JEE Advance - Chemistry (2022 - Paper 1 Online - No. 9)

For diatomic molecules, the correct statement(s) about the molecular orbitals formed by the overlap of two $2 p_{z}$ orbitals is(are)
$\sigma$ orbital has a total of two nodal planes.
$\sigma^{*}$ orbital has one node in the $x z$-plane containing the molecular axis.
$\pi$ orbital has one node in the plane which is perpendicular to the molecular axis and goes through the center of the molecule.
$\pi^{*}$ orbital has one node in the $x y$-plane containing the molecular axis.

Explanation

JEE Advanced 2022 Paper 1 Online Chemistry - Structure of Atom Question 4 English Explanation 1

Option (A) is correct. JEE Advanced 2022 Paper 1 Online Chemistry - Structure of Atom Question 4 English Explanation 2

Option (B) is incorrect. JEE Advanced 2022 Paper 1 Online Chemistry - Structure of Atom Question 4 English Explanation 3

$\pi^*$ orbital has zero node is the plane which is perpendicular to the molecular axis and goes through the center of molecule.

So, option (C) is incorrect. JEE Advanced 2022 Paper 1 Online Chemistry - Structure of Atom Question 4 English Explanation 4

$\pi^*$ Orbital has one node in the $x y-$ plane containing the molecular axis.

Option (D) is correct.

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