Quick Biochemistry - Water And Electrolyte Balance (Section 2 - No. 31)

What compound would be most effective for buffering at a typical biological pH, considering their respective pK₊ values?
Na₂HPO₄ pK₊ = 12.32
Na₂HPO₄ pK₊=7.21
NH₄OH pK₊ = 7.24
Citric acid pK₊ = 3.09

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