JEE Advance - Chemistry (1997)

  • 1
    Which one of the following compounds has sp2 hybridization?
    Відповідь
    (B)
    SO2
  • 2
    For a d-electron the orbital angular momentum is
    Відповідь
    (A)
    $$\sqrt 6 \left( {h/2\pi } \right)$$
  • 3
    The critical temperature of water is higher than that of O2 because the H2O molecule has
    Відповідь
    (D)
    dipole moment
  • 4
    Which contains both polar and non-polar bonds?
    Відповідь
    (C)
    H2O2
  • 5
    A compound of vanadium has a magnetic moment of 1.73 BM. Work out the electronic configuration of the vanadium ion in the compound.
    Відповідь
    (D)
    1s2 2s2 2p6 3s2 3p6 3d1
  • 6
    Give reasons of the following:
    The crystalline salts of alkaline earth metals contain more water of crystallisation than the corresponding alkali metal salts.
    Відповідь
    A
    C
    D
  • 7
    To a 25ml H2O2 solution, excess of acidified solution of potassium iodide was added. The iodine liberated required 20 ml of 0.3 N sodium thiosulphate solution. Calculate the volume strength of H2O2 solution.
    Відповідь
    (B)
    1.344
  • 8
    Give reactions for the oxidation of hydrogen peroxide with potassium permanganate in acidic medium.
    Відповідь
    A
    B
    C
  • 9
    Element A burns in nitrogen to give an ionic compound B. Compound B reacts with water to give C and D. A solution of C becomes 'milky' on bubbling carbon dioxide. Identify A, B, C and D.
    Відповідь
    (C)
    A = Ba, B = Ba3N2, C = Ba(OH)2, D = NH3
  • 10
    Arrange the following sulphates of Alkaline earth metals in order of decreasing thermal stability : BeSO4, MgSO4, CaSO4, SrSO4
    Відповідь
    (D)
    SrSO4 > CaSO4 > MgSO4 > BeSO4
  • 11
    How many grams of silver could be plated out on a serving tray by electrolysis of a solution containing silver in +1 oxidation state for a period of 8.0 hours at a current of 8.46 amperes? What is the area of the tray if the thickness of the silver plating is 0.00254 cm? Density of silver is 10.5 g/cm3
    Відповідь
    (A)
    272.6 g, 1.02 x 10^3 cm^2
  • 12
    Calculate the equilibrium constant for the reaction
    Fe2+ + Ce4+ $$\leftrightharpoons$$ Fe3+ + Ce3+
    (given $$E_{C{e^{4 + }}/C{e^{3 + }}}^o$$ = 1.44 V; $$E_{F{e^{3 + }}/F{e^{2 + }}}^o$$ = 0.68 V)
    Відповідь
    (D)
    7.2 x 1012