JEE Advance - Chemistry (2023 - Paper 2 Online - No. 8)

$\mathrm{H}_2 \mathrm{S}$ (5 moles) reacts completely with acidified aqueous potassium permanganate solution. In this reaction, the number of moles of water produced is $\mathbf{x}$, and the number of moles of electrons involved is $\mathbf{y}$. The value of $(\mathbf{x}+\mathbf{y})$ is ________.
Answer
18

Explanation

  1. We start with the balanced redox reaction :


    $$2 \, \mathrm{KMnO}_4 + 3 \, \mathrm{H}_2\mathrm{SO}_4 + 5 \, \mathrm{H}_2\mathrm{S} \rightarrow \mathrm{K}_2\mathrm{SO}_4 + 2 \, \mathrm{MnSO}_4 + 5 \, \mathrm{S} + 8 \, \mathrm{H}_2\mathrm{O}$$


  2. We want to find out the number of moles of water ($x$) produced and the number of moles of electrons ($y$) involved in this reaction.


  3. From the balanced equation, we can see that 8 moles of water are produced from the reaction. So, we can say :


    $$x = 8$$


  4. Hydrogen sulfide ($\mathrm{H}_2\mathrm{S}$) gets oxidized to sulfur ($\mathrm{S}$) in this reaction. Each molecule of $\mathrm{H}_2\mathrm{S}$ loses 2 electrons during this process (as sulfur has an oxidation state of -2 in $\mathrm{H}_2\mathrm{S}$ and 0 in $\mathrm{S}$).


  5. So, for every mole of $\mathrm{H}_2\mathrm{S}$, 2 moles of electrons are involved. And since 5 moles of $\mathrm{H}_2\mathrm{S}$ are reacting, the total number of moles of electrons involved is $5 \times 2 = 10$. So, we can say :


    $$y = 10$$


  6. We are asked to find the sum of $x$ and $y$, so we add these two values together to get:


    $$x + y = 8 + 10 = 18$$

Therefore, the value of $(x + y)$ is 18.

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