JEE Advance - Chemistry (1994 - No. 2)
Explanation
To find the oxidation state of copper in the superconducting compound $YBa_{2}Cu_{3}O_{7}$, we start by assuming the oxidation states of each element based on common oxidation states and the necessary neutrality of the compound. In this compound:
- Yttrium ($Y$) is in its usual oxidation state of +3.
- Barium ($Ba$) typically has an oxidation state of +2.
- Oxygen ($O$) typically has an oxidation state of -2.
The formula for the compound is given as $YBa_{2}Cu_{3}O_{7}$. The overall charge of the compound must be zero. Setting up the equation based on the oxidation states and the stoichiometry of the compound, we get:
$+3 + 2(+2) + 3(x) + 7(-2) = 0$
$3 + 4 + 3x - 14 = 0$
$3x - 7 = 0$
$3x = 7$
$x = \frac{7}{3}$
So, the oxidation state of copper (Cu) in $YBa_{2}Cu_{3}O_{7}$ is $\frac{7}{3}$, or more conventionally expressed as +$\frac{7}{3}$ or +2.33 when averaged over the three copper atoms. This mixed valency is a characteristic of the copper oxide layers in high-temperature superconducting materials, allowing for the unique electronic properties that enable superconductivity.
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