JEE Advance - Chemistry (2011 - Paper 2 Offline - No. 15)

Reduction of the metal centre in aqueous permanganate ion involves
3 electrons in neutral medium.
5 electrons in neutral medium.
3 electrons in alkaline medium.
5 electrons in acidic medium.

Explanation

In an aqueous solution, the reduction of the metal center in permanganate ions ($MnO_4^-$) varies depending on the medium :

Acidic Medium : Permanganate acts as a strong oxidizing agent. The reaction can be represented as :

$$8H^+ + 5e^- + MnO_4^- \to Mn^{2+} + 4H_2O$$

This indicates that 5 electrons are involved in the reduction process in an acidic medium.

Neutral Medium : Permanganate acts as a moderate oxidizing agent. The reaction in a neutral medium is :

$$2H_2O + 3e^- + MnO_4^- \to MnO_2 + 4OH^-$$

Here, 3 electrons are involved in the reduction process in a neutral medium.

Alkaline Medium : In alkaline conditions, the reaction is similar to that in a neutral medium :

$$2H_2O + 3e^- + MnO_4^- \to MnO_2 + 4OH^-$$

Again, 3 electrons are involved in the reduction process in an alkaline medium.

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