JEE Advance - Chemistry (2021 - Paper 2 Online - No. 18)
Consider a helium (He) atom that absorbs a photon of wavelength 330 nm. The change in the velocity (in cm s$$-$$1) of He atom after the photon absorption is __________.
(Assume : Momentum is conserved when photon is absorbed.
Use : Planck constant = 6.6 $$\times$$ 10$$-$$34 J s, Avogadro number = 6 $$\times$$ 1023 mol$$-$$1, Molar mass of He = 4 g mol$$-$$1)
(Assume : Momentum is conserved when photon is absorbed.
Use : Planck constant = 6.6 $$\times$$ 10$$-$$34 J s, Avogadro number = 6 $$\times$$ 1023 mol$$-$$1, Molar mass of He = 4 g mol$$-$$1)
Answer
30
Explanation
Wavelength of photon absorbed, $$\lambda$$ = 330 nm = 330 $$\times$$ 10$$-$$9 m
Planck's constant, h = 6.6 $$\times$$ 10$$-$$34 J s
Molar mass of He, M = 4 g mol$$-$$1 = 4 $$\times$$ 10$$-$$3 kg mol$$-$$1
Avogadro number, NA = 6 $$\times$$ 1023 mol$$-$$1
Mass of one atom of He, $$m = {M \over {{N_A}}}$$
$$ = {{4 \times {{10}^{ - 3}}} \over {6 \times {{10}^{23}}}} = {2 \over 3} \times {10^{ - 26}}$$ kg
Velocity, = V cm/s.
Using de-Broglie equation,
$$\lambda = {h \over {mv}}$$
$$ \Rightarrow v = {h \over {m\lambda }} = {{6.6 \times {{10}^{ - 34}}} \over {2/3 \times {{10}^{ - 26}} \times 330 \times {{10}^{ - 9}}}}$$
$$ = {{6.6 \times 3 \times {{10}^{ - 34}} \times {{10}^{35}}} \over {2 \times 330}} = 0.03 \times 10 = 0.3$$ m/s
= 30 cm/s
Planck's constant, h = 6.6 $$\times$$ 10$$-$$34 J s
Molar mass of He, M = 4 g mol$$-$$1 = 4 $$\times$$ 10$$-$$3 kg mol$$-$$1
Avogadro number, NA = 6 $$\times$$ 1023 mol$$-$$1
Mass of one atom of He, $$m = {M \over {{N_A}}}$$
$$ = {{4 \times {{10}^{ - 3}}} \over {6 \times {{10}^{23}}}} = {2 \over 3} \times {10^{ - 26}}$$ kg
Velocity, = V cm/s.
Using de-Broglie equation,
$$\lambda = {h \over {mv}}$$
$$ \Rightarrow v = {h \over {m\lambda }} = {{6.6 \times {{10}^{ - 34}}} \over {2/3 \times {{10}^{ - 26}} \times 330 \times {{10}^{ - 9}}}}$$
$$ = {{6.6 \times 3 \times {{10}^{ - 34}} \times {{10}^{35}}} \over {2 \times 330}} = 0.03 \times 10 = 0.3$$ m/s
= 30 cm/s
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