JEE Advance - Physics (2010 - Paper 2 Offline - No. 17)

The key feature of Bohr's theory of spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid. The rule to be applied is Bohr's quantization condition.
The key feature of Bohr's theory of spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid. The rule to be applied is Bohr's quantization condition.
The key feature of Bohr's theory of spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid. The rule to be applied is Bohr's quantization condition.
In a CO molecule, the distance between C (mass = 12 amu) and O (mass = 16 amu), where 1 amu $$ = {5 \over 3} \times {10^{ - 27}}$$ kg, is close to :
2.4 $$\times$$ 10$$-$$10 m
1.9 $$\times$$ 10$$-$$10 m
1.3 $$\times$$ 10$$-$$10 m
4.4 $$\times$$ 10$$-$$11 m

Explanation

The moment of inertia of CO molecule is

I = $$\mu$$r2 ....... (i)

where, $$\mu$$ = reduced mass of the CO molecule, r = distance between C and O or bond length

The reduced mass $$\mu$$ of the CO molecule is

$$\mu = {{{m_1}{m_2}} \over {{m_1} + {m_2}}} = \left[ {{{(12)(16)} \over {12 + 16}}} \right] \times {5 \over 3} \times {10^{ - 27}}$$ kg

But $$I = 1.87 \times {10^{ - 46}}$$ kg m2 (From the above question)

From equation (i), we get

$${r^2} = {I \over \mu }$$

Substituting the values of I and $$\mu$$ in above equation, we get

$${r^2} = {{1.87 \times {{10}^{ - 46}}} \over {\left[ {{{12 \times 16} \over {28}} \times {5 \over 3} \times {{10}^{ - 27}}} \right]}}$$

or $${r^2} = {{1.87 \times {{10}^{ - 46}} \times 28 \times 3} \over {12 \times 16 \times 5 \times {{10}^{ - 27}}}}$$ or $$r = 1.3 \times {10^{ - 10}}$$ m

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