JEE Advance - Chemistry (2024 - Paper 1 Online - No. 10)

Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. $\mathrm{NaOH}$ solution, gives $\mathbf{P}$ and $\mathbf{Q}$. Compound $\mathbf{P}$ does not give Tollens' test, whereas $\mathbf{Q}$ on acidification gives positive Tollens' test. Treatment of $\mathbf{P}$ with excess cyclohexanone in the presence of catalytic amount of $p$-toluenesulfonic acid (PTSA) gives product $\mathbf{R}$.

Sum of the number of methylene groups $\left(-\mathrm{CH}_2-\right)$ and oxygen atoms in $\mathbf{R}$ is __________.

Answer
18

Explanation

JEE Advanced 2024 Paper 1 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 5 English Explanation

Number of $\mathrm{CH}_2$ groups in $\mathrm{R}=14$

Number of $\mathrm{O}$-atoms $=4$

Required Answer $=14+4=18$

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