X is a crystalline salt of sodium solution of X in water turns litmus red and produces a gas which turns lime water milky when added to sodium carbonate. With barium chloride solution, X gives hydrochloric acid. X is
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(C)
NaHSO 4
2
The alkanol obtained from the production of soap is
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(B)
glycerol
3
The flame used by welders in cutting metals is
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(D)
oxy-acetylene flame
4
Consecutive members of an alkane homologous serires differ by
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(B)
CH2
5
If an element has the electronic configuration 1s 2 2s2 2p3 3s2 3p4, it is
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(D)
a p-Block element
6
Some copper (ll) sulphate pentahydrate (CuSO4 5H2O), was heated at 120 oC with the following results. Wt of crucible = 10.00 g; Wt of crucible + CuSO4 5H2O =14.98g; Wt of crucible + residue = 13.54 g. How many molecules of water of crystalization were lost?
[H = 1, Cu = 63.5, O = 16, S = 32]
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(D)
4
7
The three-dimensional shape of methane is
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(D)
tetrahedral
8
An unknown organic compound X has a relative molecular mass of 180. It is a colourless crystaline solid, readily soluble in water. X contains the elements C, H and O in the atomic ratio 1: 2:1. The compound has a sweet teste and melts on heating. In the presence of yeast and in the absence of air, X is converted to compound Y and a colourless gas. Compound Y reacts with sodium metal to produce a gas Z which gives a 'pop' sound with a glowing splint. Y also reacts with ethanoic acid to give a sweet smelling compound W.
Compound W is
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(D)
an ester
9
An unknown organic compound X has a relative molecular mass of 180. It is a colourless crystaline solid, readily soluble in water. X contains the elements C, H and O in the atomic ratio 1: 2:1. The compound has a sweet teste and melts on heating. In the presence of yeast and in the absence of air, X is converted to compound Y and a colourless gas. Compound Y reacts with sodium metal to produce a gas Z which gives a 'pop' sound with a glowing splint. Y also reacts with ethanoic acid to give a sweet smelling compound W.
The molecular formula of X is
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(B)
C6H12O6
10
An unknown organic compound X has a relative molecular mass of 180. It is a colourless crystaline solid, readily soluble in water. X contains the elements C, H and O in the atomic ratio 1: 2:1. The compound has a sweet teste and melts on heating. In the presence of yeast and in the absence of air, X is converted to compound Y and a colourless gas. Compound Y reacts with sodium metal to produce a gas Z which gives a 'pop' sound with a glowing splint. Y also reacts with ethanoic acid to give a sweet smelling compound W.
Reaction of X with yeast forms the basis of the
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(C)
brewing industry
11
A mixture of common salt, ammonium chloride and barium sulphate can best be separated by
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(C)
sublimation followed by addition of water then filtration
12
Which of the following relationships between the pressure P, the volume V and the temperature T, represents an ideal gas behaviour?
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(B)
P \(\alpha\) T/V
13
The colour imparted to a flame by calcuium ion is
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(C)
brick-red
14
In the reaction M + N P;∆H = + QKJ. Which of the following would increase the concentration of the product?
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(E)
Increasing the temperature
15
In which of the following processes is iron being oxidized?
1 Fe + H2SO4 → FeSO4 +H2
2 FeSO4 + H2S → FeS + H2SO4
3 2FeCI2 + Cl2 → 2FeCl3
4 2FeCl3 + SnCl2 + → 2FeCl2 + SnCl4
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(D)
1 and 3
16
In the reaction Fe + Cu2+ \(\to\) Fe2+ + Cu,iron displaces copper ions to from copper. This is due to the fact that
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(E)
iron is higher in the electrochemical series than copper
17
The correct name of the compound with the above structural formula is
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(A)
2-methylbut -1-ene
18
How many isomeric forms are there for the molecular formula C3H6Br2?
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(D)
4
19
A piece of burning sulphur will continue to burn in a gas jar of oxygen to give misty fumes which readily dissolved in water. The resulting liquid is
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(C)
trioxosulphate (IV) acid
20
Sodium sulphate decahydrate (Na2SO4.10 H2O) on exposure to air loses all its water of crystallization.
The process of loss is known as
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(A)
efflorescence
21
Which of the following happens during the electrolysis of molten sodium chloride?
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(E)
Chloride ion is oxidized
22
Crude petroleum pollutant usually seen on some Nigerian creeks and waterways can be dispersed or removed by
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(C)
pouring organic solvents to dissolve the petroleum
23
An element is electronegative if
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(D)
it has a tendency to gain electrons
24
Solutions X, Y, and Z have PH values 3.0. 5. 0 and 9. 0 respectively. Which of the following statements is correct?
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(E)
Z is the least acidic
25
In the reactions
(I) H2 (g) + 1/2O2(g) → H2O(l); ∆H = -286 KJ
(II) C(s) + O2g) → CO2 (g); ∆H = -406 KJ the equations imply that
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(C)
less heat is evolved in (l)
26
Which of these metals, Mg, Fe, Pb and Cu will dissolve in dilute HCI?
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(D)
Mg and Fe only
27
Stainless steel is an alloy of
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(B)
carbon, iron and chromium
28
Which volume of 0.5 M H 2SO4 will exactly neutralize 20 cm 3 of 0.1 M NaOH solution?
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(A)
2.0 cm 3
29
Which of the following pair of gases will NOT react further with oxygen at a temperature between 30oC AND 400oC
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(C)
NO2 and SO3
30
Some metals are extracted from their ores after some preliminary treatments by electrolysis (L), some by thermal decomposition(T), some by a combination of both processes (TL). Which set-up in the following for the extraction of iron, copper, and aluminium is correct?
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(E)
lron (T) copper (L), aluminium (TL)
31
In the preparation of some pure crystals of Cu (NO3)2 starting with CuO, a student gave the following statements as steps he employed. Which of these shows a flaw in his report ?
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(A)
some CuO was reacted with excess dilute H2SO4
32
Which of the following separation processes is most likely to yield high quality ethanol (>95%) from palm wine?
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(C)
fractional distillation with a dehydrant
33
Increasing the pressure of a gas
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(D)
increases the density of the gas
34
2.5 g of a hydrate barium salt gave on heating, 2.13 g of the anhydrous salt. Given that the relative molecular mass of the of the anhydrous salt is 208, the number of molecules of water of crystallization of the barium salt is
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(D)
2
35
3. 06 g of a sample of potassium trioxochlorate (V) (KCIO\(_3\)) was required to make a saturated solution with 10cm\(^3\) of water at 25°C. The solubility of the salt at 25°C is [K =39, Cl = 35.5, O = 16]
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(C)
2.5 moles dm3
36
The cracking process is very important in the petroleum industry because it.
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(C)
yields more engine fuels
37
A gas that can behave as a reducing agent towards chlorine and as an oxidizing agent toward hydrogen sulphide is
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(C)
SO2
38
Which of the following solutions will give a white precipitate with barium chloride solution and a green flame test?
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(B)
CuSO4
39
The mass of an atom is determined by
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(D)
the number of neutrons and protons
40
Which of the following is a neutralization reaction?
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(E)
Addition of trioxonitrate (V) acid (nitric acid) to potassium hydroxide solution
41
A jet plane carrying 3,000 kg of ethane burns off all the gas forming water and carbondioxide. if all the carbondioxide is expelled and all the water formed is condensed and kept on board the plane, then the gain in weight is
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(D)
2, 400 kg
42
Liquid X, reacts with sodium trioxocarbonate (IV) (Na2CO3) to give a gas which turns calcium chloride solution milky X is
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(D)
an acid
43
Which of the following statements is FALSE?
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(B)
Sodium metal dissolves in water giving oxygen
44
When sodium dioxonitrate (lll) (NaNO2) dissolves in water, ∆H is positive. The process of dissolution is
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(B)
endothermic
45
The equilibrium reaction between copper (l) chloride and chlorine at 25oC and 1 atmosphere is represented by the equation:
2CuCl +Cl2 ⇌ 2 CuCl2 ∆H = - 166 KJ. Which of the following statements is TRUE for the reaction, pressure remaining constant?
