English
Answer
(C)
4-ethyl-3-methylhex-2-ene
12
The decreasing order of bond angles in BF3, NH3, PF3 and I3- is :
Answer
(B)
I3- > BF3 > NH3 > PF3
13
When an electric currents passed through acidified water, 112 mL of hydrogen gas at N.T.P. was collected at the cathode in 965 seconds. The current passed, in ampere, is :
Answer
(A)
1.0
14
A sample of $$NaCl{O_3}$$ is converted by heat to $$NaCl$$ with a loss of $$0.16$$ $$g$$ of oxygen. The residue is dissolved in water and precipitated as $$AgCl.$$ The mass of $$AgCl$$ (in $$g$$) obtained will be : (Given : Molar mass of $$AgCl=143.5$$ $$g$$ $$mo{l^{ - 1}}$$)
Answer
(C)
$$0.48$$
15
n$$-$$digit numbers are formed using only three digits 2, 5 and 7. The smallest value of n for which 900 such distinct numbers can be formed, is :
Answer
(B)
7
16
If x1, x2, . . ., xn and $${1 \over {{h_1}}}$$, $${1 \over {{h_2}}}$$, . . . , $${1 \over {{h_n}}}$$ are two A.P..s such that x3 = h2 = 8 and x8 = h7 = 20, then x5.h10 equals :
Answer
(A)
2560
17
For Na+, Mg2+, F- and O2-; the correct order of increasing ionic radii is :
Answer
(C)
Mg2+ < Na+ < F- < O2-
18
Which of the following is a Lewis acid?
Answer
(B)
B(CH3)3
19
In the molecular orbital diagram for the molecular ion, N2+, the number of electrons in the $$\sigma $$2pz molecular orbital is :
Answer
(B)
1
20
Ejection of the photoelectron from metal in the photoelectric experiment can be stopped by applying 0.5 V when the radiation of 250 nm is used. The work function of the metal is :
Answer
(B)
4.5 eV
21
Ejection of the photoelectron from metal in the photoelectric experiment can be stopped by applying 0.5 V when the radiation of 250 nm is used. The work function of the metal is :
Answer
(B)
4.5 eV
22
For which of the following reactions, $$\Delta $$H is equal to $$\Delta $$U?
Answer
(B)
2HI(g) $$ \to $$ H2(g) + I2(g)
23
In which of the following reactions, an increase in the volume of the container will favour the formation of products?
Answer
(A)
2NO2(g) $$\rightleftharpoons$$ 2NO(g) + O2(g)
24
The minimum volume of water required to dissolve 0.1 g lead (II) chloride to get a saturated solution (Ksp of PbCl2 = 3.2 $$ \times $$ 10-8 atomic mass of Pb = 207 u ) is :
Answer
(C)
0.18 L
25
The minimum volume of water required to dissolve 0.1 g lead (II) chloride to get a saturated solution (Ksp of PbCl2 = 3.2 $$ \times $$ 10-8 atomic mass of Pb = 207 u ) is :
Answer
(C)
0.18 L