JEE Advance - Chemistry (2014 - Paper 1 Offline - No. 2)

In a galvanic cell, the salt bridge
does not participate chemically in the cell reaction.
stops the diffusion of ions from one electrode to another.
is necessary for the occurrence of the cell reaction.
ensures mixing of the two electrolytic solutions.

Explanation

In a galvanic cell, also known as a voltaic cell, a salt bridge plays a crucial role in maintaining electrical neutrality within the internal circuit, which is critical for the ongoing electrochemical reaction and thus the production of electrical energy. Here, we will analyze each of the given options in the context of the function of a salt bridge in a galvanic cell:

Option A: does not participate chemically in the cell reaction.

This statement is correct. The salt bridge in a galvanic cell does not directly participate in the chemical reactions occurring at the electrodes. Its primary function is to complete the electrical circuit between the cathode and anode by allowing the transfer of ions. The salt bridge contains a salt solution (usually KNO3, KCl, or NH4NO3), where the ions migrate to oppose and balance the charge buildup due to the migration of electrons through the external circuit.

Option B: stops the diffusion of ions from one electrode to another.

This option can be misleading. The salt bridge does not stop the diffusion of ions from diffusing from one electrode to another but rather provides a pathway for ions to flow back and forth, which is essential to maintain the charge balance. Hence, this statement is not the best descriptor of the salt bridge's function.

Option C: is necessary for the occurrence of the cell reaction.

This option is correct. A salt bridge is necessary for the occurrence of the cell reaction because it maintains electrical neutrality in the electrochemical cell. Without the salt bridge, the flow of electrons through the external circuit would soon cease as the solutions in the anode and cathode compartments become respectively positively and negatively charged, which would stop the electrochemical reaction.

Option D: ensures mixing of the two electrolytic solutions.

This statement is incorrect. The purpose of the salt bridge is not to mix the two electrolytic solutions; in fact, it prevents them from mixing, which could otherwise result in a direct neutralization reaction that could interfere with the proper functioning of the cell. The ions in the salt bridge only migrate enough to balance the charges in the separate solutions.

In summary, the correct answers are Option A ("does not participate chemically in the cell reaction") and Option C ("is necessary for the occurrence of the cell reaction").

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