JEE MAIN - Chemistry (2003)

• 1

  Which one of the following statements is not true?

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  (B)

  The pH of 1 $$\times$$ 10^-8 M HCl is 8
• 2

  The internal energy change when a system goes from state A to B is 40 kJ/mole. If the system goes from A to B by a reversible path and returns to state A by an irreversible path what would be the net change in internal energy?

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  (C)

  Zero
• 3

  In an irreversible process taking place at constant T and P and in which only pressure-volume work is being done, the change in Gibbs free energy (dG) and change in entropy (dS), satisfy the criteria :

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  (A)

  (dS)_{V, E} > 0, (dG)_{T, P} < 0
• 4

  The enthalpy change for a reaction does not depend upon :

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  (B)

  the nature of intermediate reaction steps
• 5

  The correct relationship between free energy change in a reaction and the corresponding equilibrium constant K_c is :

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  (C)

  - $$\Delta G^o$$ = RT ln K_c
• 6

  If at 298 K the bond energies of C - H, C - C, C = C and H - H bonds are respectively 414, 347, 615 and 435 kJ/mol, the value of enthalpy change for the reaction
  H₂C = CH₂(g) + H₂(g) $$\to$$ H₃C - CH₃(g) at 298 K will be :

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  (C)

  - 125 kJ
• 7

  The solubility in water of a sparingly soluble salt AB₂ is 1.0 $$\times$$ 10^-5 mol L^-1. Its solubility product number will be :

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  (D)

  4 $$\times$$ 10^-15
• 8

  Consider the reaction equilibrium
  2 SO₂ (g) + O₂ (g) $$\leftrightharpoons$$ 2 SO₃ (g); $$\Delta H^o$$ = -198 kJ
  One the basis of Le Chatelier's principle, the condition favourable for the forward reaction is :

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  (B)

  lowering the temperature and increasing the pressure
• 9

  For the reaction equilibrium
  N₂O₄ (g) $$\leftrightharpoons$$ 2NO₂ (g)
  the concentrations of N₂O₄ and NO₂ at equilibrium are 4.8 $$\times$$ 10^-2 and 1.2 $$\times$$ 10^-2 mol L^-1 respectively. The value of K_c for the reaction is

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  (B)

  3 $$\times$$ 10^-3 mol L^-1
• 10

  When rain is accompanied by a thunderstorm, the collected rain water will have a pH value :

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  (D)

  slightly lower than that of rain water without thunderstorm
• 11

  The IUPAC name of CH₃COCH(CH₃)₂ is

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  (C)

  3-methyl-2-butaone
• 12

  In the anion HCOO^$$-$$ the two carbon-oxygen bonds are found to be of equal length. What is the reason for it?

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  (B)

  The anion HCOO- has two resonating structures
• 13

  The general formula C_nH_2nO₂ could be for open chain

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  (A)

  carboxylic acids
• 14

  On mixing a certain alkane with chlorine and irradiating it with ultravioletlight, it forms only one monochloroalkane. This alkane could be

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  (C)

  neopentane
• 15

  Butene-1 may be converted to butane by reaction with

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  (C)

  Pd/H₂
• 16

  During dehydration of alcohols to alkenes by heating with conc. H₂SO₄ the initiation step is

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  (D)

  protonation of alcohol molecule
• 17

  When CH₂ = CH - COOH is reduced with LiAlH₄, the compound obtained will be

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  (A)

  CH₂ = CH - CH₂OH
• 18

  The correct order of increasing basic nature for the bases NH₃, CH₃NH₂ and (CH₃)₂ NH is

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  (B)

  NH₃ < CH₃NH₂ < (CH₃)₂NH
• 19

  Ethyl isocyanide on hydrolysis in acidic medium generates

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  (D)

  ethylamine salt and methanoic acid
• 20

  Complete hydrolysis of cellulose gives

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  (B)

  D-glucose
• 21

  Which one of the following statements is correct?

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  (A)

  From a mixed precipitate of AgCl and AgI, ammonia solution dissolves only AgCl
• 22

  Bottles containing C₆H₅l and C₆H₅CH₂I lost their original labels. They were labelled A and B for testing A and B were separately taken in test tubes and boiled with NaOH solution. The end solution in each tube was made acidic with dilute HNO₃ and then some AgNO₃ solution was added. Substance B gave a yellow precipitate. Which one of the following statements is true for this experiment?

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  (D)

  A was C₆H₅I
• 23

  Among the following four structures $$i$$ to $$iv,$$
  
  
  
  it is true that

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  (A)

  only $$i$$ and $$ii$$ are chiral compounds
• 24

  The reduction in atomic size with increase in atomic number is a characteristic of elements of

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  (D)

  High atomic masses.
• 25

  The atomic numbers of Vanadium (V), Chromium (cr), Manganese (Mn) and Iron (Fe), respectively, $$23,24,25$$ and $$26$$. Which one of these may be expected to have the higher second ionization enthalpy?

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  (A)

  Cr
• 26

  The reaction of chloroform with alcoholic $$KOH$$ and p-toluidine forms

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  (C)

  
• 27

  The reason for double helical structure of $$DNA$$ is operation of

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  (B)

  hydrogen bonding
• 28

  A red solid is insolvable in water. However it becomes soluble if some $$K{\rm I}$$ is added to water. Heating the red solid in a test tube results in liberation of some violet colored fumes and droplets of a metal appear on the cooler parts of the test tube. The red solid is :

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  (A)

  $$Hg{{\rm I}_2}$$
• 29

  A pressure cooker reduces cooking time for food because

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  (A)

  boiling point of water involved in cooking is increased
• 30

  In a 0.2 molal aqueous solution of a weak acid HX the degree of ionization is 0.3. Taking k_f for water as 1.85, the freezing point of the solution will be nearest to

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  (D)

  -0.480^oC
• 31

  If liquids A and B form an ideal solution

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  (D)

  the enthalpy of mixing is zero
• 32

  Standard reduction electrode potentials of three metals A,B&C are respectively +0.5 V, -3.0 V & -1.2 V. The reducing, powers of these metals are

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  (D)

  B > C > A
• 33

  For a cell reaction involving a two-electron change, the standard e.m.f. of the cell is found to be 0.295 V at 25^oC. The equilibrium constant of the reaction at 25^oC will be

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  (C)

  1 $$\times$$ 10¹⁰
• 34

  When during electrolysis of a solution of AgNO₃, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be :

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  (A)

  10.8 g
• 35

  For the redox reaction Zn(s) + Cu²⁺(0.1 M) $$\to$$ Zn²⁺(1M) + Cu(s) taking place in a cell, $$E_{cell}^o$$ is 1.10 volt. E_cell for the cell will be ($$2.303{{RT} \over F}$$ = 0.0591)

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  (B)

  1.07 volt
• 36

  Several blocks of magnesium are fixed to the bottom of a ship to :

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  (B)

  prevent action of water and salt
• 37

  The radionucleide $${}_{90}^{234}Th$$ undergoes two successive $$\beta$$ -decays followed by one $$\alpha$$-decay. The atomic number and the mass number respectively of the resulting radionucleide are

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  (B)

  90 and 230
• 38

  The half-life of a radioactive isotope is three hours. If the initial mass of the isotope were 256 g, the mass of it remaining undecayed after 18 hours would be

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  (D)

  4.0 g
• 39

  In respect of the equation k = Ae^-E_a/RT in chemical kinetics, which one of the following statements is correct?

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  (B)

  E_a is energy of activation
• 40

  The rate law for a reaction between the substances A and B is given by Rate = k[A]ⁿ [B]^m On doubling the concentration of A and halving the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as

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  (C)

  2^{( n - m)}
• 41

  For the reaction system:
  
  2NO(g) + O₂(g) $$\to$$ 2NO₂(g) volume is suddenly reduce to half its value by increasing the pressure on it. If the reaction is of first order with respect to O₂ and second order with respect to NO, the rate of reaction will

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  (B)

  increase to eight times of its initial value
• 42

  Which one of the following substances has the highest proton affinity?

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  (B)

  NH₃
• 43

  For making good quality mirrors, plates of float glass are used. These are obtained by floating molten glass over a liquid metal which does not solidify before glass. The metal used can be :

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  (D)

  mercury
• 44

  Glass is a :

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  (A)

  super-cooled liquid
• 45

  What would happen when a solution of potassium chromate is treated with an excess of dilute nitric acid?

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  (A)

  $$Cr_2O^{2-}_7$$ and H₂O are formed
• 46

  The atomic numbers of vanadium (V), Chromium (Cr), manganese (Mn) and iron (Fe) are respectively 23, 24, 25 and 26. Which one of these may be expected to have the highest second ionization enthalpy?

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  (A)

  Cr
• 47

  Which one of the following nitrates will leave behind a metal on strong heating?

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  (C)

  Silver nitrate
• 48

  Ammonia forms the complex ion [Cu(NH₃)₄]²⁺ with copper ions in alkaline solutions but not in acidic solutions. What is the reason for it?

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  (A)

  In acidic solutions protons coordinate with ammonia molecules forming $$NH^+_4$$ ions and NH₃ molecules are not available
• 49

  The radius of La³⁺ (Atomic number of La = 57) is 1.06 Å. Which one of the following given values will be closest to the radius of Lu³⁺ (Atomic number of Lu = 71) ?

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  (C)

  0.85 Å
• 50

  One mole of the complex compound Co(NH₃)₅Cl₃, gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with two moles of AgNO₃ solution to yield two moles of AgCl (s). The structure of the complex is :

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  (D)

  [Co(NH₃)₅Cl] Cl₂
• 51

  In the coordination compound, K₄[Ni(CN)₄], the oxidation state of nickel is :

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  (A)

  0
• 52

  The pair of species having identical shapes for molecules of both species is

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  (A)

  XeF₂, CO₂
• 53

  What volume of hydrogen gas at 273 K and 1 atm pressure will be consumed in obtaining 21.6 g of elemental boron (atomic mass = 10.8) from the reduction of boron trichloride by hydrogen?

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  (A)

  67.2 L
• 54

  25 ml of a solution of barium hydroxide on titration with a 0.1 molar solution of hydrochloric acid gave a litre value of 35 ml. The molarity of barium hydroxide solution was

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  (D)

  0.07
• 55

  The number of d-electrons retained in Fe²⁺ (At no of Fe = 26) ion is :

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  (C)

  6
• 56

  The orbital angular momentum for an electron revolving in an orbit is given by $$\sqrt {l(l + 1)} {h \over {2\pi }}$$. This momentum for an s-electron will be given by

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  (A)

  zero
• 57

  Which one of the following groupings represents a collection of isoelectronic species? (At. nos. : Cs : 55, Br : 35)

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  (A)

  N^3-, F^-, Na⁺
• 58

  In Bohr series of lines of hydrogen spectrum, the third line from the red end corresponds to which one of the following inter-orbit jumps of the electron for Bohr orbits in an atom of hydrogen

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  (A)

  5 $$\to$$ 2
• 59

  The de Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 meters per second is approximately

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  (D)

  10^-33 meters
• 60

  According to the Periodic Law of elements, the variation in properties of elements is related to their

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  (B)

  atomic numbers
• 61

  Which one of the following is an amphoteric oxide?

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  (D)

  ZnO
• 62

  An ethar is more volatile than an alcohol having the same molecular formula. This is due to

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  (C)

  inter-molecular hydrogen bonding in alcohols
• 63

  Which one of the following pairs of molecules will have permanent dipole moments for both members

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  (B)

  NO₂ and O₃
• 64

  Which one of the following compounds has the smallest bond angle in its molecule?

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  (B)

  SH₂