JEE Advance - Chemistry (2023 - Paper 2 Online - No. 1)

The correct molecular orbital diagram for $\mathrm{F}_2$ molecule in the ground state is :
JEE Advanced 2023 Paper 2 Online Chemistry - Chemical Bonding & Molecular Structure Question 5 English Option 1
JEE Advanced 2023 Paper 2 Online Chemistry - Chemical Bonding & Molecular Structure Question 5 English Option 2
JEE Advanced 2023 Paper 2 Online Chemistry - Chemical Bonding & Molecular Structure Question 5 English Option 3
JEE Advanced 2023 Paper 2 Online Chemistry - Chemical Bonding & Molecular Structure Question 5 English Option 4

Explanation

(1) Upto 14 electrons, molecular orbital configuration is ->

JEE Advanced 2023 Paper 2 Online Chemistry - Chemical Bonding & Molecular Structure Question 5 English Explanation 1
Nb = No of electrons in bonding molecular orbital

Na $$=$$ No of electrons in anti bonding molecular orbital

Here Na = Anti bonding electron $$=$$ 4 and Nb = 10

(2) After 14 electrons to 20 electrons molecular orbital configuration is ->

JEE Advanced 2023 Paper 2 Online Chemistry - Chemical Bonding & Molecular Structure Question 5 English Explanation 2

Here Na = 10

and Nb = 10

Now from question, in F atom 9 electrons present, so in F2, 9 $$ \times $$ 2 = 18 electrons present.

Molecular orbital configuration of F2(18 electrons) is

$${\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\sigma _{2p_z^2}}\,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,\pi _{2p_x^2}^ * \, = \,\pi _{2p_y^2}^ * $$

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