WAEC - Chemistry (2002 - No. 37)

Consider the following equation: Cr\(_2\)O\(_7\)\(^{2-}\)(aq) + 14H\(^+\)(aq) + 6e\(^-\) → 2Cr\(^{3+}\)(ag) + 7H\(_2\)O(1). The oxidation number of chromium changes from
-2 to + 3
-2 to + 6
+6 to +3
+7 to + 6

Explanation

Cr\(_2\)O\(_7\)\(^{2-}\)(aq) + 14H\(^+\)(aq) + 6e\(^-\) → 2Cr\(^{3+}\)(ag) + 7H\(_2\)O(1).

All we need to do is to calculate the oxidation number of Cr on the reactant side (LHS) and compare with the one on the RHS.

  Cr\(_2\)O\(_7\)\(^{2-}\) → Cr\(^{3+}\)

 Cr\(_2\)O\(_7\) = - 2 → Cr  = + 3

  2Cr + 7(O) = - 2 

  2Cr + 7(- 2) = - 2

  2Cr - 14  = - 2

  2Cr = - 2 + 14

  2Cr = + 12

 Cr = \(\frac{12}{2}\)

 Cr = + 6 → Cr  = + 3

Therefore, the change in oxidation number of Cr changed from +6 to +3 - Option C

 

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