JEE Advance - Chemistry (2008 - Paper 2 Offline - No. 2)

The correct stability order for the following species is :

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English

(II) > (IV) > (I) > (III)
(I) > (II) > (III) > (IV)
(II) > (I) > (IV) > (III)
(I) > (III) > (II) > (IV)

Explanation

Stability of the following species depends upon the no. of $$\alpha$$ hydrogen which can undergoes hyperconjugation as well as resonance. Higher the no. of $$\alpha$$ hydrogen, higher will be the stability of the carbocation.

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English Explanation 1

Stabilizes by resonance and have six $$\alpha$$-hydrogen atoms (hyperconjugation).

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English Explanation 2

Stabilizes by resonance and have three $$\alpha$$-hydrogen atoms.

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English Explanation 3

It have five $$\alpha$$-hydrogen atoms.

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English Explanation 4

It have only two $$\alpha$$-hydrogen atoms.

$$\therefore$$ (I) > (III) > (II) > (IV)

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