JEE Advance - Chemistry (2023 - Paper 1 Online - No. 17)
The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option.
| List - I | List - II |
|---|---|
| (P) Etard reaction | (1) Acetophenone $\stackrel{\mathrm{Zn}-\mathrm{Hg}, \mathrm{HCl}}{\longrightarrow}$ |
| (Q) Gattermann reaction | (2) $$ \text { Toluene } \underset{\text { (ii) } \mathrm{SOCl}_2}{\stackrel{\text { (i) } \mathrm{KMnO}_4, \mathrm{KOH}, \Delta}{\longrightarrow}} $$ |
| (R) Gattermann-Koch reaction | (3) $$ \text { Benzene } \underset{\text { anhyd. } \mathrm{AlCl}_3}{\stackrel{\mathrm{CH}_3 \mathrm{Cl}}{\longrightarrow}} $$ |
| (S) Rosenmund reduction | (4) $$ \text { Aniline } \underset{273-278 \mathrm{~K}}{\stackrel{\mathrm{NaNO}_2 / \mathrm{HCl}}{\longrightarrow}} $$ |
| (5) $$ \text { Phenol } \stackrel{\mathrm{Zn}, \Delta}{\longrightarrow} $$ |
$$
\mathrm{P} \rightarrow 2 ; \mathrm{Q} \rightarrow 4 ; \mathrm{R} \rightarrow 1 ; \mathrm{S} \rightarrow 3
$$
$$
\mathrm{P} \rightarrow 1 ; \mathrm{Q} \rightarrow 3 ; \mathrm{R} \rightarrow 5 ; \mathrm{S} \rightarrow 2
$$
$$
\mathrm{P} \rightarrow 3 ; \mathrm{Q} \rightarrow 2 ; \mathrm{R} \rightarrow 1 ; \mathrm{S} \rightarrow 4
$$
$$
\mathrm{P} \rightarrow 3 ; \mathrm{Q} \rightarrow 4 ; \mathrm{R} \rightarrow 5 ; \mathrm{S} \rightarrow 2
$$
Explanation
$(P) \rightarrow(3)$
$(Q) \rightarrow(4)$
$(\mathrm{R}) \rightarrow(5)$
$(S) \rightarrow(2)$
$(Q) \rightarrow(4)$
$(\mathrm{R}) \rightarrow(5)$
$(S) \rightarrow(2)$
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