JEE Advance - Chemistry (2008 - Paper 1 Offline - No. 2)
Hyperconjugation involves overlapping of the following orbitals:
$$\sigma-\sigma$$
$$\sigma-p$$
$$p-p$$
$$\pi-\pi$$
Explanation
Hyperconjugation effect is one of the type of permanent effect in which delocalisation of $$\sigma$$ electrons of C-H bond of an alkyl group directly attached to an atom of the unsaturated system or to an atom with an unshared p orbital. The main role of hyperconjugation is to stabilise the carbocation because it helps in the dispersal of positive charge. Higher the number of alkyl groups attached to a positively charged carbon atom, greater is the hyperconjugative effect and stability of carbonation. It generally involves the interaction of electrons in a C-H sigma orbital with nearby non-bonding p or anti-bonding $$\sigma^*$$ or $$\pi^*$$ orbitals to provide extended conjugation which further increases the stability of the carbocation. Sometimes, low lying anti-bonding $$\sigma^*$$ also interact with filled orbitals of lone pair character. This type of conjugation is termed as negative hyperconjugation.
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