JEE Advance - Chemistry (2011 - Paper 1 Offline - No. 3)

According to kinetic theory of gases
collisions are always elastic
heavier molecules transfer more momentum to the wall of the container
only a small number molecules have very high velocity
between collisions, the molecules move in straight line with constant velocity

Explanation

(A) When gas molecules collide with each other, high energy molecule transfers some of its energy to less energetic molecule, but the total energy remains conserved. This type of collision between gas molecules is called elastic collision. According to kinetic theory of gas, no loss of energy is observed on collisions and kinetic energy is proportional to absolute temperature of gas.

Option (A) is correct.

(B) Momentum of any particle for example, gas molecules depends upon the mass as well as the velocity of the gas. But when there is huge increase in the mass of the gas, its velocity decreases considerably. Hence, heavier gas molecules collides the walls of container with less impact. The transfer of momentum to the walls is very less.

Option (B) is incorrect.

(C) Maximum number (no.) of gas molecules have speed distributed around the most probable speed ( $v_{\mathrm{mps}}$ ). This speed corresponds to the maximum peak of Maxwell-Boltzmann distribution curve.

IIT-JEE 2011 Paper 1 Offline Chemistry - Gaseous State Question 23 English Explanation

There are few molecules which have very high speed (the shaded area under the curve).

Option $(\mathrm{C})$ is correct.

(D) Molecules are assumed to be moving in straight line with constant velocities.

Option (D) is correct.

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